Effect of the formation of CNTs on the reduction of ilmenite

Shenggao Wang , Wenbo Zhang , Kaiwei Xu , Mingyang Wang , Jianhua Wang , Jianjun Han , Xiujian Zhao , Weiguo Xu

Journal of Wuhan University of Technology Materials Science Edition ›› 2012, Vol. 27 ›› Issue (5) : 948 -951.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2012, Vol. 27 ›› Issue (5) : 948 -951. DOI: 10.1007/s11595-012-0579-z
Article

Effect of the formation of CNTs on the reduction of ilmenite

Author information +
History +
PDF

Abstract

The reduction process of ilmenite by hydrogen and methane under MPCVD was analyzed by XRD result. The reduction degree of ilmenite increased with adding methane, the case similar to reduction rate. The mechanism of reduction process changed with the increasement of methane flow because of the formation of carbon nanotubes (CNTs). The morphology of reduced samples was observed by SEM, and it was found that CNTs played an important role in the fracture of ilmenite particles. The reduction kinetics showed that the reduction was rate-controlling for hydrogen, and diffusion-controlling when hydrogen mixed with high flow methane.

Keywords

ilmenite / microwave plasma / carbon nanotube / reduction

Cite this article

Download citation ▾
Shenggao Wang, Wenbo Zhang, Kaiwei Xu, Mingyang Wang, Jianhua Wang, Jianjun Han, Xiujian Zhao, Weiguo Xu. Effect of the formation of CNTs on the reduction of ilmenite. Journal of Wuhan University of Technology Materials Science Edition, 2012, 27(5): 948-951 DOI:10.1007/s11595-012-0579-z

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Dewan A. R. M., Zhang G. Q., Ostrovsk O. Phase Development in Carbothermal Reduction of Ilmenite Concentrates and Synthetic Rutile[J]. ISIJ Int., 2010, 50(5): 647-653.

[2]

Chen Y., Hwang T., Marsh M., . Mechanically Activated Carbothermic Reduction of Ilmenite[J]. Metall. Mater. Trans. A, 1997, 28: 1 115-1 121.

[3]

EL-Guindy M. I., Davenport W. G. Kinetics and Mechanism of Ilmenite Reduction with Graphite[J]. Metall. Trans., 1970, 1: 1 729-1 734.

[4]

Wang Y. M., Yuan Z. F. Reduction Mechanism of Natural Ilmenite with Graphite[J]. Trans. Nonferrous Met. Soc., 2008, 18: 962-968.

[5]

Wang Y. M., Yuan Z. F. Reductive Kinetics of the Reaction Between a Natural Ilmenite and Carbon[J]. Int. J. Miner. Pro., 2006, 81: 133-140.

[6]

Wouterlood H. J. The Reduction of Ilmenite with Carbon[J]. J. Chem. Technol. Biotechnol., 1979, 29: 603-618.

[7]

Welham N. J. A Parametric Study of the Mechanically Activated Carbothermic Reduction of Ilmenite[J]. Miner. Eng., 1996, 9(12): 1 189-1 200.

[8]

Galgali R. K., Ray H. S., Chakrabarti A. K. A study on Carbothermic Reduction of Ilmenite Ore in Plasma Reactor[J]. Metall. Mater. Trans. B, 1998, 29: 1 175-1 180.

[9]

Wang S. G., Wang J. H., Ma Z. B., . Vertically Aligned Carbon Nanoutbes Grown on Geometrically Different Types of Surface[J]. Diam. Relat. Mater., 2003, 12(12): 2 175-2 177.

[10]

Mohammad Dewan A. R., Zhang G. Q., Ostrovsk O. Carbothermal Reduction of Primary Ilmenite Concentrate in Different Gas Atmospheres[J]. Metall. Mater. Trans. B, 2010, 41: 182-192.

[11]

Hua Y. X., Liu C. P. Microwave-assisted Carbothermic Reduction of Ilmenite[J]. Acta Metall. Sin., 1996, 9(3): 164-170.

AI Summary AI Mindmap
PDF

96

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/