PDF
Abstract
Magnetic seeding agglomeration (MSA), i.e., adding magnetic seeds and a low intensity pre-magnetization for fine agglomeration, was applied to the flotation of coal, pyrite and hematite ore slimes. Size analysis and flotation tests highlight that the MSA improved flotation recovery and kinetics of pyrite ore while causing some loss in selectivity, and in the presences of the polyacrylamide for coal and starch for hematite the agglomeration flotation was further strengthened due to the synergetic effect between the flocculants and magnetic seeds. Magnetism analyses and calculation confirmed the adsorption of magnetic seeds onto minerals, resulting in a decreased threshold magnetic field intensity for the MSA to happen. Then atomic force microscope (AFM) study found that there exists a long range force between magnetic seeds and minerals, which facilitates the adsorption of magnetic seeds on minerals. FTIR shows both the polyacrylamide and starch adsorbed onto minerals and magnetic seeds, thus acting as the bridging media between minerals and magnetic seeds, intensifying the agglomeration in flotation. Surface characterization of the MSA was understood by SEM imaging, and models of the MSA were proposed.
Keywords
magnetic seeds
/
magnetic seeding agglomeration (MSA)
/
magnetic seeding flotation (MSF)
/
fine agglomeration
/
fine flotation
/
flocculation
Cite this article
Download citation ▾
Tao Yue, Xi-qing Wu, Liang Dai.
Effect of magnetic seeding agglomeration on flotation of fine minerals.
Journal of Central South University, 2019, 26(1): 75-87 DOI:10.1007/s11771-019-3983-0
| [1] |
WillsB A, Napier-MunnT J. Wills’ mineral processing technology: An introduction to the practical aspects of ore treatment and mineral recovery [M]. Butterworth-Heinemann, 2015
|
| [2] |
PeaseJ D, CurryD C, YoungM F. Designing flotation circuits for high fines recovery [J]. Minerals Engineering, 2006, 19(6): 831-840
|
| [3] |
LaskowskiJ S, Lopez-VladiviesoA. Fine particle aggregation in mineral processing circuits [C]. Proceedings of 5th UBC-McGill-UA Symposium. MetSoc, Hamilton, Canada., 20041732
|
| [4] |
ForbesE. Shear, selective and temperature responsive flocculation: A comparison of fine particle flotation techniques [J]. International Journal of Mineral Processing, 2011, 99(1): 1-10
|
| [5] |
HuW B, WangD Z, QuG Z. Autogenous carrier flotation [C]. Proceedings of International of Mineral Processing Congress, 1988, 16: 329-335
|
| [6] |
ValderramaL, RubioJ. High intensity conditioning and the carrier flotation of gold fine particles [J]. International Journal of Mineral Processing, 1998, 52(4): 273-285
|
| [7] |
ZhuY G, ZhangG F, FengQ M, LuY P, OuL M. Autogenous-carrier flotation of fine ilmenite [J]. The Chinese Journal of Nonferrous Metals, 2009, 3: 554-560
|
| [8] |
AtesokG, BoyluF, ElikM S. Carrier flotation for desulfurization and deashing of difficult-to-float coals [J]. Minerals Engineering, 2001, 14(6): 661-670
|
| [9] |
LiuJ, VandenbergheaJ, MasliyahaJ, XuZ, YordanJ. Fundamental study on talc–ink adhesion for talc-assisted flotation deinking of wastepaper [J]. Minerals Engineering, 2007, 20(6): 566-573
|
| [10] |
LuY P, ZhongH, HuangX H. Flotation of fine wolframine flocs using polyarcylic acid as flocculant [J]. Mining and Metallurgical Engineering, 1994, 14(1): 30-33
|
| [11] |
SongS X, ZhangX W, YangB QLOPEZMENDOZA. Flotation of molybdenite fines as hydrophobic agglomerates [J]. Separation and Purification Technology, 2012, 98: 451-455
|
| [12] |
NgW S, SonsieR, ForbesE, FranksG V. Flocculation/flotation of hematite fines with anionic temperature-responsive polymer acting as a selective flocculant and collector [J]. Minerals Engineering, 2015, 77: 64-71
|
| [13] |
RubioJ, CapponiF, RodriguesR T, MatioloE. Enhanced flotation of sulfide fines using the emulsified oil extender technique [J]. International Journal of Mineral Processing, 2007, 84(1): 41-50
|
| [14] |
DuzyolaS, OzkanA. Role of hydrophobicity and surface tension on shear flocculation and oil agglomeration of magnesite [J]. Separation and Purification Technology, 2010, 72(1): 7-12
|
| [15] |
YinW Z, YangX S, ZhouD P, LiY J, LüZ F. Shear hydrophobic flocculation and flotation of ultrafine Anshan hematite using sodium oleate [J]. Transactions of Nonferrous Metals Society of China, 2011, 21(3): 652-664
|
| [16] |
BakkerM G, SpearsD R, MurphyD D, TurnerG L. Whatever happened to shear-flocculation [J]. Fluid-Particle Separation Journal, 2002, 14: 155-168
|
