PDF
Abstract
The effects of solution treatment temperature and holding time on the microstructure and mechanical properties of extruded Al-6.02 wt.%Zn-1.94 wt.%Mg alloy were investigated by differential scanning calorimetry (DSC), optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and tensile test. The results showed that the optimum solution treatment process for the alloy was 470 °C, 2 h. The tensile strength, yield strength, and elongation of the samples after the aging treatment at 120 ° C for 24 h were 486 MPa, 431 MPa, and 14.8%, respectively. The alloy produced more copious recrystallization with the augment of solution temperature and the extension of holding time. While the second phase of η (MgZn2), and T (AlZnMgCu) in the matrix was not fully re-dissolved under the treatment condition of lower temperature or shorter holding time. Interestingly, the Zr aggregation was observed in the samples treated at 510 ° C for 2 h, which led to the growth of the second phase particles and the increase of their area fraction.
Keywords
microstructure
/
solution treatment
/
second phase
/
recrystallization
/
aggregation
Cite this article
Download citation ▾
Chang-chang Nie, Yuan-chun Huang, Hong-bang Shao, Jin-chuan Wen.
Microstructure and mechanical properties of Al-6.02Zn-1.94Mg alloy at higher solution treatment temperature.
Journal of Central South University, 2022, 29(3): 937-949 DOI:10.1007/s11771-022-4965-1
| [1] |
HuJ, WuX, BoH, et al.. Dislocation density model and microstructure of 7A85 aluminum alloy during thermal deformation [J]. Journal of Central South University, 2021, 28(10): 2999-3007
|
| [2] |
PengG, ChenK, ChenS, et al.. Evolution of the second phase particles during the heating-up process of solution treatment of Al-Zn-Mg-Cu alloy [J]. Materials Science and Engineering A, 2015, 641: 237-241
|
| [3] |
RometschP A, ZhangY, KnightS. Heat treatment of 7xxx series aluminium alloys—Some recent developments [J]. Transactions of Nonferrous Metals Society of China, 2014, 24(7): 2003-2017
|
| [4] |
ZhangX, XuH, ChenT, et al.. Forming properties and microstructure of Al-Cu alloy prepared by liquid-die forging [J]. Journal of Central South University, 2022, 29(1): 60-79
|
| [5] |
WeiS, FengY, ZhangH, et al.. Influence of aging on microstructure, mechanical properties and stress corrosion cracking of 7136 aluminum alloy [J]. Journal of Central South University, 2021, 28(9): 2687-2700
|
| [6] |
DengY, WanL, ZhangY, et al.. Evolution of microstructures and textures of 7050 Al alloy hot-rolled plate during staged solution heat-treatments [J]. Journal of Alloys and Compounds, 2010, 498(1): 88-94
|
| [7] |
FangH C, ChenK H, ChenX, et al.. Effect of Cr, Yb and Zr additions on localized corrosion of Al-Zn-Mg-Cu alloy [J]. Corrosion Science, 2009, 51(12): 2872-2877
|
| [8] |
HuangL P, ChenK H, LiS, et al.. Influence of high-temperature pre-precipitation on local corrosion behaviors of Al-Zn-Mg alloy [J]. Scripta Materialia, 2007, 56(4): 305-308
|
| [9] |
ChenC, HanW, QiM, et al.. Microstructural evolution and mechanical properties of an ultrahighstrength Al-Zn-Mg-Cu alloy via powder metallurgy and hot extrusion [J]. Journal of Central South University, 2021, 28(4): 1195-1205
|
| [10] |
VlachM, KodetovaV, CizekJ, et al.. Role of small addition of Sc and Zr in clustering and precipitation phenomena induced in AA7075 [J]. Metals, 2020, 11(1): 8
|
| [11] |
HanN M, ZhangX M, LiuS D, et al.. Effect of solution treatment on the strength and fracture toughness of aluminum alloy 7050 [J]. Journal of Alloys and Compounds, 2011, 509104138-4145
