Preparation of tungsten slag-bentonite particle adsorbent and its adsorption performance for lead ion from wastewater

Bo-han Wei , Zhi-yuan Xue , Yu-dong Yang , Xiao-cong Zhong , Ru-shan Ren , Rui-xiang Wang , Kui-fang Zhang

Journal of Central South University ›› 2023, Vol. 30 ›› Issue (6) : 1841 -1855.

PDF
Journal of Central South University ›› 2023, Vol. 30 ›› Issue (6) : 1841 -1855. DOI: 10.1007/s11771-023-5351-3
Article

Preparation of tungsten slag-bentonite particle adsorbent and its adsorption performance for lead ion from wastewater

Author information +
History +
PDF

Abstract

In this study, the preparation of tungsten slag-bentonite particle adsorbent was studied using orthogonal and static adsorption tests. The adsorbent was characterized, and its adsorption performance for heavy metal lead ions was clarified. The results indicate that the optimum conditions are as follows: mass ratio of tungsten slag to bentonite of 5:1, particle size of 2 mm, and sintering at 800 °C for 2 h. The adsorbent primarily consisted of granular Fe-Mn oxides with a large number of holes on its surface. When the pH value of the solution is 6, adsorbent dosage is 15 g/L, initial lead concentration is 300 mg/L and adsorption time is 200 min, the removal rate of lead in wastewater by adsorbent reaches 99.95%. The adsorption process conforms to the pseudo-second-order kinetic equation, and its adsorption isotherm conforms to the langmuir equation. The adsorption of lead belongs to the specific chemical adsorption of single molecular layer.

Keywords

tungsten slag-bentonite particle adsorbent / preparation / characterization / adsorption / lead wastewater

Cite this article

Download citation ▾
Bo-han Wei, Zhi-yuan Xue, Yu-dong Yang, Xiao-cong Zhong, Ru-shan Ren, Rui-xiang Wang, Kui-fang Zhang. Preparation of tungsten slag-bentonite particle adsorbent and its adsorption performance for lead ion from wastewater. Journal of Central South University, 2023, 30(6): 1841-1855 DOI:10.1007/s11771-023-5351-3

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

GB 8978—1996. Integrated wastewater discharge standard [S]. (in Chinese)

[2]

ZHANG Xiao. Trend of and the Governance System for Water Pollution in China [J]. China Soft Science, 2014(10): 11–24. DOI: https://doi.org/10.3969/j.issn.1002-9753.2014.10.002. (in Chinese)

[3]

WangS-y, YangS-j, ZhangH, et al. . Summary of the sources of lead pollution in soil [J]. Agriculture and Technology, 2022, 42(9): 78-81(in Chinese)

[4]

XU Jia-jie, LI Chang-ying. Study on treatment and reuse of lead-zinc beneficiation wastewater [J]. China Metal Bulletin, 2021(4): 219–220. (in Chinese)

[5]

WangW-xiaExperimental study on high concentration lead and copper wastewater in electrodeposition treatment [D], 2019, Changsha, China, Hunan University(in Chinese)

[6]

LiB-j, HuP-d, WangX-lei. Lead removal from wastewater of lead-acid battery production with process of IonExchange resin [J]. Water Purification Technology, 2015, 34(5): 82-86(in Chinese)

[7]

GouY, NiuL-j, ZhaoM-q, et al. . Removal of Pb2+ from water by Pb-tolerant streptomyces-induced precipitation of calcium carbonate [J]. Nonferrous Metals Engineering, 2022, 12(9): 165-172(in Chinese)

[8]

LiuF-fanThe study on mass transfer model of ESIP and simulation of reuse process of wastewater from lead-zinc mine [D], 2019, Taiyuan, China, Taiyuan University of Technology(in Chinese)

[9]

YangT-tingInorganic combination-removal of low concentration of lead in pit gushing water by microbial flocculant [D], 2015, Kunming, China, Kunming University of Science and Technology(in Chinese)

[10]

ChangL-tongElectrically switched coal-based carbon membrane based on double electric layer efficiently separate lead and calcium ions [D], 2020, Taiyuan, China, Taiyuan University of Technology(in Chinese)

[11]

LiY, LiuJ, LuY, et al. . Study on adsorption of lead-containing wastewater by modified activated carbon [J]. Guangdong Chemical Industry, 2022, 49(1): 147-149(in Chinese)

[12]

ZhaoX-h, RuanHong. Preparation of lignin/calcium carbonate composite absorbent and its treatment of Pb2+ in water [J]. Chemical Research and Application, 2022, 34(9): 2044-2052(in Chinese)

[13]

LiY-n, ChenM-j, WuY, et al. . Study on adsorption behavior of nanoplastics polystyrene for lead ions in water [J]. Acta Scientiae Circumstantiae, 2022, 42(4): 177-185(in Chinese)

[14]

GuX-c, MeiP-y, ZhangZ, et al. . Research progress on treatment technology of lead-bearing wastewater [J]. Industrial Water Treatment, 2020, 40(12): 14-19(in Chinese)

[15]

FuY-x, SongX-l, MaT-t, et al. . Preparation of modifying activated carbon and treatment of Pb2+ in oil pollution wastewater [J]. Science and Technology in Chemical Industry, 2022, 30(3): 5-10(in Chinese)

[16]

WANG Li, XU Xiao-zhen, ZHENG Xiao-qing, et al. Adsorption of Cr(VI) from Water using Biochar-supported Iron manganese bimetallic oxides [J]. Chemical Management, 2022(24): 162–165. DOI: https://doi.org/10.19900/j.cnki.ISSN1008-4800.2022.24.048. (in Chinese)

