Tailoring the microstructure of bamboo-derived hard carbon to realize high sodium storage

Abstract

Hard carbon is regarded as a promising anode material for sodium-ion batteries, while it remains a huge challenge to initial coulombic efficiency and rate performance. Numerous studies show that critical structural features in hard carbon, namely defects, crystallites, and close pores, are directly responsible for the electrochemical performance in sodium-ion batteries. Here, we employ bamboo-derived hard carbon to systematically regulate the defects and crystallites in hard carbon by introducing mechanical activation. Benefiting from ball milling, the intermediate product with a high specific area more easily transforms into hard carbon, which possesses abundant closed pores, effective interlayer spacing, and suitable sodium storage defects, helping to improve the sodium ion storage performance. As a result, the hard carbon ball milled for 20 min presents a high reversible capacity of 315.2 mA·h/g at 17.5 mA/g with an initial coulombic efficiency up to 79.3%, as well as good rate and cycling performances.

References

[1] Zhao C-l, Wang Q-d, Yao Z-p, et al.. Rational design of layered oxide materials for sodium-ion batteries [J]. Science, 2020, 370(6517): 708-711.

[2] Huang Y-j, Zhong X, Hu X-y, et al.. Rationally designing closed pore structure by carbon dots to evoke sodium storage sites of hard carbon in low-potential region [J]. Advanced Functional Materials, 2024, 34(4): 2308392.

[3] Peng T, Luo Y-h, Tang L-b, et al.. MoSe₂@N, P-C composites for sodium ion battery [J]. Journal of Central South University, 2022, 29(9): 2991-3002.

[4] Xu R, Sun N, Zhou H-y, et al.. Hard carbon anodes derived from phenolic resin/sucrose cross-linking network for high-performance sodium-ion batteries [J]. Battery Energy, 2023, 2(2): 20220054.

[5] Ma X-d, Ji C, Li X-k, et al.. Red@black phosphorus core - shell heterostructure with superior air stability for high-rate and durable sodium-ion battery [J]. Materials Today, 2022, 59: 36-45.

[6] Hou Z-d, Jiang M-w, Lei D, et al.. Regulation of pseudographitic carbon domain to boost sodium energy storage [J]. Nano Research, 2024, 17(6): 5188-5196.

[7] Qiu G-j, Ning M, Zhang M-l, et al.. Flexible hard-soft carbon heterostructure based on mesopore confined carbonization for ultrafast and highly durable sodium storage [J]. Carbon, 2023, 205: 310-320.

[8] Zhao R, Sun N, Xu Bin. Recent advances in heterostructured carbon materials as anodes for sodium-ion batteries [J]. Small Structures, 2021, 2(12): 2100132.

[9] Chu Y, Zhang J, Zhang Y-b, et al.. Reconfiguring hard carbons with emerging sodium-ion batteries: A perspective [J]. Advanced Materials, 2023, 35(31): e2212186.

[10] Chen R, Li X-y, Cai C-c, et al.. Amine-aldehyde condensation-derived N-doped hard carbon microspheres for high-capacity and robust sodium storage [J]. Small, 2023, 19(44): e2303790.

[11] Kubota K, Shimadzu S, Yabuuchi N, et al.. Structural analysis of sucrose-derived hard carbon and correlation with the electrochemical properties for lithium, sodium, and potassium insertion [J]. Chemistry of Materials, 2020, 32(7): 2961-2977.

[12] Meng Q-s, Lu Y-x, Ding F-x, et al.. Tuning the closed pore structure of hard carbons with the highest Na storage capacity [J]. ACS Energy Letters, 2019, 4(11): 2608-2612.

[13] Wang J, Li Y-s, Liu P, et al.. Green large-scale production of N/O-dual doping hard carbon derived from bagasse as high-performance anodes for sodium-ion batteries [J]. Journal of Central South University, 2021, 28(2): 361-369.

[14] Zhang X-h, Han R-y, Liu Y-z, et al.. Porous and graphitic structure optimization of biomass-based carbon materials from 0D to 3D for supercapacitors: A review [J]. Chemical Engineering Journal, 2023, 460: 141607.

[15] Wang H, Liu S-t, Lei C, et al.. Ammonium polyphosphate assisted thermal polymerization of preoxidized asphalt to prepare N/P double-doped hard carbon for improved sodium ion storage [J]. Journal of Energy Storage, 2024, 85: 111045.

[16] Kamiyama A, Kubota K, Igarashi D, et al.. MgO-template synthesis of extremely high capacity hard carbon for Na-ion battery [J]. Angewandte Chemie (International Ed), 2021, 60(10): 5114-5120.

[17] Zheng J-q, Guan C-h, Li H-x, et al.. Unveiling the microscopic origin of irreversible capacity loss of hard carbon for sodium-ion batteries [J]. Advanced Energy Materials, 2024, 14(15): 2303584.

[18] Xu T-y, Qiu X, Zhang X, et al.. Regulation of surface oxygen functional groups and pore structure of bamboo-derived hard carbon for enhanced sodium storage performance [J]. Chemical Engineering Journal, 2023, 452: 139514.

