Effect of wet surface treated nano-SiO₂ on mechanical properties of polypropylene composite

Abstract

Nano-SiO₂/polypropylene composite was prepared by melt-blending process. The nano-SiO₂ particles were organized by wet process surface treatment with silane coupling agent KH-570. The effect of mass fraction of nano-SiO₂ particles and dosage of KH-570 on the toughening and strengthening of PP matrix were investigated based on the fractography of impact notch and the analysis of crystal structure by X-ray and dispersive structure of nano-SiO₂ by TEM. Results show that the impact and flexural strength and modulus of the composite are improved obviously with low loading of nano-SiO₂ (3 wt%–5 wt%), and the izod impact strength of PP increases twice with 4 wt% nano-SiO₂. The nano-SiO₂ particles treated can disperse into the matrix resin, which has evident heterogeneous nucleation effects on the crystallization of PP. The optimal toughening and strengthening effects of PP matrix can be obtained when the content of nano-SiO₂ and KH-570 are 4 wt% and 3 wt%, respectively.

Keywords

nano-SiO₂ / silane coupling agent / wet process surface treatment / polypropylene / mechanical properties

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