High frequency discharge plasma induced grafting of polystyrene onto titanium dioxide powder

Shaofeng Zhong , Qiongrong Ou , Yuedong Meng

Journal of Wuhan University of Technology Materials Science Edition ›› 2007, Vol. 22 ›› Issue (2) : 303 -306.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2007, Vol. 22 ›› Issue (2) : 303 -306. DOI: 10.1007/s11595-005-2303-8
Article

High frequency discharge plasma induced grafting of polystyrene onto titanium dioxide powder

Author information +
History +
PDF

Abstract

Grafting of polystyrene (PS) onto titanium dioxide powder was investigated. The graft polymerization reaction was induced by high frequency discharge produced N2 plasma treatment of the surfaces of titanium dioxide. IR, XPS and TGA results show that PS was grafted on the titanium dioxide powder. And the crystal structure of the titanium dioxide powder observed by XRD was unchanged after plasma treatment.

Keywords

high frequency discharge / plasma / titanium dioxide / graft polymerization / PS / surface modification

Cite this article

Download citation ▾
Shaofeng Zhong, Qiongrong Ou, Yuedong Meng. High frequency discharge plasma induced grafting of polystyrene onto titanium dioxide powder. Journal of Wuhan University of Technology Materials Science Edition, 2007, 22(2): 303-306 DOI:10.1007/s11595-005-2303-8

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Nussbaumer R. J., Caser W., Tervoort T., . Synthesis and Characterization of Surface-Modified Rutile Nanoparticles and Transparent Polymer Composites Thereof[J]. J. Nanopart. Res., 2002, 4: 319-323.

[2]

Diebold U. The Surface Science of Titanium Dioxide[J]. Surf. Sci.Rep., 2003, 48: 53-229.

[3]

Fujishima A., Rao T. N., Tryk D. A. Titanium Dioxide Photocatalysis[J]. J. Photoch. Photobio. C-Photoch. Rev., 2000, 1: 1-21.

[4]

Wang P., Zakeeruddin S. M., Comte P., . Enhance the Performance of Dye-Sensitized Solar Cells by Co-Grafting Amphiphilic Sensitizer and Hexadecylmalonic Acid on TiO2 Nanocrystals[J]. J. Phys. Chem. B, 2003, 107: 14336-14341.

[5]

Zhu M. F., Xing Q., He H. K., . Preparation of PA6/Nano Titanium Dioxide(TiO2) Composites and Their Spinnability[J]. Macromol. Symp., 2004, 210: 251-261.

[6]

Abboud M., Turner M., Duguet E., . PMMA-Based Composite Materials with Reactive Ceramic Fillers Part 1.—Chemical Modification and Characterisation of Ceramic Particles[J]. J. Mater. Chem., 1997, 7(8): 1527-1532.

[7]

Li D., Zhu S., Pelton R. H., . Flocculation of Dilute Titanium Dioxide Suspensions by Graft Cationic Polyelectrolytes[J]. Colloid Polym. Sci., 1999, 277: 108-114.

[8]

Marcinko S., Fadeev A. Y. Hydrolytic Stability of Organic Monolayers Supported on TiO2 and ZrO2[J]. Langmuir, 2004, 20: 2270-2273.

[9]

Frantz R., Granier M., Durand J. O., . Phosphonate Derivatives of Pyridine Grafted onto Oxide Nanoparticles[J]. Tetrahedron. Lett., 2002, 43: 9115-9117.

[10]

Sidorenko A., Minko S., Gafijchuk G., . Radical Polymerization Initiated from a Solid Substrate. 3. Grafting from the Surface of an Ultrafine Powder[J]. Macromolecules, 1999, 32: 4539-4543.

[11]

Lin J., Siddiqui J. A., Ottenbrite R. M. Surface Modification of Inorganic Oxide Particles with Silane Coupling Agent and Organic Dyes[J]. Polym. Adv.Technol., 2001, 12: 285-292.

[12]

Zan L., Liu Z. S., Zhong J. C., . Organic Modification on TiO2 Nanoparticles by Grafting Polymer[J]. J. Mater. Sci., 2004, 39: 3261-3264.

[13]

Kim J. W., Shim J. W., Bae J. H., . Titanium Dioxide/Poly(methyl methacrylate) Composite Microspheres Prepared by in Situ Suspension Polymerization and Their Ability to Protect against UV Rays[J]. Colloid. Polym. Sci., 2002, 280: 584-588.

[14]

McTaggart F. K. Plasma Chemistry in Electrical Discharges[M], 1970. Amsterdam: Elsevier. 218

[15]

Yasuda H. Plasma Polymerization[M], 1985. Boston: Academic Press. 75

[16]

Hudis M. Hollahan J. R., Bell A. T. Techniques and Applications of Plasma Chemistry, 1974. New York: Wiley. 489

[17]

Kuzuya M., Ishikawa M., Noguchi A., . Nature of Plasma-Induced Radicals on Cross-Linked Methacrylic Polymers Studied by Electron-Spin-Resonance[J]. J. Polym. Sci. Part A: Polym.Chem., 1992, 30(3): 379-387.

[18]

Zhang F., Kang E. T., Neoh K. G., . Surface Modification of Stainless Steel by Grafting of Poly(ethylene glycol) for Reduction in Protein Adsorption[J]. Biomaterials, 2001, 22(12): 1541-1548.

[19]

Tian J., Lin X., Huang B. T., . Plasma Induced Grafting of Styrene onto Nascent Polyethylene Powder[J]. Eur. Polym. J., 1995, 31(8): 755-760.

[20]

Iriyama Y., Ikeda S. Plasma-Induced Graft Polymerization onto Powders[J]. Polym.J., 1994, 26(1): 109-111.

[21]

Inagaki N., Tasaka S., Abe H. Surface Modification of Polyethylene Powder Using Plasma Reactor with Fluidized-Bed[J]. J. Appl. Polym. Sci., 1992, 46: 595-601.

[22]

Ou Q. R., Meng Y. D., Xu X., . Effect of Frequency on Emission of XeI* Excimer in a Pulsed Dielectric Barrier Discharge[J]. Chin.Phys.Lett., 2004, 21(7): 1317-1319.

[23]

Murata Y., Aradachi T. Change in Charging Characteristics of Polymer Powder by Plasma Treatment[J]. J. Electrostat., 2001, 51–52: 97-104.

[24]

Hirotsu T. Effects of Oxygen Exposure on Plasma Graft Polymerization of Some Hydrophilic Monomers onto Polypropylene Films[J]. J. Macromol. Sci.-Pure Appl. Chem., 1996, A33(11): 1663-1674.

[25]

Zan L., Tian L. H., Liu Z. S., . A New Polystyrene-TiO2 Nanocomposite Film and Its Photocatalytic Degradation[J]. Appl. Catal. A-Gen., 2004, 264: 237-242.

[26]

Kwon O. H., Nho Y. C., Chen J. Surface Modification of Polypropylene Film by Radiation-Induced Grafting and Its Blood Compatibility[J]. J. App. Polym. Sci., 2003, 88: 1726-1736.

[27]

Beamson G., Briggs D. The Scienta ESCA300 Database: High Resolution XPS of Organic Polymer[M], 1992. Chichester: John Wiley & Sons. 375

[28]

Ihara T., Miyoshi M., Ando M., . Preparation of a Visible-Light-Active TiO2 Photocatalyst by RF Plasma Treatment[J]. J. Mater. Sci., 2001, 36: 4201-4207.

AI Summary AI Mindmap
PDF

135

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/