Exploring the evolution of texture and properties of ultrafine copper wire during high strain drawing process

Jin-song Liu , Yan Zhou , Song-wei Wang , Shuai-feng Chen , Hong-wu Song , Shi-hong Zhang

Journal of Central South University ›› 2025, Vol. 32 ›› Issue (6) : 1973 -1994.

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Journal of Central South University ›› 2025, Vol. 32 ›› Issue (6) : 1973 -1994. DOI: 10.1007/s11771-025-5896-4
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Exploring the evolution of texture and properties of ultrafine copper wire during high strain drawing process

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Abstract

The ultrafine copper wire with a diameter of 18 µm is prepared via cold drawing process from the single crystal downcast billet (Φ8 mm), taking a drawing strain to 12.19. In this paper, in-depth investigation of the microstructure feature, texture evolution, mechanical properties, and electrical conductivity of ultrafine wires ranging from Φ361 µm to Φ18 µm is performed. Specially, the microstructure feature and texture type covering the whole longitudinal section of ultrafine wires are elaborately characterized. The results show that the average lamella thickness decreases from 1.63 µm to 102 nm during the drawing process. Whereas, inhomogeneous texture evolution across different wire sections was observed. The main texture type of copper wires are components of <111>, <001> and <112> orientations. Specifically, the peripheral region is primarily dominated by <111> and <112>, while the central region is <001> and <111>. As the drawing strain increases, the volume fraction of hard orientation <111> with low Schmid factor increase, where notably higher fraction of <111> is result from the consumption of <112> and <001> for the wire of Φ18 µm. For drawn copper wire of 18 µm, superior properties are obtained with a tensile strength of 729.8 MPa and an electrical conductivity of 86.9% IACS. Furthermore, it is found that grain strengthening, dislocation strengthening, and texture strengthening are three primary strengthening mechanisms of drawn copper wire, while the dislocation density is main factor on the reducing of conductivity.

Keywords

Copper wires / ultrafine wire / drawing / texture evolution / tensile strength

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Jin-song Liu, Yan Zhou, Song-wei Wang, Shuai-feng Chen, Hong-wu Song, Shi-hong Zhang. Exploring the evolution of texture and properties of ultrafine copper wire during high strain drawing process. Journal of Central South University, 2025, 32(6): 1973-1994 DOI:10.1007/s11771-025-5896-4

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References

[1]

ChenC-H, LeeP I, ChuangT H. Microstructure evolution and failure mechanism of electromigration in Ag-alloy bonding wire [J]. Journal of Alloys and Compounds, 2022, 913165266

[2]

BreitlingH M, HummelR E. Electromigration in thin silver, copper, gold, indium, tin, lead and magnesium films [J]. Journal of Physics and Chemistry of Solids, 1972, 33(4): 845-852

[3]

LiuP-S, TongL-Y, WangJ-L, et al.. Challenges and developments of copper wire bonding technology [J]. Microelectronics Reliability, 2012, 52(6): 1092-1098

[4]

ZhongZ-W. Wire bonding using copper wire [J]. Microelectronics International, 2009, 26(1): 1048-1058

[5]

LuL, ShenY-F, ChenX-H, et al.. Ultrahigh strength and high electrical conductivity in copper [J]. Science, 2004, 304(5669): 422-426

[6]

KimK S, SongJ P, ChungE K, et al.. Relationship between mechanical properties and microstructure of ultrafine gold bonding wires [J]. Mechanics of Materials, 2006, 38(1): 119-127

[7]

ZhouH-L, ChangA-D, FanJ-L, et al.. Copper Wire Bonding: A review [J]. Micromachines, 2023, 1481612

[8]

ChenJ, MaX-G, YanW, et al.. Effect of transverse grain boundary on microstructure, texture and mechanical properties of drawn copper wires [J]. Journal of Materials Science & Technology, 2014, 30(2): 184-191

[9]

