The antioxidation properties of the in-situ ceramic from pyrolyzing polysilicone preceramic

Song Renyi , Zhang Lianmeng , Wang Jun , Qin Kai

Journal of Wuhan University of Technology Materials Science Edition ›› 2005, Vol. 20 ›› Issue (2) : 123 -126.

PDF
Journal of Wuhan University of Technology Materials Science Edition ›› 2005, Vol. 20 ›› Issue (2) : 123 -126. DOI: 10.1007/BF02838508
Article

The antioxidation properties of the in-situ ceramic from pyrolyzing polysilicone preceramic

Author information +
History +
PDF

Abstract

A systematic research on the pyrolysis process of polymethysilicone (SAR-2) and the thermostability of the pyrolysis residue was made by the thermogravimetric analysis, DTA and infrared spectroscopy. The experimental results indicate that the pyrolysis residue of SAR-2 converted into the amorphous SiCxO4−x phase above 900°C, the residue at 1200°C is the most thermostable and antioxidant. It is suitable to be used as polysilicone preceramic.

Keywords

polysilicone / preceramic / in-stu ceramic

Cite this article

Download citation ▾
Song Renyi, Zhang Lianmeng, Wang Jun, Qin Kai. The antioxidation properties of the in-situ ceramic from pyrolyzing polysilicone preceramic. Journal of Wuhan University of Technology Materials Science Edition, 2005, 20(2): 123-126 DOI:10.1007/BF02838508

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Jones R, Szweda A, Petrak D. Polymer Derived Ceramic Matrix Composites. Composite, Part A, 1999, 30: 569-575.

[2]

Sato K, Tezuka A, Aunayama O, Isoda T. Frabracation and Pressure Testing of a Gas-turbine Component Manufactured by a Preceramic Polymer Impregnation Method. Comp. Sci. Technol., 1999, 59: 853-859.

[3]

Yoshid H, Miyata N, Sagawa M, Ishikawa S. Preparation of Unidirectionally Reinforced Carbon-SiC Composite by Repeated Infiltration of Polycarbosilane. J. Ceram. Soc. Japan, 1992, 100: 454-458.

[4]

Camposotrini R, Dandrea G, Carturan G, Ceccato R. Pyrolysis Study of Methyl-substituted Si−H Containing Gels as Precursors for Oxycarbide Glasses by Combined Thermogravimetry, Gas Chromatographic and Mass Spectrometric Analysis. J. Mater. Chem., 1996, 6: 585-594.

[5]

Liu Q, Shi W, Babonnean F, Interrante L V. Synthesis of Polycarbonsilane/Silioxane Hybrid Polymers and Their pyrolytic Conversion to Silicone Oxycarbide Ceramics. Chem. Mater., 1997, 9: 2434-2341.

[6]

Colombo P, Ricardi B, Donato A. Joining of SiC/SiC Ceramic Matrix Composites for Fusion Reactor Blanket Applications. J. of Nuclear Materials, 2000, 278: 27-35.

[7]

Colombo P, Sglavo V. Joining of Reaction-bonded Silicone Carbide Using a Preceramic Polymer. J. of Mater. Sci., 1995, 33(2): 405-412.

[8]

Manocha L M, Satish Manocha M. Studies on Solution-derived Ceramic Coatings for Oxidation Protection of C/C Composites. Carbon, 1995, 33: 435-440.

[9]

Schiavon M A, Radovanovic E, Yoshida I V P. Microstructural Characterization of Monolithic Ceramic Matrix Composite from Polysiloxane and SiC Powder. Powder Technology, 2002, 123: 232-241.

[10]

Koo J H, Venumbaka S, Weispfenning J, Blackmon C. Silicone Matrix Composites for Thermal Protection. Inter. SAMPE Tech. Confer., 1999, 31: 163-176.

[11]

Koo J H, Venumbaka S, Miller M J, Wilson D, Beckley D A. Effects of Major Constituents on the Performance Silicone Polymer Composite. SAMPE Tech. Confer., 1998, 30: 117-126.

[12]

Soraru G D, Liu Q, Interrante L V. Apple. Role of Precursor Molecular Structure on the Microstructure and High Temperature Stability of Silicone Oxycarbide Glasses Derived from Methylene-bridged Polycarbosilanes. Chem. Mater., 1998, 10: 4047-4054.

[13]

Hubert Mutin P. Role of Redistribution Reactions in the Polymer Route to Silicon-carbon-oxygen Ceramics. J. Am. Ceram. Soc., 2000, 85(5): 1185-1189.

[14]

Bellamy I J. The Infra-red Spectra of Complex Molecules, 1978 3rd ed. London: Chapman and Hall.

[15]

Silverstein R M, Bassler G C, Morrill T C. Spectrometric Indentification of Compounds, 1981 4th ed. Wuhan: Wiley.

[16]

Anderson D R. Infro-red Raman and Ultraviolet Spectroscopy, Analysis of Silicones, 1981 Wuhan: Wiley.

[17]

Stevens N S M, Rezac M E. Nanoporous Organic/Inorganic Hybrid Materials Produced from Poly (Dimethy Silicone). Polymer, 1999, 4: 4289-4298.

AI Summary AI Mindmap
PDF

113

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/