Microstructure, mechanical properties and corrosion performance of selective laser melting Ti/GNPs composite with a porous structure

Xin Yang , Zhao-yang Zhang , Ben Wang , Wen-jun Ma , Wan-lin Wang , Wen-ge Chen , Ning-ning Kang , Shi-feng Liu

Journal of Central South University ›› 2021, Vol. 28 ›› Issue (8) : 2257 -2268.

PDF
Journal of Central South University ›› 2021, Vol. 28 ›› Issue (8) : 2257 -2268. DOI: 10.1007/s11771-021-4767-x
Article

Microstructure, mechanical properties and corrosion performance of selective laser melting Ti/GNPs composite with a porous structure

Author information +
History +
PDF

Abstract

In this study, nano-graphene reinforced titanium matrix composites (GNPs/Ti) with a honeycomb porous structure were fabricated by selective laser melting (SLM). The effects of graphene on the microstructure, mechanical properties and corrosion performance of the SLM GNPs/Ti were systematically investigated. Results of microstructure characterization show that: 1) the density of the SLM GNPs/Ti was improved as compared to that of the SLM Ti; 2) abundant TiC particles were formed in the SLM GNPs/Ti. The hardness and compressive strength of the composite increased by 90% (from HV 236 to HV 503) and 14% (from 277 MPa to 316 MPa), respectively, attributed to the uniformly distributed TiC and fine GNPs in the Ti matrix. Electrochemical tests reveal that the corrosion current density of the SLM GNPs/Ti is only 0.328 μA/cm2, that is about 25% less than that of the SLM Ti. The results indicate that the incorporation of nano-graphene is a potential method to strengthen the Ti by SLM.

Keywords

porous GNPs/Ti composites / selective laser melting / microstructure / mechanical properties / corrosion properties

Cite this article

Download citation ▾
Xin Yang, Zhao-yang Zhang, Ben Wang, Wen-jun Ma, Wan-lin Wang, Wen-ge Chen, Ning-ning Kang, Shi-feng Liu. Microstructure, mechanical properties and corrosion performance of selective laser melting Ti/GNPs composite with a porous structure. Journal of Central South University, 2021, 28(8): 2257-2268 DOI:10.1007/s11771-021-4767-x

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

LiZ-J, DongA-P, XingH, XuH, DuD, ZhangT, SheH, WangD-H, ZhuG-L. Microstructure and mechanical properties of bimodal Ti-Bi alloys fabricated by mechanical alloying and spark plasma sintering for biomedical applications [J]. Materials Characterization, 2020, 161: 110134

[2]

FerreriN C, SavageD J, KnezevicM. Non-acid, alcohol-based electropolishing enables high-quality electron backscatter diffraction characterization of titanium and its alloys: Application to pure Ti and Ti-6Al-4V [J]. Materials Characterization, 2020, 166110406

[3]

ZhangF-M, LiuS-L, ZhaoP-P, LiuT-F, SunJ. Titanium/nanodiamond nanocomposites: Effect of nanodiamond on microstructure and mechanical properties of titanium [J]. Materials & Design, 2017, 131144-155

[4]

HouY-H, LiuB, LiuY, ZhouY-H, SongT-T, ZhouQ, ShaG, YanM. Ultra-low cost Ti powder for selective laser melting additive manufacturing and superior mechanical properties associated [J]. Opto-Electronic Advances, 2019, 2(5): 18002801-18002808

[5]

BolzoniL, Ruiz-NavasE M, GordoE. Powder metallurgy CP-Ti performances: Hydride-dehydride vs. sponge [J]. Materials & Design, 2014, 60: 226-232

[6]

YanM, DarguschM S, EbelT, QianM. A transmission electron microscopy and three-dimensional atom probe study of the oxygen-induced fine microstructural features in as-sintered Ti-6Al-4V and their impacts on ductility [J]. Acta Materialia, 2014, 68: 196-206

[7]

ZhangX Z, LearyM, TangH P, SongT, QianM. Selective electron beam manufactured Ti-6Al-4V lattice structures for orthopedic implant applications: Current status and outstanding challenges [J]. Current Opinion in Solid State and Materials Science, 2018, 22(3): 75-99

[8]

HacisalihoğluI, YildizF, ÇelikA. The effects of build orientation and hatch spacing on mechanical properties of medical Ti-6Al-4V alloy manufactured by selective laser melting [J]. Materials Science and Engineering A, 2021, 802: 140649

[9]