[19] Chen L, Bai L-l, Yeo J, et al.. Wood-derived carbon with selectively introduced C = O groups toward stable and high capacity anodes for sodium storage [J]. ACS Applied Materials & Interfaces, 2020, 12(24): 27499-27507.

[20] Cheng D-j, Zhou X-q, Hu H-y, et al.. Electrochemical storage mechanism of sodium in carbon materials: A study from soft carbon to hard carbon [J]. Carbon, 2021, 182: 758-769.

[21] Zhong W-h, Cheng D-j, Zhang M-l, et al.. Boosting ultrafast and durable sodium storage of hard carbon electrode with graphite nanoribbons [J]. Carbon, 2022, 198: 278-288.

[22] Shi L, Sun Y-d, Liu W, et al.. Tailoring the microstructure and solid electrolyte interface of hard carbon to realize high-initial-coulombic-efficiency and high-rate sodium storage [J]. Electrochimica Acta, 2023, 459: 142557.

[23] Wang J, Yan L, Liu B-h, et al.. A solvothermal pre-oxidation strategy converting pitch from soft carbon to hard carbon for enhanced sodium storage [J]. Chinese Chemical Letters, 2023, 34(4): 107526.

[24] Smith M W, Pecha B, Helms G, et al.. Chemical and morphological evaluation of chars produced from primary biomass constituents: Cellulose, xylan, and lignin [J]. Biomass and Bioenergy, 2017, 104: 17-35.

[25] Ning M, Wen J-j, Duan Z-h, et al.. Edge graphitized oxygen-rich carbon based on stainless steel-assisted high-energy ball milling for high-capacity and ultrafast sodium storage [J]. Small, 2023, 19(34): 2301975.

[26] Xing T, Li L-h, Hou L-t, et al.. Disorder in ball-milled graphite revealed by Raman spectroscopy [J]. Carbon, 2013, 57: 515-519.

[27] Zhang S, Cui Y-h, Wu B, et al.. Control of graphitization degree and defects of carbon blacks through ball-milling [J]. RSC Advances, 2014, 4(1): 505-509.

[28] Lin J-h, Zhou Q-f, Liao Z-s, et al.. Steric hindrance engineering to modulate the closed pores formation of polymer-derived hard carbon for highperformance sodium-ion batteries [J]. Angewandte Chemie (International Ed), 2024, 63(39): e202409906

[29] Tang Z, Zhou S-y, Wu P-f, et al.. Engineering surface oxygenated functionalities on commercial hard carbon toward superior sodium storage [J]. Chemical Engineering Journal, 2022, 441: 135899.

[30] Wang Q-q, Zhu X-s, Liu Y-h, et al.. Rice husk-derived hard carbons as high-performance anode materials for sodium-ion batteries [J]. Carbon, 2018, 127: 658-666.

[31] Wang H-y, Chen H-x, Chen C, et al.. Tea-derived carbon materials as anode for high-performance sodium ion batteries [J]. Chinese Chemical Letters, 2023, 34(4): 107465.

[32] Xie F, Niu Y-s, Zhang Q-q, et al.. Screening heteroatom configurations for reversible sloping capacity promises high-power Na-ion batteries [J]. Angewandte Chemie (International Ed), 2022, 61(11): e202116394.

[33] Liu M-q, Wu F, Gong Y-t, et al.. Interfacial-catalysis-enabled layered and inorganic-rich SEI on hard carbon anodes in ester electrolytes for sodium-ion batteries [J]. Advanced Materials, 2023, 35(29): e2300002.

[34] Sun F, Wang H, Qu Z-b, et al.. Carboxyl-dominant oxygen rich carbon for improved sodium ion storage: Synergistic enhancement of adsorption and intercalation mechanisms [J]. Advanced Energy Materials, 2021, 11(1): 2002981.

[35] Cai P, Zou K-y, Deng X-l, et al.. Comprehensive understanding of sodium-ion capacitors: Definition, mechanisms, configurations, materials, key technologies, and future developments [J]. Advanced Energy Materials, 2021, 11(16): 2003804.

[36] Sun N, Zhao R, Xu M-y, et al.. Design advanced nitrogen/oxygen co-doped hard carbon microspheres from phenolic resin with boosted Na-storage performance [J]. Journal of Power Sources, 2023, 564: 232879.

[37] Ghani U, Iqbal N, Aboalhassan A A, et al.. One-step sonochemical fabrication of biomass-derived porous hard carbons; towards tuned-surface anodes of sodium-ion batteries [J]. Journal of Colloid and Interface Science, 2022, 611: 578-587.

[38] Song M-x, Xie L-j, Su F-y, et al.. New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores [J]. Chinese Chemical Letters, 2024, 35(6): 109266.

[39] Chen H, Sun N, Zhu Q-z, et al.. Microcrystalline hybridization enhanced coal-based carbon anode for advanced sodium-ion batteries [J]. Advanced Science, 2022, 9(20): e2200023.

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Central South University