PDF
Abstract
To study the influence of multi-wall carbon nanotubes (MWCNTs) on the mechanical and microstructural properties of cementitious composites, 0.00, 0.02, 0.08, 0.10, and 0.20 wt% of multi-wall carbon nanotubes were added into cement mortar, in which the cement-sand ratio was 1:1.5. The flexural and compressive strengths of cement mortar at the age of 3, 7, 28 and 90 d and the fracture performance at the age of 28 d were determined, its 2D micrograph was tested by means of SEM, and the 3D defects distribution was firstly determined with or without CNTs by means of XCT (X-ray computerized tomography). The results showed that 0.08 wt% of CNTs improved the compressive strength and flexural strength by 18% and 19%, respectively, and a significant improvement of its fracture property was observed. Moreover lower addition of carbon nanotubes to cement mortars can improve its microstructure and decrease the defects significantly compared to the cement mortar without CNTs. With the increase of the content of CNTs, the mechanical properties of cement mortars presented to be declined largely due to the agglomeration of CNTs.
Keywords
carbon nanotubes
/
cement mortar
/
mechanical properties
/
agglomeration
/
microstructure
/
XCT (X-ray computerized tomography)
Cite this article
Download citation ▾
Qiaoling Liu, Wei Sun, Hao Jiang, Caihui Wang.
Effects of carbon nanotubes on mechanical and 2D-3D microstructure properties of cement mortar.
Journal of Wuhan University of Technology Materials Science Edition, 2014, 29(3): 513-517 DOI:10.1007/s11595-014-0950-3
| [1] |
S I Helical Microtubes of Graphitic Carbon[J]. Nature, 1991, 354: 56-58.
|
| [2] |
Yu X, Kwon E A Carbon Canotube/Cement Composite with Piezoresistive Properties [J]. Smart Mater. Struct., 2009, 18: 1-5.
|
| [3] |
Li G Y, Wang P M, Zhao X Mechanical Behavior and Microstructure of Cement Composites Incorporating Surface-Treated Multi-Walled Carbon Nanotube [J]. Carbon, 2005, 43: 1 239-1 245.
|
| [4] |
Y A The Preparation of Carbon Nanotubes[J]. Fuel Sci. Technol., 1994, 2(2): 173-180.
|
| [5] |
Salvetat J P, Bonard J M, Thomson N H, . Mechanical Properties of Carbon Nanotubes [J]. Appl. Phys., 1999, 69(3): 255-260.
|
| [6] |
Maser W K, Benito A M, Martinez M T Production of Carbon Nanotubes the Light Approach [J]. Carbon, 2002, 40(10): 1 685-1 695.
|
| [7] |
Konsta-Gdoutos M S, Metaxa Z S, Shah S P Highly Dispersed Carbon Nanotube Reinforced Cement Based Materials[J]. Cem. Concr. Res., 2010, 40: 1 052-1 059.
|
| [8] |
Belytschko T, Xiao S P, Schatz G C, . Atomistic Simulations of Nanotube Fracture [J]. Phys. Rev., 2002, B65(23): 235 430-235 437.
|
| [9] |
Lau K T, Hui D The Revolutionary Creation of New Advanced Materials-Carbon Nanotube [J]. Compos., 2002, B33: 263-277.
|
| [10] |
Wei T, Fan Z, Luo G, . A New Structure for Multi-Walled Carbon Nanotubes Reinforced Alumina Nanocomposite with High Strength and Toughness [J]. Mater. Lett., 2008, 62: 641-644.
|
| [11] |
Zhu Y F, Shi L, Liang J, . Synthesis of Zirconia Nanoparticles on Carbon Nanotubes and Their Potential for Enhancing the Fracture Toughness of Alumina Ceramics[J]. Compos., 2008, B39: 1 136-1 141.
|
| [12] |
Lee H, Mall S, He P, . Characterization of Carbon Nanotube/Nanofiber-Reinforced Polymer Composites Using an Instrumented Indentation Technique [J]. Compos., 2007, B38: 58-65.
|
| [13] |
Esawia A M K, Morsi K, Sayed A, . Fabrication and Properties of Dispersed Carbon Nanotube-Aluminum Composites [J]. Mater. Sci. Eng., 2009, A508: 167-173.
