A novel green porous ceramics fabricated simply by utilizing both manganese slag and silicate tailings as raw materials at low temperature

Meng-ke Li , Zi-han Geng , Xin Xu , Xin-yi Cai , Yun Liu , Yue-hui Chen , Zhi-min You , Jing Guo , Jun Wang , Bao-jun Yang

Journal of Central South University ›› 2026, Vol. 33 ›› Issue (4) : 1541 -1552.

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Journal of Central South University ›› 2026, Vol. 33 ›› Issue (4) :1541 -1552. DOI: 10.1007/s11771-026-6265-7
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A novel green porous ceramics fabricated simply by utilizing both manganese slag and silicate tailings as raw materials at low temperature
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Abstract

A porous wollastonite ceramic with high porosity and low density has been successfully fabricated at low temperature with silicate tailings and electrolytic manganese slag (MS) as primary raw materials in this study. The influences of calcination temperature, SiC, and MS addition amounts on porosity, water adsorption, pore size distribution, bulk density, and bending strength were systematically studied. The results showed that 0.4 wt% of SiC was optimal for the ceramic foaming at a sintering temperature of 1140 °C. The porosity of ceramics reduced from 78.4% to 63.7%, bulk density elevated from 0.96 to 1.13 g/cm3, and bending strength increased from 8.43 to 11.22 MPa as the MS increased from 8.33 wt% to 41.67 wt%. Moreover, the best corrosion resistance performance reached to 99.55% with 8.33 wt% MS content and a sintering temperature of 1160 °C. This work is of significance for the solid waste utilization.

Keywords

low temperature / manganese slag / porous ceramics / silicate tailings

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Meng-ke Li, Zi-han Geng, Xin Xu, Xin-yi Cai, Yun Liu, Yue-hui Chen, Zhi-min You, Jing Guo, Jun Wang, Bao-jun Yang. A novel green porous ceramics fabricated simply by utilizing both manganese slag and silicate tailings as raw materials at low temperature. Journal of Central South University, 2026, 33 (4) : 1541-1552 DOI:10.1007/s11771-026-6265-7

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References

[1]

Thomsen L, Jensen L R, Yue Y-z, et al.. Crystallinity dependence of thermal and mechanical properties of glass-ceramic foams [J]. Journal of the European Ceramic Society, 2024, 44(13): 7936-7942.

[2]

Ma Z-y, Zeng J-y, Chu S-z, et al.. Effect of different foam stabilizers on the setting behavior and pore characteristics of CAC-bonded Al2O3 foamed ceramics [J]. Ceramics International, 2023, 49(7): 10574-10579.

[3]

Deng F-q, Wang F, Shi X-p, et al.. Synthesis and properties of foam glass-ceramics from granite tailings by using SiC and MnO2 as the mixed foaming agent [J]. Ceramics International, 2023, 49(22): 34647-34656.

[4]

Taurino R, Martinuzzi S, Padovano E, et al.. Laser additive manufacturing of Al2O3 and ZrO2-based eutectic ceramic oxide: An overview [J]. Journal of the European Ceramic Society, 2025, 45(5): 117133.

[5]

Sun H, He B-c, Xu H-x, et al.. Experimental investigation on the fracture conductivity behavior of quartz sand and ceramic mixed proppants [J]. ACS Omega, 2022, 7(12): 10243-10254.

[6]

Xing Z-h, Hu Y-h, Xiang D-p, et al.. Porous SiC-mullite ceramics with high flexural strength and gas permeability prepared from photovoltaic silicon waste [J]. Ceramics International, 2020, 46(1): 1236-1242.

[7]

Xi C-p, Zhou J-m, Zheng F, et al.. Conversion of extracted titanium tailing and waste glass to value-added porous glass ceramic with improved performances [J]. Journal of Environmental Management, 2020, 261: 110197.

[8]

Jiang L, Sun H-j, Peng T-j, et al.. Comprehensive evaluation of environmental availability, pollution level and leaching heavy metals behavior in non-ferrous metal tailings [J]. Journal of Environmental Management, 2021, 290: 112639.

[9]

Su C-x, Rana N M, Zhang S, et al.. Environmental pollution and human health risk due to tailings storage facilities in China [J]. Science of the Total Environment, 2024, 928: 172437.

[10]

Li Z-y, Wang J, She Z-x, et al.. Tailings particle size effects on pollution and ecological remediation: A case study of an iron tailings reservoir [J]. Journal of Hazardous Materials, 2024, 476: 135024.

[11]

Huang Q-x, Liu T-y, Zhang J-s, et al.. Properties and pore-forming mechanism of silica sand tailing-steel slag-coal gangue based permeable ceramics [J]. Construction and Building Materials, 2020, 253: 118870.

[12]

Hu N-y, Fu F-h, Luo B-y, et al.. Preparation, characterization and self-foaming mechanism of total-tailings-based foamed glass-ceramics [J]. Ceramics International, 2023, 49(19): 31881-31890.

[13]

Chen R-y, Hei D-q, Li S-j, et al.. Environment-oriented low-cost Al2O3 ceramics with hierarchical pore structure fabricated from SiC solid waste [J]. International Journal of Applied Ceramic Technology, 2020, 17(1): 184-189.

