Viscosity of kaolin slurries: Effects of dispersant and urea-intercalation

Xiumei Qiu , Yadong Liu , Aref Alshameri , Xiaoyan Zhu , Chunjie Yan

Journal of Wuhan University of Technology Materials Science Edition ›› 2017, Vol. 32 ›› Issue (1) : 51 -57.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2017, Vol. 32 ›› Issue (1) : 51 -57. DOI: 10.1007/s11595-017-1557-2
Advanced Materials

Viscosity of kaolin slurries: Effects of dispersant and urea-intercalation

Author information +
History +
PDF

Abstract

Good fluidity (low viscosity) of highly concentrated kaolin is highly needed in paper-coating industry. We put forward an effective route to improve the viscosity concentration of Beihai kaolin slurries. The effects of various factors such as solid content, pH, dispersant content, and urea-intercalation on the viscosity of kaolin slurries were investigated. The results revealed that the viscosity of kaolin slurries significantly decreased with decreasing solid content or with increasing pH and dispersant content. It was worth noting that urea-intercalation was proven to be an efficient method for promoting the dispersion of highly concentrated kaolin as compared with adding dispersant. The intercalation ratio of urea-intercalated kaolin was increased from 17.36% with 2% of urea addition to 81.30% with 6% of urea addition. Meanwhile, the viscosity concentration of raw kaolin slurry was improved from 65.0% to 70.13% after the intercalation of urea with 6% addition, which was attributed to finer particle size, increased pH value and more negative charges of urea-intercalated kaolin. Therefore, the route is effective to improve the dispersion of highly concentrated kaolin for paper-coating.

Keywords

beihai kaolin / dispersion / urea-intercalation / viscosity concentration

Cite this article

Download citation ▾
Xiumei Qiu, Yadong Liu, Aref Alshameri, Xiaoyan Zhu, Chunjie Yan. Viscosity of kaolin slurries: Effects of dispersant and urea-intercalation. Journal of Wuhan University of Technology Materials Science Edition, 2017, 32(1): 51-57 DOI:10.1007/s11595-017-1557-2

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Conceição S, Santos N F, Velho J, et al. Properties of Paper Coated with Kaolin: The Influence of the Rheological Modifier[J]. Appl. Clay Sci., 2005, 30(3): 165-173.

[2]

Murray H H, Jessica E K. Engineered Clay Products for the Paper Industry[J]. Appl. Clay Sci., 2005, 29(29): 199-206.

[3]

Penner D, Lagaly G. Influence of Anions on the Rheological Properties of Clay Mineral Dispersions[J]. Appl. Clay Sci., 2001, 19(1): 131-142.

[4]

General Administration of Quality Supervision, InspectionQuarantine of the People's Republic of ChinaAQSIQStandardization Administration of the People's Republic of China. Specification and Test Method of Kaolin Clay[S]. 2008

[5]

Zhu X Y, Chen J C, Chen J Y, et al. Urea Intercalation Compound Production in Industrial Scale for Paper Coating[J]. Chem. Ind. Chem. Eng. Q, 2014, 20(2): 241-248.

[6]

Lei D S, Fang J G, Yuan J Z, et al. Experimental Study on Reducing the Viscosity of Paper Coating Kaolin[J]. China Non-Metallic Mining Industry Hetad, 2006, 2: 21-24.

[7]

Qiu X M, Lei X R, Alshameri A, et al. Comparison of the Physicochemical Properties and Mineralogy of Chinese (Beihai) and Brazilian Kaolin[J]. Ceram. Int., 2014, 40(40): 5397-5405.

[8]

Bundy W M, Ishley JN. Kaolin in Paper Filling and Coating[J]. Appl. Clay Sci., 1991, 5(5): 397-420.

[9]

Yuan J, Murray H H. The Importance of Crystal Morphology on the Viscosity of Concentrated Suspensions of Kaolins[J]. Appl. Clay Sci., 1997, 3(12): 209-219.