|
| [14] |
Makar J M, Beaudoin J J Carbon Nanotubes and their Applications in the Construction Industry [C]. Proceedings of the First International Symposium on Nanotechnology in Construction, Paisley, Scotland, 2003
|
| [15] |
Chong K P, Garboczi E J Smart and Designer Structural Material Systems [J]. Prog. Struct. Mater. Eng., 2002, 4: 417-30.
|
| [16] |
Sanchez F, Sobolev K Nanotechnology in Concrete-A review [J]. Construction and Building Materials, 2010, 24: 2 060-2 071.
|
| [17] |
Makar J M, Margeson J, Luh J Carbon Nanotube/Cement Composites-Early Results and Potential Applications [C]. Proceedings of 3rd International Conference on Construction Materials: Performance, 2005 Vancouver Innovations and Structural Implications
|
| [18] |
Li G Y, Wang P M, Zhao X Pressure-Sensitive Properties and Microstructure of Carbon Nanotube Reinforced Cement Composites [J]. Cem. Concr. Compos., 2007, 29(5): 377-82.
|
| [19] |
Konsta-Gdoutos M S, Metaxa Z S, Shah S P Multi-Scale Mechanical and Fracture Characteristics and Early-Age Strain Capacity of High Performance Carbon Nanotube/Cement Nanocomposites [J]. Cem. Concr. Compos., 2010, 32(2): 110-115.
|
| [20] |
Chong K P, Garboczi E J Smart and Designer Structural Material Systems [J]. Prog. Struct. Mater. Eng., 2002, 4: 417-430.
|
| [21] |
Chaipanich A, Nochaiya T, Wongkeo W, . Compressive Strength and Microstructure of Carbon Nanotubes-Fly Ash Cement Composites [J]. Mater. Sci. Eng., 2010, A527: 1 063-1 067.
|
| [22] |
Nochaiya T, Tolkidtikul P, Singjai P, Chaipanich A Microstructure and Characterizations of Portland-Carbon Nanotubes Pastes [J]. Adv. Mater. Res., 2008, 55: 549-552.
|
| [23] |
Torkittikul P, Chaipanich A Bioactivity Properties of White Portland Cement Paste with Carbon Nanotubes [C]. Proceedings of INEC 2010 3rd International Nanoelectronics Conference, Hong Kong, 2010
|
| [24] |
Cwirzen A, Habermehl-Cwirzen K, Nasibulin A, . SEM/AFM Studies of Cementitious Binder Modified by MWCNT and Nano-Sized Fe Needles [J]. Mater. Char., 2008, 60: 753-760.
|
| [25] |
Shah S P, Konsta-Gdoutos M S, Metaxa Z S, . Nanoscale Modification of Cementitious Materials [C]. Nanotechnology in Construction: Proceedings of the NICOM 3 (3rd International Symposium on Nanotechnology in Construction), Prague, Czech Republic, 2009
|
| [26] |
Cwirzen A, Habermehl-Cwirzen K, Penttala V Surface Decoration of Carbon Nanotubes and Mechanical Properties of Cement/Carbon Nanotube Composites [J]. Adv. Cem. Res., 2008, 20(2): 65-73.
|
| [27] |
Saez de Ibarra Y, Gaitero J J, Erkizia E, . Atomic Force Microscopy and Nanoindentation of Cement Pastes with Nanotube Dispersions [J]. Phys. Status. Solidi., 2006, 203(6): 1 076-1 081.
|
| [28] |
Junrong Y, Grossiord N, Koning C E, . Controlling the Dispersion of Multi-Wall Carbon Nanotubes in Aqueous Surfactant Solution [J]. Carbon, 2007, 45(3): 618-623.
|
| [29] |
Hielscher T Ultrasonic Production of Nano-Size Dispersions and Emulsions [C]. Proceedings of 1st Workshop on NanoTechnology Transfer in Europe, Grenoble, France, 2006
|
| [30] |
Han J, Sun W, Pan G, . Application of X-ray Computed Tomography in Characterization Microstructure Changes of Cement Pastes in Carbonation Process[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2012, 27(2): 358-363.
|