YangX, MaW-J, RenY-J, LiuS-F, WangY, WangW-L, TangH-P. Subgrain microstructures and tensile properties of 316L stainless steel manufactured by selective laser melting [J]. Journal of Iron and Steel Research International, 2021, 281159-1167

[10]

ZhengJ-P, ChenL-J, ChenD-Y, ShaoC-S, YiM-F, ZhangB. Effects of pore size and porosity of surface-modified porous titanium implants on bone tissue ingrowth [J]. Transactions of Nonferrous Metals Society of China, 2019, 29(12): 2534-2545

[11]

WangD, YangY-Q, LiuR-C, XiaoD, SunJ-F. Study on the designing rules and processability of porous structure based on selective laser melting (SLM) [J]. Journal of Materials Processing Technology, 2013, 213(10): 1734-1742

[12]

ChangC, HuangJ, YanX-C, LiQ, LiuM, DengS-H, GardanJ, BolotR, ChemkhiM. Microstructure and mechanical deformation behavior of selective laser melted Ti6Al4V ELI alloy porous structures [J]. Materials Letters, 2020, 277: 128366

[13]

FaríasI, OlmosL, JiménezO, FloresM, BraemA, VleugelsJ. Wear modes in open porosity titanium matrix composites with TiC addition processed by spark plasma sintering [J]. Transactions of Nonferrous Metals Society of China, 2019, 29(8): 1653-1664

[14]

YablokovaG, SpeirsM, van HumbeeckJ, KruthJ P, SchrootenJ, ClootsR, BoschiniF, LumayG, LuytenJ. Rheological behavior of β-Ti and NiTi powders produced by atomization for SLM production of open porous orthopedic implants [J]. Powder Technology, 2015, 283199-209

[15]

MaconachieT, LearyM, LozanovskiB, ZhangX-Z, QianM, FaruqueO, BrandtM. SLM lattice structures: Properties, performance, applications and challenges [J]. Materials & Design, 2019, 183: 108137

[16]

KorznikovaG, CzeppeT, KhalikovaG, GunderovD, KorznikovaE, Litynska-DobrzynskaL, SzlezyngerM. Microstructure and mechanical properties of Cu-graphene composites produced by two high pressure torsion procedures [J]. Materials Characterization, 2020, 161110122

[17]

XiongJ-J, YanH. Microstructure and mechanical properties of ADC12 composites reinforced with graphene nanoplates prepared by ultrasonic assisted casting [J]. Transactions of Nonferrous Metals Society of China, 2020, 30(12): 3210-3225

[18]

Khoshghadam-PireyousefanM, RahmanifardR, OrovcikL, ŠvecP, KlemmV. Application of a novel method for fabrication of graphene reinforced aluminum matrix nanocomposites: Synthesis, microstructure, and mechanical properties [J]. Materials Science and Engineering A, 2020, 772138820

[19]

GülerÖ, BağciN. A short review on mechanical properties of graphene reinforced metal matrix composites [J]. Journal of Materials Research and Technology, 2020, 9(3): 6808-6833

[20]

WuL-Y, ZhaoZ-Y, BaiP-K, ZhaoW, LiY-X, LiangM-J, LiaoH-H, HuoP, LiJ. Wear resistance of graphene nano-platelets (GNPs) reinforced AlSi10Mg matrix composite prepared by SLM [J]. Applied Surface Science, 2020, 503144156

[21]

SuY, ZuoQ, YangG, YangY, WeiC, WangL, LiuJ. Compressive properties of the grahpene reinforced titanium composites [J]. Rare Metal Materials and Engineering, 2017, 46(12): 3882-3886(in Chinese)

[22]

KongX, WangY-M, YangQ, ZhangX, ZhangG-X, YangL-N, WuY, YangR. Low-cycle fatigue behavior and damage progression of a fiber reinforced titanium matrix composite [J]. International Journal of Lightweight Materials and Manufacture, 2021, 4(1): 9-17

[23]

ZhangZ Y, LiangY L. Preparation of graphene/titanium matrix composites and their conductive properties [J]. Journal of Yunnan University: Natural Science Edition, 2019, 41(3): 551-556(in Chinese)

[24]

JinJ-B, ZhouS-F, ZhaoY, ZhangQ, WangX-J, LiW, ChenD-C, ZhangL. Refined microstructure and enhanced wear resistance of titanium matrix composites produced by selective laser melting [J]. Optics & Laser Technology, 2021, 134106644

[25]

MuX N, ChenP W, ZhangH M, ChengX W, LiuL, GeY X. Interface-dependent failure behaviors in graphene nanoflakes reinforced Ti matrix composites [J]. Materials Letters, 2021, 289129422