LiX, ZhouY-J, SongK-X, et al.. Effect of cold drawing deformation on microstructure and properties of single crystal copper prepared by heated-mold horizontal continuous casting [J]. Transactions of Materials and Heat Treatment, 2022, 43(7): 46-52(in Chinese)

[10]

GuJ-H, ZhangX-B, ZhouY-J, et al.. Effect of drawing deformation on microstructure and properties of Cu-4 mass% Ag alloy wire [J]. Transactions of Materials and Heat Treatment, 2023, 44(7): 65-73(in Chinese)

[11]

ChangY Q, KongL W, ZhuX L, et al.. Investigation on the strengthening behaviour of micro-scale copper fiber [J]. Materials Science & Engineering, A, 2022, 859144186

[12]

WuH-J, HuangT, SongK-X, et al.. Effect of large deformation on microstructure and properties of copper alloy wire[J]. Journal of Materials Research and Technology, 2024, 29: 5136-5148

[13]

HouJ P, LiR, WangQ, et al.. Three principles for preparing Al wire with high strength and high electrical conductivity [J]. Journal of Materials Science & Technology, 2019, 35(5): 742-751

[14]

WangL-J, SongK-X, WangQ, et al.. Effects of drawing deformation on microstructures and properties of pure copper wires with different diameters [J]. Journal of Henan University of Science and Technology: Natural Science, 2013, 34(3): 14-17(in Chinese)

[15]

ChenJ, YanW, LiW, et al.. Fan. Texture evolution and its simulation of cold drawing copper wires produced by continuous casting [J]. Transactions of Nonferrous Metals Society of China, 2011, 21(1): 152-158

[16]

ChenJ, YanW, LiuC X, et al.. Dependence of texture evolution on initial orientation in drawn single crystal copper [J]. Materials Characterization, 2011, 62(2): 237-242

[17]

ChenJ, YanW, DingR G, et al.. Dislocation boundaries in drawn single crystal copper wires produced by Ohno continuous casting [J]. Journal of Materials Science, 2009, 4481909

[18]

LiX, ZhouY-J, LiuY-H, et al.. Microstructure evolution of high-strength and ultra-high-conductivity microfilament wire prepared by continuous deformation of single-crystal copper [J]. Journal of Materials Science, 2022, 57: 20895-20908

[19]

GuoS, HeY-M, LiuD-B, et al.. Geometrically necessary dislocations induced size effect in the torsional stress relaxation behavior of thin metallic wires [J]. Scripta Materialia, 2019, 173: 129-133

[20]

ShigematsyT, MoritaK, FujiiY, et al.. Investigation of annealing effects of ultra pure copper [J]. Cryogenics, 1992, 32(10): 913-915

[21]

WangJ, LiN, MisraA. Structure and stability of Σ3 grain boundaries in face centered cubic metals [J]. Philosophical magazine, 2013, 93(4): 315-327

[22]

ChoJ H, OnmsesK H, RollettA D, et al.. Investigation of recrystallization and grain growth of copper and gold bonding wires [J]. Metall Mater Trans A, 2006, 10: 3085-3097

[23]

ZhangY, LiS Y, TaoR N, et al.. High strength and high electrical conductivity in bulk nanograined Cu embedded with nanoscale twins [J]. Applied Physics Letters, 2007, 91(21): 211901-1-211901-3

[24]

SaldanaC, KingA H, ChandrasekarS. Thermal stability and strength of deformation microstructures in pure copper [J]. Acta Materialia, 2012, 60(10): 4107-4116

[25]

ZhangY, WangJ-T, ChengC, et al.. Stored energy and recrystallization temperature in high purity copper after equal channel angular pressing [J]. Journal of Materials Science, 2008, 43(23): 7326-7330

[26]

LiuL, BakerI. The dependence of recrystallization temperature and stored energy on rolling strain in polycrystalline copper [J]. Scripta Metallurgica Et Materialia, 1993, 28(2): 197-200

[27]

HuangK, LogeR E. A review of dynamic recrystallization phenomena in metallic materials [J]. Materials & Design, 2016, 111: 548-574

[28]

