Preparation of poly (ethylene oxide) (PEO) modified tungsten oxide hybrid filmsvia sol-gel processing

Yuan Jian , Shangguan Wenfeng , Liu Ming-zhi , Ouyang shi-xi

Journal of Wuhan University of Technology Materials Science Edition ›› 2003, Vol. 18 ›› Issue (1) : 4 -6.

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Journal of Wuhan University of Technology Materials Science Edition ›› 2003, Vol. 18 ›› Issue (1) : 4 -6. DOI: 10.1007/BF02835074
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Preparation of poly (ethylene oxide) (PEO) modified tungsten oxide hybrid filmsvia sol-gel processing

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Abstract

Poly (ethylene axide) (PEO) modified WO3 thin films were prepared on glass substrates with special temperature. The sol-gel transition proess was investigated by using DTA-TG, SEM and XRD. The electrochemical characteristic of the films was studied by cyclic voltmmetry measurement. The results show that PEO has heavy effects on the crystallization of WO3 during structure evolution because of the interaction between PEO and WO3. It increases the crystallization temperature of the gels and thus improves the electrochemical properties and cyclic life of WO3 film as electrochromic materials.

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sol-gel dipcoating films / electrochromic / PEO / WO3

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Yuan Jian, Shangguan Wenfeng, Liu Ming-zhi, Ouyang shi-xi. Preparation of poly (ethylene oxide) (PEO) modified tungsten oxide hybrid filmsvia sol-gel processing. Journal of Wuhan University of Technology Materials Science Edition, 2003, 18(1): 4-6 DOI:10.1007/BF02835074

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References

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C G Granqvist.Handbook of Inorganic Electrochromic Materials. Elsevier. 1995

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Faughnan B W, Crandall R S, Heyman P M. Electrochromic in WO3 Amorphous Films. RCA Rev., 1975, 36(1): 177-197.

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Surca A, Orel B. Sol-gel Hydrated Nicked Oxide Electrochromic Films: Optical, Spectrochemical and structure Properties. Journal of sol-gel Science and Technology, 1998, 13: 923-927.

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Pecquenard B, Lecacheux H, Castro-Garcia S. Electrochromic Properties of WO3 Thin Films. Journal of Sol-gel Science and Technology, 1997, 8: 743-749.

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