[26]

ManamN S, HarunW S W, ShriD N A, GhaniS A C, KurniawanT, IsmailM H, IbrahimM H I. Study of corrosion in biocompatible metals for implants: A review [J]. Journal of Alloys and Compounds, 2017, 701698-715

[27]

PraveenB, SureshS, PethurajanV. Heat transfer performance of graphene nano-platelets laden micro-encapsulated PCM with polymer shell for thermal energy storage based heat sink [J]. Applied Thermal Engineering, 2019, 156: 237-249

[28]

MittalG, DhandV, RheeK Y, ParkS J, LeeW R. A review on carbon nanotubes and graphene as fillers in reinforced polymer nanocomposites [J]. Journal of Industrial and Engineering Chemistry, 2015, 21: 11-25

[29]

AlmangourB, GrzesiakD, YangJ M. In situ formation of TiC-particle-reinforced stainless steel matrix nanocomposites during ball milling: Feedstock powder preparation for selective laser melting at various energy densities [J]. Powder Technology, 2018, 326: 467-478

[30]

KazantsevaN, KrakhmalevP, ThuvanderM, YadroitsevI, VinogradovaN, EzhovI. Martensitic transformations in Ti-6Al-4V (ELI) alloy manufactured by 3D printing [J]. Materials Characterization, 2018, 146: 101-112

[31]

AttarH, Ehtemam-HaghighiS, KentD, OkulovI V, WendrockH, BönischM, VolegovaS, CalinM, EckertJ. Nanoindentation and wear properties of Ti and Ti-TiB composite materials produced by selective laser melting [J]. Materials Science and Engineering A, 2017, 688: 20-26

[32]

MandalA, TiwariJ K, SathishN, SrivastavaA K. Microstructural and mechanical properties evaluation of graphene reinforced stainless steel composite produced via selective laser melting [J]. Materials Science and Engineering A, 2020, 774: 138936

[33]

BelyakovA, WeiF G, TsuzakiK, KimuraY, MishimaY. Incomplete recrystallization in cold worked steel containing TiC [J]. Materials Science and Engineering A, 2007, 471(12): 50-56

[34]

WangZ J, QiuZ X, SunH Y, LiuW C. Effect of TiC content on the microstructure, texture and mechanical properties of 1060/Al-TiC/1060 laminated composites [J]. Journal of Alloys and Compounds, 2019, 806788-797

[35]

WeiY-K, LuoX-T, ChuX, HuangG, LiC-J. Solid-state additive manufacturing high performance aluminum alloy 6061 enabled by an in situ micro-forging assisted cold spray [J]. Materials Science and Engineering: A, 2020, 776: 139024

[36]

ArabnejadS, Burnett JohnstonR, PuraJ A, SinghB, TanzerM, PasiniD. High-strength porous biomaterials for bone replacement: A strategy to assess the interplay between cell morphology, mechanical properties, bone ingrowth and manufacturing constraints [J]. Acta Biomaterialia, 2016, 30345-356

[37]

BenedettiM, Du PlessisA, RitchieR O, DallagoM, RazaviS M J, BertoF. Architected cellular materials: A review on their mechanical properties towards fatigue-tolerant design and fabrication [J]. Materials Science and Engineering R: Reports, 2021, 144: 100606

[38]

WeiY-K, LuoX-T, GeY, ChuX, HuangG-S, LiC-J. Deposition of fully dense Al-based coatings via in situ micro-forging assisted cold spray for excellent corrosion protection of AZ31B magnesium alloy [J]. Journal of Alloys and Compounds, 2019, 8061116-1126

[39]

KrishnaN G, GeorgeR P, PhilipJ. Anomalous enhancement of corrosion resistance and antibacterial property of commercially pure Titanium (CP-Ti) with nanoscale rutile titania film [J]. Corrosion Science, 2020, 172108678

[40]

WeiY-K, LuoX-T, ChuX, GeY, HuangG-S, XieY-C, HuangR-Z, LiC-J. Ni coatings for corrosion protection of Mg alloys prepared by an in situ micro-forging assisted cold spray: Effect of powder feedstock characteristics [J]. Corrosion Science, 2021, 184109397

[41]

HanB, ZhuS-G, DongW-W, BaiY-F, DingH, LuoY-L, DiP. Improved mechanical performance and electrochemical corrosion of WC-Al2O3 composite in NaCl solution by adding the TiC additives [J]. International Journal of Refractory Metals and Hard Materials, 2021, 99105566

AI Summary AI Mindmap
PDF

138

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/