Initiation of single-part epoxy in cementitious system

Jipeng Zhu , Zongjin Li , Yamei Zhang

Journal of Wuhan University of Technology Materials Science Edition ›› 2016, Vol. 31 ›› Issue (3) : 713 -716.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2016, Vol. 31 ›› Issue (3) : 713 -716. DOI: 10.1007/s11595-016-1434-4
Organic Materials

Initiation of single-part epoxy in cementitious system

Author information +
History +
PDF

Abstract

In order to make clear the interaction mechanism of single component epoxy in cementitious environment, the interaction between epoxy resin and active silanol, epoxy resin and alkali was investigated From solid-state 13C NMR and FT-IR tests, it is confirmed that silanol group can initiate epoxy resin. Test results have also revealed that alkali as the dominant product of cement hydration can open the epoxide ring making epoxy harden.

Keywords

cementitious system / epoxy / hardener-free

Cite this article

Download citation ▾
Jipeng Zhu, Zongjin Li, Yamei Zhang. Initiation of single-part epoxy in cementitious system. Journal of Wuhan University of Technology Materials Science Edition, 2016, 31(3): 713-716 DOI:10.1007/s11595-016-1434-4

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Sepideh K, Narges Hassani. Adhesion Strength Improvement of Epoxy Resin Reinforced with Nanoelastomeric Copolymer[J]. Materials Science and Engineering: A, 2010, 527: 6562-6567.

[2]

Deng S, Zhou X, Fan C, et al. Release of Interfacial Thermal Stress and Accompanying Improvement of Interfacial Adhesion in Carbon Fiber Reinforced Epoxy Resin Composites: Induced by Diblock Copolymers[J]. Composites Part A: Applied Science and Manufacturing, 2012, 43: 990-996.

[3]

Andrea S, Vittorio Magnaghi. Durability of Epoxy Resin-Based Materials for the Repair of Damaged Cementitious Composites[J]. Cement and Concrete Research, 1999, 29: 95-98.

[4]

Gulnare A, Huseyin D, Ulku S, et al. Coating, Mechanical and Thermal Properties of Epoxy Toluene Oligomer Modified Epoxy Resin/Sepiolite Composites[J]. Progress in Organic Coatings, 2012, 75: 97-105.

[5]

Muhammad A, Rafique Bhutta. Effects of Polymer-cement Ratio and Accelerated Curing on Flexural Behavior of Hardener-free Epoxymodified Mortar Panels[J]. Materials and Structures, 2010, 43: 429-439.

[6]

Ohama Y, Demura K, Uchiyama T. Weatherability of Polymer Modified Mortars after Ten-Year Outdoor Exposure in Koriyama and Sappro, Polymer in Concrete[C]. Proc. of the Second East Asia Symp on Polymer in Concrete, 1997

[7]

Ohama Y, Demura K, Endo T. Properties of Polymer-Modified Mortars Using Epoxy Resin without Hardener, Polymer-Modified Hydraulic-Cement Mixtures[R], 1993

[8]

Jo YK. Development of Epoxy-Modified Mortar and Concrete without Hardener[D], 1995 Japan: Nihon University.

[9]

Jo YK, Soh YS. A Study on the Hardening of Epoxy Resin in Epoxy Modified Cementitious Composites[J]. J. Architect. Inst. Korea, 1996, 12: 238-247.

[10]

Jo Y K. Basic Properties of Epoxy Cement Mortars without Hardener after Outdoor Exposure[J]. Construction and Building Materials, 2008, 22: 911-920.

[11]

ZHU J, LI Z, YANG R, et al. Organic Additive Implantation onto Cement Hydration Products[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2014, 3: 527-533.

[12]

ZHU J, LI Z, YANG R, et al. Mutual Interaction Relationship in Polymer Modified Cementitious System[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2015, 1: 122-128.

[13]

Sabina A, Alberto S, Eugenio C, et al. Structural Investigation of E-Beam Cured Epoxy Resins Through Solid-state NMR[J]. Radiation Physics and Chemistry, 2012, 81: 1328-1331.

[14]

Benard F, Campistro I, Laguerre A, et al. Influence of Silica Fillers During the Electron Irradiations of DGEBA/TETA Epoxy Resins, Part I: Study of the Chemical Modication on Model Compounds[J]. Polymer Degradation and Stability, 2006, 91: 2110-2118.

[15]

Benard F, Buzare J Y, Campistron I, et al. Influence of Silica Fillers During the Electron Irradiation of DGEBA/TETA Epoxy Resins, Part III: Solid-state NMR Investigations[J]. Polymer Degradation and Stability, 2007, 92: 785-794.

AI Summary AI Mindmap
PDF

85

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/