[14]

Li L-l, Cao G-y, Zhao R-m, et al.. High-porosity whisker-mullite/corundum membrane support prepared from recycled industrial waste coal cinder [J]. Ceramics International, 2020, 46(4): 4086-4094.

[15]

Fu F-h, Hu N-y, Ye Y-c, et al.. Production of lightweight foam ceramics by adjusting sintering time and heating rate [J]. Construction and Building Materials, 2023, 394: 132063.

[16]

Li M-k, Huang F-l, Hu L, et al.. Efficient activation of peroxymonosulfate by a novel catalyst prepared directly from electrolytic manganese slag for degradation of recalcitrant organic pollutes [J]. Chemical Engineering Journal, 2020, 401: 126085.

[17]

Huang Y-j, Zhang C-p, Lu J-x, et al.. Performance improvement of glass-based lightweight aggregates through thermodynamic modelling design and lightweight mortar validation [J]. Cement and Concrete Composites, 2024, 152: 105662.

[18]

Ouyang D-x, Zhuo Y-t, Hu L, et al.. Research on the adsorption behavior of heavy metal ions by porous material prepared with silicate tailings [J]. Minerals, 2019, 9(5): 291.

[19]

Hou Z-p, Cui B-x, Liu L-l, et al.. Effect of the different additives on the fabrication of porous Kaolin-based mullite ceramics [J]. Ceramics International, 2016, 42(15): 17254-17258.

[20]

Zhao L-h, Li Y, Zhang L-l, et al.. Effects of CaO and Fe2O3 on the microstructure and mechanical properties of SiO2–CaO–MgO–Fe2O3 ceramics from steel slag [J]. ISIJ International, 2017, 57(1): 15-22.

[21]

Li Z, Li X, Tang Y, et al.. Sintering behaviour and characterisation of low-cost ceramic foams from coal gangue and waste quartz sand [J]. Advances in Applied Ceramics, 2016, 115(7): 377-383.

[22]

Ding L-f, Ning W, Wang Q-w, et al.. Preparation and characterization of glass – ceramic foams from blast furnace slag and waste glass [J]. Materials Letters, 2015, 141: 327-329.

[23]

Zhou X-y, Zheng F, Li H-g, et al.. An environment-friendly thermal insulation material from cotton stalk fibers [J]. Energy and Buildings, 2010, 42(7): 1070-1074.

[24]

Jiang L-min. Heat treatment parameters of preparing glass-ceramic with electrolytic manganese residue and their properties [J]. Journal of Thermal Analysis and Calorimetry, 2020, 140(4): 1737-1744.

[25]

Wang Z-m, Lyu X-j, Yao G, et al.. Preparation of Ca – Si – Al – Mg porous ceramics by cooperation of Ca&Mg-contained soda residue and altered rock gold tailings [J]. Journal of Cleaner Production, 2020, 262: 121345.

[26]

Zhang J-s, Liu T-y, Huang Q-x, et al.. Preparation, properties characterization and structure formation mechanism of silica sand tailings-based ceramic materials [J]. Materials Chemistry and Physics, 2020, 255: 123611.

[27]

Ren B, Li Y-w, Sang S-b, et al.. Lightweight design of bauxite-SiC composite refractories as the lining of rotary cement kiln using alternative fuels [J]. Ceramics International, 2017, 43(14): 11048-11057.

[28]

Li L-x, Chai W, Kang J, et al.. Utilization of graphite tailings and coal gangue in the preparation of foamed ceramics [J]. International Journal of Applied Ceramic Technology, 2025, 22(3): e15012.

[29]

Topateş G. Direct production of Si3N4 foams by carbothermal reduction and nitridation of SiO2 [J]. Ceramics International, 2018, 44(16): 20545-20550.

[30]

Dong Y-c, Hampshire S, Zhou J-e, et al.. Recycling of fly ash for preparing porous mullite membrane supports with titania addition [J]. Journal of Hazardous Materials, 2010, 180(1–3): 173-180.

[31]

Ma B-y, Su C, Ren X-m, et al.. Preparation and properties of porous mullite ceramics with high-closed porosity and high strength from fly ash via reaction synthesis process [J]. Journal of Alloys and Compounds, 2019, 803: 981-991.

[32]

Han Y, Zhou L-j, Liang Y-x, et al.. Fabrication and properties of silica/mullite porous ceramic by foam-gelcasting process using silicon kerf waste as raw material [J]. Materials Chemistry and Physics, 2020, 240: 122248.

[33]

Kyono A, Ikeda R, Takagi S, et al.. Structural evolution of gypsum (CaSO4·2H2O) during thermal dehydration [J]. Journal of Mineralogical and Petrological Sciences, 2022, 117(1): 220811.

[34]

Liu W-t, Zhang H-t, Zhang B-n, et al.. New insight into non-isothermal kinetics of oxidation of SiC powders: The effect of particle size [J]. Applied Physics A, 2025, 131(9): 673.

[35]

Darabian L M, Gonçalves G R, Schettino M A, et al.. Synthesis of nanostructured iron oxides and study of the thermal crystallization process using DSC and in situ XRD experiments [J]. Materials Chemistry and Physics, 2022, 285: 126065.

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