Effect of reductant sodium bentonite content and reaction temperature in sponge iron production from composite pellets

Ilker Kara

Journal of Central South University ›› 2021, Vol. 28 ›› Issue (5) : 1324 -1332.

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Journal of Central South University ›› 2021, Vol. 28 ›› Issue (5) : 1324 -1332. DOI: 10.1007/s11771-021-4705-y
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Effect of reductant sodium bentonite content and reaction temperature in sponge iron production from composite pellets

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Abstract

In recent years, composite pellet production with added reductant has been developed instead of traditional iron production. Composite pellets produced by the addition of appropriate proportions of reductant produce sponge iron in the reductant melting process at high temperatures. The elements created in the structure by pellet production directly affect the quality of the product obtained by determining the chemical composition and the appropriate reaction temperature. In this study, sponge iron ore concentrate (scale) and reductant (coke coal dust and sodium bentonite) were mixed at certain proportions to produce composite pellet samples; the effects of addition rate of the reductant material of sodium bentonite (1 wt%–4 wt%) and variation in reaction temperature (900–1200 °C) on the metallization and compressive strength properties of the produced composite pellet samples were investigated. The analysis results show that the highest compressive strength is obtained from pellet samples produced with 3% sodium bentonite at 1100 °C. Additionally, SEM-EDS analysis results of the samples show that the morphologic structure has much lower porosity rates compared to samples produced under the other conditions which makes the samples denser and increases the metallization properties.

Keywords

solid waste / reduction / iron oxides / pellets / sponge iron

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Ilker Kara. Effect of reductant sodium bentonite content and reaction temperature in sponge iron production from composite pellets. Journal of Central South University, 2021, 28(5): 1324-1332 DOI:10.1007/s11771-021-4705-y

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References

[1]

DasB, PrakashS, ReddyP S R, MisraV N. An overview of utilization of slag and sludge from steel industries [J]. Resources, Conservation and Recycling, 2010, 50(1): 40-57

[2]

PengJ, TangM T, PengB, YuD, KozinskiJ A, TangC B. Heating and melting mechanism of stainless steelmaking dust pellet in liquid slag [J]. Journal of Central South University of Technology, 2007, 14(1): 32-36

[3]

ParkJ W, AhnJ C, SongH, ParkK, ShinH, AhnJ S. Reduction characteristics of oily hot rolling mill sludge by direct reduced iron method [J]. Resources, Conservation and Recycling, 2002, 34(2): 129-140

[4]

MatsumuraT, TakenakaY, ShimizuM, NegamiT, KobayashiJ, UragamiA. Direct production of molten iron from carbon composite iron ore pellet [J]. La Revue de Métallurgie-CIT, 1998, 95(3): 341-352

[5]

JungW G. Recovery of tungsten carbide from hard material sludge by oxidation and carbothermal reduction process [J]. Journal of Industrial and Engineering Chemistry, 2014, 20(4): 2384-2388

[6]

BoechatF O, deC R M, TavaresL M. Simulation of mechanical degradation of iron ore pellets in a direct reduction furnace [J]. KONA Powder and Particle Journal, 2018, 35: 216-225

[7]

JohanssonA, HolappaL. From megaplants to minimills-a trend in steelmaking-a prospect for papermaking [J]. Resources, Conservation and Recycling, 2004, 40(2): 173-183

[8]

OzawaL, SheinbaumC, MartinN, WorrellE, PriceL. Energy use and CO2 emissions in Mexico’s iron and steel industry [J]. Energy, 2002, 27(3): 225-239

[9]

KirschenM, RisonartaV, PfeiferH. Energy efficiency and the influence of gas burners to the energy related carbon dioxide emissions of electric arc furnaces in steel industry [J]. Energy, 2009, 34(9): 1065-1072

[10]

CetinkayaS, ErogluS. Thermodynamic analysis and reduction of tin oxide with methane [J]. International Journal of Mineral Processing, 2012, 110: 71-73

[11]

LiG H, YouZ X, ZhangY B, RaoM J, WenP D, GuoY F, JiangT. Synchronous volatilization of Sn, Zn, and As, and preparation of direct reduction iron (DRI) from a complex iron concentrate via CO reduction [J]. JOM, 2014, 66(9): 1701-1710

[12]

ZareG A, ValipourM S, VahediS M, SohnH Y. A review on the modeling of gaseous reduction of iron oxide pellets [J]. Steel Research International, 2020, 91(1): 1900270

[13]

ChunT, LongH, DiZ, MengQ, WangP. Preparation of direct reduction sponge iron (DRI) using pyrite cinder containing nonferrous metals [J]. High Temperature Materials and Processes, 2017, 3610971-978

[14]

StalhedJ L. Sponge iron in electric arc furnaces [J]. JOM, 1957, 9(2): 246-249

[15]

HAVEMANN H A. Direct iron ore reduction for Asia [J]. Indian Construction News, 1959(8): 260–272. http://eprints.nmlindia.org/3059/1/260-272.PDF.

[16]

PineauA, KanariN, GaballahI. Kinetics of reduction of iron oxides by H2: Part I: Low temperature reduction of hematite [J]. Thermochimica Acta, 2006, 447(1): 89-100

[17]

ZhuD Q, MendesV, ChunT J, PanJ, LiQ H, LiJ, QiuG Z. Direct reduction behaviors of composite binder magnetite pellets in coal-based grate-rotary kiln process [J]. ISIJ International, 2011, 51(2): 214-219

[18]

KhaidurovaA A, KonovalovP N, KonovalovN P. Microwave treatment of a brown coal concentrate from mugunsk coal for the manufacture of sponge iron. [J]. Solid Fuel Chemistry, 2008, 42(2): 120-122

[19]

GaoS, BrownB, YoungD, SingerM. Formation of iron oxide and iron sulfide at high temperature and their effects on corrosion [J]. Corrosion Science, 2018, 135(1): 167-176

[20]

EsperF J, ExnerH E, MetzlerH. The correlation between raw materials, preparation conditions, and properties of sintered iron [J]. Powder Metallurgy, 1975, 18(35): 107-123

[21]

vanW S, NeomagusH W J P, BuntJ R, EversonR C. Coal reactivity and selection for solid-based pre-reduction of sponge iron [J]. International Journal of Coal Preparation and Utilization, 2020, 40(45): 233-246

[22]

ZhangY B, LiG H, JiangT, GuoY F, HuanZ C. Reduction behavior of tin-bearing iron concentrate pellets using diverse coals as reducers [J]. International Journal of Mineral Processing, 2012, 110: 109-116

[23]

SenR, PandelU. Closed crucible reduction of lump powdered mill scale or iron ore by coal: The sequential methodology and mechanism for optimization of process parameters [J]. Advanced Powder Technology, 2020, 31(9): 3760-3773

[24]

NayakD, RayN, DashN, RathS S, BiswalS K. Reduction behavior of Odisha sands complex, India ilmenitecoke composite pellets [J]. Journal of Central South University, 2020, 27(6): 1678-1690

[25]

YuW, SunT C, LiuZ Z, KouJ, XuC Y. Study on the strength of cold-bonded high-phosphorus oolitic hematite-coal composite briquettes [J]. International Journal of Minerals, Metallurgy, and Materials, 2014, 21(5): 423-430

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