[10]

Zhang L, Lu Q Y, Xu Z, et al. Effect of Polycarboxylate ether Combtype Polymer on Viscosity and Interfacial Properties of Kaolinite Clay Suspensions[J]. J. Colloid Interf. Sci., 2012, 378(1): 222-231.

[11]

Duman O, Tunc S, Etinkaya A C. Electrokinetic and Rheological Properties of Kaolinite in Poly(diallyldimethylammonium chloride), Poly(sodium 4-styrene sulfonate) and Poly(vinyl alcohol) Solutions[J]. Colloid. Surface. A, 2012, 394(2): 23-32.

[12]

Maxim L, Olivier L, Nikolai L, et al. Fluidity of Highly Concentrated Kaolin Suspensions: Influence of Particle Concentration and Presence of Dispersant[J]. Colloid. Surface. A, 2008, 325(1): 64-71.

[13]

Valášková M, Rieder M, Matějka V. Exfoliation/Delamination of Kaolinite by Low-Temperature Washing of Kaolinite-Urea Intercalates[J]. Appl. Clay Sci., 2007, 35(1-2): 108-118.

[14]

Zhang Z, Lu X C, Su P. Dispersion of Kaolin Powders in Silica Sols[J]. Appl. Clay Sci., 2010, 49(1-2): 51-54.

[15]

Gardolinski J E F C, Lagaly G. Grafted Organic Derivatives of Kaolinite: I. Synthesis, Chemical and Rheological Characterization[J]. Clay Miner., 2005, 40(4): 537-546.

[16]

Cheng H F, Liu Q F, Zhang J S, et al. Delamination of Kaolinite-Potassium Acetate Intercalates by Ball-Milling[J]. J. Colloid Interf. Sci., 2010, 348(2): 355-359.

[17]

Orzechowski K, Słonka T, Głowinsk J. Dielectric Properties of Intercalated Kaolinite[J]. J. Phys. Chem. Solids, 2006, 67(5-6): 915-919.

[18]

Zhu X Y, Yan C J, Chen J Y. Application of Urea-Intercalated Kaolinite for Paper Coating[J]. Appl. Clay Sci., 2012, 55(7): 114-119.

[19]

Goh R, Leong Y K, Lehane B. Bentonite Slurries-Zeta Potential, Yield Stress, Adsorbed Additive and Time-Dependent Behaviour[J]. Rheol. Acta, 2011, 50(1): 29-38.

[20]

Fu J, Zhang Z. A Study of Order Degree in the Structure of Kaolinite by X-ray Diffraction[J]. J. Cent. South Univ., 1988, 6: 604-611.

[21]

Rao F, Ramirez-Acosta F J, Sanchez-Leija R J, et al. Stability of Kaolinite Dispersions in the Presence of Sodium and Aluminum Ions[J]. Appl. Clay Sci., 2011, 51(1-2): 38-42.

[22]

Konan K L, Peyratout C, Cerbelaud M, et al. Influence of Two Dispersants on the Rheological Behavior of Kaolin and Illite in Concentrated Calcium Hydroxide Dispersions[J]. Appl. Clay Sci., 2008, 42(1): 252-257.

[23]

Penner D, Lagaly G. Influence of Anions on the Rheological Properties of Clay Mineral Dispersions[J]. Appl. Clay Sci., 2001, 19(1): 131-142.

[24]

Beazley K M. Viscosity-Concentration Relations in Deflocculated Kaolin Suspensions[J]. J. Colloid Interf. Sci., 1972, 41(1): 105-115.

[25]

Lagaly G. Principles of Flow of Kaolin and Bentonite Dispersions[J]. Appl. Clay Sci., 1989, 4(2): 105-123.

[26]

Wang B X, Zhao X P. The Influence of Intercalation Rate and Degree of Substitution on the Electrorheological Activity of a Novel Ternary Intercalated Nanocomposites[J]. J. Solid State Chem., 2006, 179(3): 949-954.

AI Summary AI Mindmap
PDF

101

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/