|
| [12] |
LiuY, JiangD, LiB, et al.. Heating aging behavior of Al-8.35Zn-2.5Mg-2.25Cu alloy [J]. Materials & Design, 2014, 60: 116-124
|
| [13] |
GuoF, ZhuB, JinL, et al.. Microstructure and mechanical properties of 7A56 aluminum alloy after solution treatment [J]. Rare Metals, 2021, 40(1): 168-175
|
| [14] |
XuX, ZhangP, ZhangR, et al.. Effect of multi-stage solution on microstructure and properties of Al-10.5Zn-2.05Mg-1.02Cu-0.2Zr-0.923Ti alloy extrusion [J]. Applied Physics A, 2020, 126(9): 1-8
|
| [15] |
WenK, XiongB, FanY, et al.. Transformation and dissolution of second phases during solution treatment of an Al-Zn-Mg-Cu alloy containing high zinc [J]. Rare Metals, 2018, 37(5): 376-380
|
| [16] |
LiangM, ChenL, ZhaoG, et al.. Effects of solution treatment on the microstructure and mechanical properties of naturally aged EN AW 2024 Al alloy sheet [J]. Journal of Alloys and Compounds, 2020, 824: 153943
|
| [17] |
VlachM, ČıžekJ, KodetováV, et al.. Annealing effects in cast commercial aluminium Al-Mg-Zn-Cu (-Sc-Zr) alloys [J]. Metals and Materials International, 2021, 27(5): 995-1004
|
| [18] |
LangY, ZhouG, HouL, et al.. Significantly enhanced the ductility of the fine-grained Al-Zn-Mg-Cu alloy by strain-induced precipitation [J]. Materials & Design, 2015, 88625-631
|
| [19] |
LiD, ZhangD, LiuS, et al.. Dynamic recrystallization behavior of 7085 aluminum alloy during hot deformation [J]. Transactions of Nonferrous Metals Society of China, 2016, 26(6): 1491-1497
|
| [20] |
GuoR, ZhangC, LiuM, et al.. Influence of isothermal and non-isothermal aging treatments on microstructure and properties of Al-Zn-Mg alloy helical profile [J]. Materials Characterization, 2020, 169: 110613
|
| [21] |
ZhangC, WangC, GuoR, et al.. Investigation of dynamic recrystallization and modeling of microstructure evolution of an Al-Mg-Si aluminum alloy during high-temperature deformation [J]. Journal of Alloys and Compounds, 2019, 77359-70
|
| [22] |
XuD K, RometschP A, BirbilisN. Improved solution treatment for an as-rolled Al-Zn-Mg-Cu alloy. Part I. Characterisation of constituent particles and overheating [J]. Materials Science and Engineering A, 2012, 534: 234-243
|
| [23] |
PengX, LiY, LiangX, et al.. Precipitate behavior and mechanical properties of enhanced solution treated Al-Zn-Mg-Cu alloy during non-isothermal ageing [J]. Journal of Alloys and Compounds, 2018, 735: 964-974
|
| [24] |
XuD K, RometschP A, BirbilisN. Improved solution treatment for an as-rolled Al-Zn-Mg-Cu alloy. Part II. Microstructure and mechanical properties [J]. Materials Science and Engineering A, 2012, 534: 244-252
|
| [25] |
LiuQ, FanG, TanZ, et al.. Precipitation of Al3Zr by two-step homogenization and its effect on the recrystallization and mechanical property in 2195 Al-Cu-Li alloys [J]. Materials Science and Engineering A, 2021, 821: 141637
|
| [26] |
YangY, TanP, SuiY, et al.. Influence of Zr content on microstructure and mechanical properties of Ascast Al-Zn-Mg-Cu alloy [J]. Journal of Alloys and Compounds, 2021, 867158920
|
| [27] |
MorereB, EhrströmJ C, GregsonP J, et al.. Microstructural effects on fracture toughness in AA7010 plate [J]. Metallurgical and Materials Transactions A, 2000, 31(10): 2503-2515
|
| [28] |
ZhangY, BettlesC, RometschP A. Effect of recrystallisation on Al3Zr dispersoid behaviour in thick plates of aluminium alloy AA7150 [J]. Journal of Materials Science, 2014, 49(4): 1709-1715
|
| [29] |
LiuY, JiangD, LiB, et al.. Effect of cooling aging on microstructure and mechanical properties of an Al-Zn-Mg-Cu alloy [J]. Materials & Design, 2014, 5779-86