| [17] |
CapesC E, DarcovichK. Size enlargement [M]. Kirk-Othmer Encyclopedia of Chemical Technology. New York: John Wiley & Sons, Inc., 1997
|
| [18] |
LaskowskiJ S, YuZ. Oil agglomeration and its effect on beneficiation and filtration of low-rank/oxidized coals [J]. International Journal of Mineral Processing, 2000, 58(1): 237-252
|
| [19] |
LiH, FranksG V, LiH, FranksG V. Role of temperature sensitive polymers in hydrophobic aggregation/flotation of silicate minerals [C]. 24th Int. Minerals Processing Congress China Scientific, 2008, Book Service, Beijing, China: 12611269
|
| [20] |
FranksG V, LiH, O’SheaJ P, QiaoG G. Application of poly (N-isopropyl acrylamide)(PNIPAM) as a multifunction process aid in mineral flotation and solid/liquid separation [C]. 24th International Minerals Processing Congress, 2008, China Scientific Book Service, Beijing, China: 20992106
|
| [21] |
FranksG V, LiH, O’SheaJ P, QiaoG G. Temperature responsive polymers as multiple function reagents in mineral processing [J]. Advanced Powder Technology, 2009, 20(3): 273-279
|
| [22] |
BurdukovaE, LiH, IshidaN, O’SheaJ P, FranksG V. Temperature controlled surface hydrophobicity and interaction forces induced by poly (N-isopropylacrylamide) [J]. Journal of Colloid and Interface Science, 2010, 342(2): 586-592
|
| [23] |
ForbesE, BradshawD J, FranksG V. Temperature sensitive polymers as efficient and selective flotation collectors [J]. Minerals Engineering, 2011, 24(8): 772-777
|
| [24] |
Akdemir, SönmezI. Investigation of coal and ash recovery and entrainment in flotation [J]. Fuel Processing Technology, 2003, 82(1): 1-9
|
| [25] |
KumarS, RawatV. Froth flotation of refuse coal fines and process optimization using 2D surface plots [J]. Journal of Central South University, 2016, 23(10): 2520-2525
|
| [26] |
CuiG-w, ZhangJ-z, FuX-t, CaoM-c T-J, DongH-jian. Study on the influence of size composition on the flotation of coal [J]. Coal Preparation Technology, 2007, 4: 20-22
|
| [27] |
LittlefairM J, LoweN R S. On the selective flocculation of coal using polystyrene latex [J]. International Journal of Mineral Processing, 1986, 17(34): 187-203
|
| [28] |
ShahbaziB, RezaiB, KoleiniS M J. Bubble–particle collision and attachment probability on fine particles flotation [J]. Chemical Engineering and Processing: Process Intensification, 2010, 49(6): 622-627
|
| [29] |
ChipfunhuD, ZaninM, GranoS. Flotation behaviour of fine particles with respect to contact angle [J]. Chemical Engineering Research and Design, 2012, 90(1): 26-32
|
| [30] |
AhmadiR, KhodadadiD A, AbdollahyM, FanM. Nano-microbubble flotation of fine and ultrafine chalcopyrite particles [J]. International Journal of Mining Science and Technology, 2014, 24(4): 559-566
|
| [31] |
WU Xi-qing, DAI Chuan, DAI Liang. Magnetic seeding flotation (MSF): CN 104117432A [P]. 2014-7-10. (in Chinese)
|
| [32] |
WuX-q, XieX, CaoY-fan. Self-magnetization of pyrite and its application in flotation [J]. Transactions of Nonferrous Metals Society of China, 2016, 26(12): 3238-3244
|
| [33] |
WuX-q, YangP-w, ChengZ, DaiLiang. Surface magnetization of hematite by metal ions [J]. Advanced Materials Research, 2013, 785-786: 1104-1110
|
| [34] |
WU Xi-qing, CAO Yang-fan. A stirring pre-magnetizer: CN 20449700OU [P]. 2015-7-22. (in Chinese)
|
| [35] |
WuX-q, XuP-y, DuanY-f, HuC, LiG-ping. Surface magnetization of siderite mineral [J]. International Journal of Mining Science and Technology, 2012, 22(6): 825-830
|
| [36] |
LvY-t, ZhaoL-y, ShiQ-lei. The influence of magnetic field on the flocculation and sedimentation of coal slimes [J]. Heilongjiang University of Science and Technology, 2013, 5: 424-426
|
| [37] |
SvobodaJ. A theoretical approach to the magnetic flocculation of weakly magnetic minerals [J]. International Journal of Mineral Processing, 1981, 8(4): 377-390
|
| [38] |
SvobodaJ. Magnetic flocculation and treatment of fine weakly magnetic minerals [J]. IEEE Transactions on Magnetics, 1982, 18(2): 796-801
|
| [39] |
DaiLiang. The magnetic seed-polymer agglomeration of coal slime [D]. Changsha: School of Minerals Processing and Bioengineering, Central South University, 2015
|
| [40] |
WatsonJ H P. Magnetic separation at high magnetic fields [C]. Proceedings of the Sixth International Cryogenic Engineering Conference, 1976, ICEC, Grenoble
|
| [41] |
TangM, LiuQ. The acidity of caustic digested starch and its role in starch adsorption on mineral surfaces [J]. International Journal of Mineral Processing, 2012, 112: 94-100
|