[17]

LianB, WuJ-z, ZhaoK-l, et al. . Novel insight into the adsorption mechanism of Fe-Mn oxide-microbe combined biochar for Cd(II) and As(III) [J]. Environmental Science, 2022, 43(3): 1584-1595(in Chinese)

[18]

WuL-s, KhodadoustA P, PuniaS. Removal of chromium from water using manganese (II, III) oxides coated sand: Adsorption and transformation of Cr(VI) and Cr(III) [J]. Environmental Technology, 2023, 44(14): 2113-2133

[19]

MaM-y, DuY-g, BaoS-x, et al. . Removal of cadmium and lead from aqueous solutions by thermal activated electrolytic manganese residues [J]. Science of the Total Environment, 2020, 748: 141490

[20]

MaS-c, GuH-n, MeiZ-m, et al. . Conversion synthesis of manganese sulfate residue into iron hydroxide adsorbent for Cu(II) removal from aqueous solution [J]. Environmental Science and Pollution Research, 2020, 27(19): 23871-23879

[21]

LiB, LiC, ZhaoM-q, et al. . Study on adsorption characteristics and speciation distribution of lead in soil [J]. Applied Chemical Industry, 2022, 51(5): 1360-1364(in Chinese)

[22]

LianX-yuSorption of Pb(II) in water by iron and manganese oxide [D], 2021, Taiyuan, China, Taiyuan University of Science and Technology(in Chinese)

[23]

JingQ-x, WangY-y, ChaiL-y, et al. . Adsorption behavior of ammonium in leachate from ionic rare earth mining area soil by diatomite and tungsten residue based porous ceramsite [J]. The Chinese Journal of Nonferrous Metals, 2018, 28(5): 1033-1042(in Chinese)

[24]

ChakravartyS, DurejaV, BhattacharyyaG, et al. . Removal of arsenic from groundwater using low cost ferruginous manganese ore [J]. Water Research, 2002, 36(3): 625-632

[25]

YamashitaT, HayesP. Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials [J]. Applied Surface Science, 2008, 254(8): 2441-2449

[26]

DiC V, PolzonettiG, ContiniG, et al. . XPS study of MnO2 minerals treated by bioleaching [J]. Surface and Interface Analysis, 1990, 16571-574

[27]

Ivanov-EhminB N, NevskayaN A, ZajtsevB E, et al. . Synthesis and properties of calcium and strontium hydroxomanganates(3) [J]. Zhurnal Neorganicheskoj Khimii, 1982, 27(12): 3101-3104

[28]

YangW-h, SuZ-a, XuZ-h, et al. . Comparative study of α-, β -, γ - and δ -MnO2 on toluene oxidation: Oxygen vacancies and reaction intermediates [J]. Applied Catalysis B: Environmental, 2020, 260118150

[29]

ChangJ K, TsaiW T. Effects of temperature and concentration on the structure and specific capacitance of manganese oxide deposited in manganese acetate solution [J]. Journal of Applied Electrochemistry, 2004, 34(9): 953-961

[30]

SharmaR K, RastogiA C, DesuS B. Manganese oxide embedded polypyrrole nanocomposites for electrochemical supercapacitor [J]. Electrochimica Acta, 2008, 53(26): 7690-7695

[31]

ZhaoL-j, LiuM-d, WangY-j, et al. . Adsorption of lead from wastewater by blast-furnace slag [J]. Chinese Journal of Environmental Engineering, 2010, 4(7): 1473-1477(in Chinese)

[32]

ZHENG Li-sheng, WANG Shi-long, ZHANG Hong, et al. Experimental study on the treatment of lead-containing wastewater with slag [J]. Environmental Science and Technology, 1995(1): 13–14, 46.

[33]

PanP-ling. Experimental comparison of two adsorption methods for removing Pb2+ from simulated wastewater [J]. Contemporary Chemical Industry, 2016, 45(8): 1700-1703(in Chinese)

[34]

TanT C, TeoW K. Combined effect of carbon dosage and initial adsorbate concentration on the adsorption isotherm of heavy metals on activated carbon [J]. Water Research, 1987, 21(10): 1183-1188

[35]

LiY-h, WangS-g, WeiJ-q, et al. . Lead adsorption on carbon nanotubes [J]. Chemical Physics Letters, 2002, 357(3–4): 263-266

[36]

WANG Ying-nan, SHENG Lin-lin, HUANG Juan, et al. Study on adsorption performance of lead from water by coal-fired slag [J]. Inorganic Chemicals Industry, 2023. DOI: https://doi.org/10.19964/j.issn.1006-4990.2022-0684. (in Chinese)

[37]

ZouX-g, W-y, WangY-l, et al. . Study on adsorption of Pb2+ by mesoporous Fe-Mn binary oxide and its mechanisms [J]. Acta Scientiae Circumstantiae, 2018, 38(3): 982-992(in Chinese)

[38]

HaoY-l, ZhangY, QuA-yun. Adsorption performance of Fe-Mn binary oxide loaded on palygorskite clay for phosphate [J]. Journal of Rock Mineralogy, 2016, 35(6): 1085-1090(in Chinese)

[39]

XuK, LiC-g, LiuJ-t, et al. . Study on chromium (VI) removal from aqueous solution using Fe-Mn bimetal oxide [J]. Technology of Water Treatment, 2011, 37(12): 20-232011. (in Chinese)

AI Summary AI Mindmap
PDF

160

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/