|
| [30] |
CvijovićZ, RakinM, VratnicaM, et al.. Microstructural dependence of fracture toughness in high-strength 7000 forging alloys [J]. Engineering Fracture Mechanics, 2008, 75(8): 2115-2129
|
| [31] |
GaoR, ZengL, DingH, et al.. Characterization of oxide dispersion strengthened ferritic steel fabricated by electron beam selective melting [J]. Materials & Design, 2016, 89: 1171-1180
|
| [32] |
ZhaoZ, TongT, LiangJ, et al.. Microstructure, mechanical properties and fracture behavior of ultra-high strength dual-phase steel [J]. Materials Science and Engineering A, 2014, 618: 182-188
|
| [33] |
ChenG, ChenL, ZhaoG, et al.. Microstructure evolution during solution treatment of extruded Al-Zn-Mg profile containing a longitudinal weld seam [J]. Journal of Alloys and Compounds, 2017, 729: 210-221
|
| [34] |
YuanS, ChenL, TangJ, et al.. Correlation between homogenization treatment and subsequent hot extrusion of Al-Mg-Si alloy [J]. Journal of Materials Science, 2019, 54(13): 9843-9856
|
| [35] |
YuJ, ZhaoG, ChenL. Investigation of interface evolution, microstructure and mechanical properties of solid-state bonding seams in hot extrusion process of aluminum alloy profiles [J]. Journal of Materials Processing Technology, 2016, 230: 153-166
|
| [36] |
LiuS D, ChenB, LiC B, et al.. Mechanism of low exfoliation corrosion resistance due to slow quenching in high strength aluminium alloy [J]. Corrosion Science, 2015, 91: 203-212
|
| [37] |
MarlaudT, MalkiB, HenonC, et al.. Relationship between alloy composition, microstructure and exfoliation corrosion in Al-Zn-Mg-Cu alloys [J]. Corrosion Science, 2011, 53(10): 3139-3149
|
| [38] |
SongW, PuJ, WangH, et al.. Effect of solid-solution process on the properties of 7050 aluminum alloy [J]. Key Engineering Materials, 2020, 866: 63-71
|
| [39] |
DeshpandeN U, GokhaleA M, DenzerD K, et al.. Relationship between fracture toughness, fracture path, and microstructure of 7050 aluminum alloy: Part I. Quantitative characterization [J]. Metallurgical and Materials Transactions A, 1998, 29(4): 1191-1201
|
| [40] |
MACKENZIE D. Quench rate and aging effects in aluminum-zinc-magnesium-copper aluminum alloys [D]. University of Missouri-Rolla, 2000.
|
| [41] |
ArchambaultP, GodardD. High temperature precipitation kinetics and ttt curve of a 7xxx alloy by in situ electrical resistivity measurements and differential calorimetry [J]. Scripta Materialia, 2000, 42(7): 675-680
|
| [42] |
KLUG H, ALEXANDER L. X-ray diffraction procedures: For polycrystalline and amorphous materials [M]. 2nd edition. John Wiley & Sons, Inc, 1974.
|
| [43] |
ZhaoY H, LiaoX Z, JinZ, et al.. Microstructures and mechanical properties of ultrafine grained 7075 Al alloy processed by ECAP and their evolutions during annealing [J]. Acta Materialia, 2004, 52(15): 4589-4599
|
| [44] |
LiuG, SunJ, NanC, et al.. Experiment and multiscale modeling of the coupled influence of constituents and precipitates on the ductile fracture of heat-treatable aluminum alloys [J]. Acta Materialia, 2005, 53(12): 3459-3468
|
| [45] |
ShaG, CerezoA. Early-stage precipitation in Al-Zn-Mg-Cu alloy (7050) [J]. Acta Materialia, 2004, 52(15): 4503-4516
|
| [46] |
CaiB, AdamsB L, NelsonT W. Relation between precipitate-free zone width and grain boundary type in 7075-T7 Al alloy [J]. Acta Materialia, 2007, 55(5): 1543-1553
|
| [47] |
HornbogenE, StarkeE A. Overview no. 102 Theory assisted design of high strength low alloy aluminum [J]. Acta Metallurgica et Materialia, 1993, 41(1): 1-16
|