Hydrothermal synthesis and characterization of inorganic/organic hybrid complex containing tungstophsphate

Jin Su-rong; Zhang Lian-meng; Liu Shi-zhong; Zhao Wei-feng

doi:10.1007/BF02841359

Journal of Wuhan University of Technology Materials Science Edition ›› 2004, Vol. 19 ›› Issue (4) : 21 -22. DOI: 10.1007/BF02841359

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Hydrothermal synthesis and characterization of inorganic/organic hybrid complex containing tungstophsphate

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Abstract

A new complex [Cu(C₁₂H₈N₂)₂]_1.5PW₁₂O₄₀·1.5H₂O was synthesized under hydrothermal conditions. The complex was characterized by the elemental analysis, SEM, X-ray powder diffraction analysis, IR, UV-Vis spectroscopy, and TG thermal analysis, respectively. The experimental result shows that the heteropolyanion is of a Keggin structure containing coordinated cations. Photochromism studies show that the electron transfer takes place from the organic compound to the heteropolyanion.

Keywords

polyoxometalate / hybrid / hydrothermal synthesis

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Jin Su-rong, Zhang Lian-meng, Liu Shi-zhong, Zhao Wei-feng. Hydrothermal synthesis and characterization of inorganic/organic hybrid complex containing tungstophsphate. Journal of Wuhan University of Technology Materials Science Edition, 2004, 19(4): 21-22 DOI:10.1007/BF02841359

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