A facile synthesis of carbon black fluid grafting by polyetheramine using neutralization reaction

Yanbing Wang; Chong Wei; Na Chen; Zhixiong Huang

doi:10.1007/s11595-014-0921-8

Journal of Wuhan University of Technology Materials Science Edition ›› 2014, Vol. 29 ›› Issue (2) : 357 -360. DOI: 10.1007/s11595-014-0921-8

Organic Materials

A facile synthesis of carbon black fluid grafting by polyetheramine using neutralization reaction

Yanbing Wang ¹^,²^,^{^a}
, Chong Wei ¹^,²
, Na Chen ¹^,²
, Zhixiong Huang ¹^,²

Author information +

History +

PDF

Abstract

Nanoscale ionic materials(NIMS) based on carbon black(CB) were prepared through a facile method. Firstly, CB was oxidized in the mixture of nitric acid and sulfuric acid, resulting in a large amounts of -COOH on surface of CB. Then oxidized CB was grafted by polyetheramine through neutralization reaction between -COOH of CB and -NH₂-of polyetheramine, and CB derivatives were obtained. This surface-functionalized CB can behave as liquid at ambient temperature in the absence of solvent by carefully varying the components. FTIR and thermaogravimetric analysis confirmed that the successively grafting of polyetheramine. TEM revealed the monodisperse core-shell structure of CB derivatives particles. The viscoelasticity of CB derivatives were closely related to the molecular weight and loading of polyetheramine. The unique core-shell and ionic structure and flowability of these CB derivatives could guide our future work on obtaining NIMs with tunable and controllable properties and broaden its commercial applications.

Keywords

carbon black / polyetheramine / core-shell / fluid

Cite this article

Download citation ▾

Yanbing Wang, Chong Wei, Na Chen, Zhixiong Huang. A facile synthesis of carbon black fluid grafting by polyetheramine using neutralization reaction. Journal of Wuhan University of Technology Materials Science Edition, 2014, 29(2): 357-360 DOI:10.1007/s11595-014-0921-8

登录浏览全文

4963

注册一个新账户忘记密码

References

Publishing order | Descend order by publishing year | Descend order by cited within

[1]	Xue P, Gao J, Wu Chifei An Analysis of Microstructural Variations in Carbon Black Modified by Oxidation or Ultrasound[J]. Carbon, 2011, 49: 3 346-3 355.

[2]	Bourlinos AB, Herrera R, Chalkias N Surface-Functionalized Nanoparticles with Liquid-like Behavior[J]. Advanced Materials, 2005, 17: 234-237.

[3]	Rodriguez R, Herrera R, Emmanuel P, Giannelis The Synthesis and Properties of Nanoscale Ionic Materials[J]. Applied Organometallic Chemistry, 2010, 24: 581-589.

[4]	Li Q, Dong L, FANF J, . Property-Structure Relationship of Nanoscale Ionic Materials based on Multiwalled Carbon Nanotubes[J]. ACS Nano, 2010, 4(5): 797-5 806.

[5]	Li Q, Dong L, Liu Y, . A Carbon Black Derivative with Liquid Behavior[J]. Carbon, 2011, 49(1): 1 047-1 051.

[6]	Li Q, Dong L, Deng W, . Solvent-free Fluids based on Rhombohedral Nanoparticles of Calcium Carbonate[J]. Journal of the American Chemical Society, 2009, 131(9): 148-9 149.