Thermoplastic starch prepared with different plasticizers: Relation between degree of plasticization and properties

Yingfeng Zuo , Jiyou Gu , Haiyan Tan , Yanhua Zhang

Journal of Wuhan University of Technology Materials Science Edition ›› 2015, Vol. 30 ›› Issue (2) : 423 -428.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2015, Vol. 30 ›› Issue (2) : 423 -428. DOI: 10.1007/s11595-015-1164-z
Biomaterials

Thermoplastic starch prepared with different plasticizers: Relation between degree of plasticization and properties

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Abstract

Ethylene glycol, glycerol, sorbitol, formamide, and urea were used as plasticizers for the preparation of thermoplastic starch (TPS) from corn starch. The properties of TPS were tested by analysis method. The results showed that TPSs were more highly plasticized with amines than alcohols. For the same type of plasticizer, the degree of plasticization decreased as the molecular weight of plasticizer increased. The relationship between plasticization degree and TPS properties was characterized and described by mechanical properties and water absorption. The experimental results showed that when the degree of plasticization increased, the tensile strength decreased and the elongation at breakage and water absorption increased.

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corn starch / plasticizer / thermoplastics / degree of plasticization / properties

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Yingfeng Zuo, Jiyou Gu, Haiyan Tan, Yanhua Zhang. Thermoplastic starch prepared with different plasticizers: Relation between degree of plasticization and properties. Journal of Wuhan University of Technology Materials Science Edition, 2015, 30(2): 423-428 DOI:10.1007/s11595-015-1164-z

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References

[1]

Muscat D, Adhikari B, Adhikari R, et al. Comparative Study of Film Forming Behavior of Low and High Amylose Starches Using Glycerol and Xylitol as Plasticizers[J]. J. Food. Eng., 2012, 109(2): 189-201.

[2]

Zhang Y, Han JH. Plasticization of Pea Starch Films with Monosaccharides and Polyols[J]. J. Food. Sci., 2006, 71(6): 253-261.

[3]

Lu DR, Xiao CM, Xu SJ. Starch-based Completely Biodegradable Polymer Materials [J]. J. Polym. Sci. Polym. Lett., 2009, 3(6): 366-375.

[4]

Janjarasskul T, Krochta JM. Edible Packaging Materials [J]. Annu. Rev. Food. Sci. T., 2010, 1: 415-448.

[5]

Guilbert S, Cuq B, Contard N. Recent Innovations in Edible and/or Biodegradable Packaging Materials [J]. Food. Addit. Contam., 1997, 14(6–7): 741-751.

[6]

Laohakunjit N, Noomhorm A. Effect of Plasticizers on Mechanical and Barrier Properties of Rice Starch Film [J]. Starch/Starke, 2004, 56(8): 348-356.

[7]

Pareta R, Edirisinghe MJ. A Novel Method for the Preparation of Starch Films and Coatings[J]. Carbohyd. Polym., 2005, 63(3): 425-431.

[8]

Shogren RL, Swanson CL, Thompson AR. Extrudates of Cornstarch with Urea and Glycols: Structure/Mechanical Property Relations[J]. Starch/Starke, 1992, 44(9): 335-338.

[9]

Zheng PW, Chang PR, Yu JG, et al. Formamide and 2-Hydroxy-N-[2-(2-Hydroxy-Propionylamino)-Ethyl] Propionamide (HPEP) as a Mixed Plasticizer for Thermoplastic Starch[J]. Carbohyd. Polym., 2009, 78(2): 296-301.

[10]

Van Soest JJG, Knooren N. Influence of Glycerol and Water Content on the Structure and Properties of Extruded Starch Plastic Sheets during Aging[J]. J. Appl. Polym. Sci., 1996, 64(7): 1 411-1 422.

[11]

Ma XF, Yu JG. Thermoplastic Starch Plasticized by the Mixture of Urea and Formamide[J]. Acta. Polym. Sin., 2004, 4: 483-489.

[12]

Ogawa KZ, Aso KJ, Ono S, et al. Effects of the Noncyclic Cyanamides on the Retrogradation of Waxy Corn Starch[J]. B. Chem. Soc. Jpn., 2000, 73: 1 283-1 284.

[13]

Thomas MS, Richard VG. Amino Acids as Plasticizers for Starch-based Plastics[J]. Starch/starke, 1997, 49: 245-249.

[14]

Ma XF, Yu JG. Formamide as the Plasticizer for Thermoplastic Starch[J]. J. Appl. Polym. Sci., 2004, 93: 1 769-1 773.

[15]

Ma XF, Yu JG, Wan JJ. Urea and Ethanolamine as a Mixed Plasticizer for Thermoplastic Starch [J]. Carbohyd. Polym., 2006, 64: 267-273.

[16]

Van Soest JJG, Vliegenthart JFG. Crystallinity in Starch Plastics: Consequences for Material Properties [J]. Trends. Biotechnol., 1997, 15: 208-213.

[17]

Ma XF, Yu JG. Studies on the Properties of Formamide Plasticized-Thermoplastic Starch [J]. Acta. Polym. Sin., 2004, 2: 240-245.

[18]

Yao DM, He HZ. Thermoplastic Starch Plasticized by Mix of Urea and Glycerol[J]. Chem. Ind. Eng. Prog., 2011, 30(9): 2 018-2 020.

[19]

Tung CC, Ku TH, Lin CA. Study of the Plasticizer Effect and Characterization on Diverse Pseudo-Thermoplastic Starch Biodegradable Films[J]. Polym.-Plast. Technol., 2011, 50(3): 320-327.

[20]

Thomas AW, Donald AM, Heidelbach F. Analysis of the Native Structure of Starch Granules with Small Angle X-ray Microfocus Scattering[J]. Biopolymers, 1999, 49(1): 91-105.

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