Extraction of metals from boiler slag by sintering

Abstract

A new method of recycling aluminum and iron in boiler slag derived from plants that use coal as fuel was presented. The new method can integrate efficient extraction and reuse of the leached pellets together. An elemental analysis of aqueous solutions leached by sulfuric acid was conducted by the EDTA-Na₂-ZnCl₂ titration method, and the components and microstructures of the samples were examined by means of XRF, XRD and SEM. An aluminum extraction efficiency of 86.50% was achieved when the sintered pellets were leached using 4 mol·L⁻¹ H₂SO₄ with solid/liquid ratio(m/V) of 1:5 at 80 °C for 24 h. An iron extraction efficiency of 94.60% was achieved under the same condition for the maximum extraction efficiency of Al. The extraction efficiency of Al and Fe increased with temperature, leaching time and acidity. The concentration of alumina and iron hydroxide in the final product was determined to be 99.12% and 92.20% respectively. This product of alumina would be used directly for the production of metallic aluminum.

Keywords

boiler slag / Al extraction efficiency / Fe extraction efficiency / leaching / alumina

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