YangF, DongL-M, CaiL, et al.. Effect of cold drawing strain on the microstructure, mechanical properties and electrical conductivity of low-oxygen copper wires [J]. Materials Science & Engineering, A, 2021, 818141348

[29]

PopovaE N, PopovV V, RomanovN E, et al.. Effect of deformation and annealing on texture parameters of composite Cu-Nb wire [J]. Scripta Materialia, 2004, 51(7): 727-731

[30]

LiX, ZhouY-J, LiuY-H, et al.. Texture evolution and its influence mechanism on properties of single crystal copper and polycrystalline copper during cumulative deformation [J]. Journal of Materials Research and Technology, 2023, 24: 6808-6819

[31]

ShatzkesM, ChaudhariP, LeviA A, et al.. Twin boundary resistivity: Application to silver [J]. Physical review B, 1973, 7(12): 5058-5062

[32]

DasharathS M, KochC C, MulaS. Effect of stacking fault energy on mechanical properties and strengthening mechanisms of brasses processed by cryorolling [J]. Materials Characterization, 2015, 110: 14-24

[33]

GrumJ. Book review: mechanical behavior of materials by M. A. Meyers and K. K. Chawla [J]. International Journal of Microstructure and Materials Properties, 2009, 4686

[34]

ZhangZ F, WangZ G. Effects of grain boundaries on cyclic deformation behavior of copper bicrystals and columnar crystals [J]. Acta Materialia, 1998, 46(14): 5063-5072

[35]

BettinaliL, TostiS, PizzutoA. Mechanical and electrical properties of cryo-worked Cu [J]. Journal of Low Temperature Physics, 2014, 174(1): 64-752

[36]

MeyersM A, MishraA, BensonD J. Mechanical properties of nanocrystalline materials [J]. Progress in Materials Science, 2006, 51(4): 427-556

[37]

GubiczaJ, ChinhN Q, LábárJ L, et al.. Correlation between microstructure and mechanical properties of severely deformed metals [J]. Journal of Alloys and Compounds, 2009, 483(1): 271-2742

[38]

RodriguezC, FerrerN, CabreraJ M. Analysis of microstructure and strengthening in CuMg alloys deformed by equal channel angular pressing [J]. Journal of Alloys & Compounds, 2015, 626: 340-348

[39]

ZhangP-F, ZhouY-J, SongK-X, et al.. Effect of cold drawing deformation on microstructure and properties of Cu-20 mass% Ag alloy wire [J]. Transactions of Materials and Heat Treatment, 2022, 43(4): 81-88(in Chinese)

[40]

WangX, LiZ, MengX-P, et al.. Ultrahigh strength and improved electrical conductivity in an aging strengthened copper alloy processed by combination of equal channel angular pressing and thermomechanical treatment [J]. Journal of Central South University, 2024, 31(6): 1823-1837

[41]

MaoQ-Z, ZhangY-S, GuoY-Z, et al.. Enhanced electrical conductivity and mechanical properties in thermally stable fine-grained copper wire [J]. Communications Materials, 2021, 2(1): 1-9

[42]

ChengC, SongK-X, MiX-J, et al.. Microstructural evolution and properties of Cu-20 wt% Ag alloy wire by multi-pass continuous drawing[J]. Nanotechnology Reviews, 2020, 9(1): 1359-1367

[43]

CHEN Bing, LI Su-zhi, DING Jun, et al. Correlating dislocation mobility with local lattice distortion in refractory multi-principal element alloys [J]. Scripta Materialia, 2023, 222. DOI: https://doi.org/10.1016/j.scriptamat.2022.115048.

[44]

SunP-F, LiZ-W, HouJ-P, et al.. Quantitative study on the evolution of microstructure, strength, and electrical conductivity of the annealed oxygen-free copper wires [J]. Advanced Engineering Materials, 2022, 2492200037

[45]

WaryobaD R, KaluP N, RollettA D. The role of orientation pinning in statically recrystallized oxygen-free high-conductivity copper wire [J]. Metallurgical and Materials Transactions A, 2005, 36: 205-215

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