Lattice thermal transport in double-filled skutterudites In0.1Yb yCo4Sb12
Wei Xu , Jiangying Peng , Jian He , Menghan Zhou , Junyou Yang , Liangwei Fu
Journal of Wuhan University of Technology Materials Science Edition ›› 2013, Vol. 28 ›› Issue (4) : 677 -681.
Lattice thermal transport in double-filled skutterudites In0.1Yb yCo4Sb12
In order to investigate the phonon scattering mechanisms in double-filled skutterudites, the low-temperature lattice thermal conductivities of In0.1Yb yCo4Sb12 were measured and analyzed based on the Debye model. The eingenmode frequencies of In and Yb were obtained from low-temperature specific heat capacity analysis. It is found that filling these two types of guest atoms with different eingenmode frequencies into the voids in skutterudites could introduce strong point defect and resonant scattering to lattice phonons, thus lead to significant decrease in the lattice thermal conductivity.
thermoelectric / thermal conductivity / phonons
| [1] |
|
| [2] |
|
| [3] |
|
| [4] |
|
| [5] |
Mandrus D, Sales BC, Keppens V, et al. Thermoelectric Materials — New Directions and Approaches[M]. Edited by Tritt TM, Mahan G, Lyon HB Jr, and Kanatzidis MG, Materials Research Society Symposium Proceedings, 1997 |
| [6] |
|
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
|
| [11] |
|
| [12] |
|
| [13] |
|
| [14] |
|
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
|
| [19] |
|
| [20] |
|
| [21] |
|
| [22] |
|
| [23] |
|
| [24] |
|
| [25] |
|
| [26] |
|
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