Interactions between gas flow and reversible chemical reaction in porous media

Yuan-yong Jiang , Zeng-he Xu , Meng-zhou Zhang , Li-yuan Bai

Journal of Central South University ›› 2017, Vol. 24 ›› Issue (5) : 1144 -1154.

PDF
Journal of Central South University ›› 2017, Vol. 24 ›› Issue (5) : 1144 -1154. DOI: 10.1007/s11771-017-3517-6
Article

Interactions between gas flow and reversible chemical reaction in porous media

Author information +
History +
PDF

Abstract

Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g) + bB(s) ⇄ cC(g) + dD(s). The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.

Keywords

porous media / compressible gas flow / reversible chemical reaction / interaction

Cite this article

Download citation ▾
Yuan-yong Jiang, Zeng-he Xu, Meng-zhou Zhang, Li-yuan Bai. Interactions between gas flow and reversible chemical reaction in porous media. Journal of Central South University, 2017, 24(5): 1144-1154 DOI:10.1007/s11771-017-3517-6

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

WeiM-q, DuanY-g, FangQ-t, WangR, YuB-m, YuC-sheng. Mechanism model for shale gas transport considering diffusion, adsorption/desorption and Darcy flow [J]. Journal of Central South University, 2013, 20(7): 1928-1937

[2]

FuD, ZhouC Q, ChenYan. Numerical methods for simulating the reduction of iron ore in blast furnace shaft [J]. Journal of Thermal Science and Engineering Applications, 2014, 6(2): 1-9

[3]

GuiochonG. Flow of gases in porous media: Problems raised by the operation of gas chromatography columns [J]. Chromatographic Reviews, 1966, 8: 1-47

[4]

MengX-m, JongW, PalR, VerkooijenA, HM. In bed and downstream hot gas desulphurization during solid fuel gasification: A review [J]. Fuel Processing Technology, 2010, 91(8): 964-981

[5]

QuintardM, WhitakerS. Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions [J]. Transport in porous media, 1994, 14(2): 163-177

[6]

QuintardM, WhitakerS. Transport in ordered and disordered porous media II: Generalized volume averaging [J]. Transport in porous media, 1994, 14(2): 179-206

[7]

QuintardM, WhitakerS. Transport in ordered and disordered porous media III: Closure and comparison between theory and experiment [J]. Transport in Porous Media, 1994, 15(1): 31-49

[8]

QuintardM, WhitakerS. Transport in ordered and disordered porous media IV: Computer generated porous media for threedimensional systems [J]. Transport in Porous Media, 1994, 15(1): 51-70

[9]

QuintardM, WhitakerS. Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems [J]. Transport in Porous Media, 1994, 15(2): 183-196

[10]

QuintardM, WhitakerS. Transport in chemically and mechanically heterogeneous porous media I: Theoretical development of region-averaged equations for slightly compressible single-phase flow [J]. Advances in Water Resources, 1996, 19(1): 29-47

[11]

QuintardM, WhitakerS. Transport in chemically and mechanically heterogeneous porous media II: Comparison with numerical experiments for slightly compressible single-phase flow [J]. Advances in Water Resources, 1996, 19(1): 49-60

[12]

QuintardM, WhitakerS. Transport in chemically and mechanically heterogeneous porous media III: Large-scale mechanical equilibrium and the regional form of Darcy’s law [J]. Advances in Water Resources, 1998, 21(7): 617-629

[13]

QuintardM, WhitakerS. Transport in chemically and mechanically heterogeneous porous media IV: Large-scale mass equilibrium for solute transport with adsorption [J]. Advances in Water Resources, 1998, 22(1): 33-57

[14]

QuintardM, WhitakerS. Transport in chemically and mechanically heterogeneous porous media V: Two-equation model for solute transport with adsorption [J]. Advances in Water Resources, 1998, 22(1): 59-86

[15]

WhitakerSThe method of volume averaging [M], 1999, Netherlands, Kluwer Academic Publishers

[16]

SahimiM, GavalasG R, TsotsisT T. Statistical and continuum models of fluid-solid reactions in porous media [J]. Chemical Engineering Science, 1990, 45(6): 1443-1502

[17]

BearJKakacS, KilkisB, KulackiF A, ArincF. Modeling transport phenomena in porous media [C]. Convective heat and mass transfer in porous media. Netherlands: Kluwer Academic Publishers, 1991769

[18]

RosnerD E. High-temperature gas-solid reactions [J]. Annual Review of Materials Science, 1972, 2: 573-606

[19]

CivanFPorous Media Transport Phenomena [M], 2011, Hoboken, John Wiley and Sons

[20]

WhitakerS. Conservation Equations [C]. Gas Transport in Porous Media. Netherlands: Springer, 200671120

[21]

SeverinoG, TartakovskyD M, SrinivasanG, ViswanathanH. Lagrangian models of reactive transport in heterogeneous porous media with uncertain properties [J]. Proceedings of the Royal Society A, 2012, 468(2140): 1154-1174

[22]

DeenN G, PetersE, AJ F, PaddingJ T, KuipersJ A M. Review of direct numerical simulation of fluid-particle mass, momentum and heat transfer in dense gas-solid flows [J]. Chemical Engineering Science, 2014, 116: 710-724

[23]

BelghitA, DaguenetM, ReddyA. Heat and mass transfer in a high temperature packed moving bed subject to an external radiative source [J]. Chemical Engineering Science, 2000, 55(18): 3967-3978

[24]

TartakovskyD M, BroydaS. PDF equations for advective-reactive transport in heterogeneous porous media with uncertain properties [J]. Journal of Contaminant Hydrology, 2011, 120–121: 129-140

[25]

HallettW, GreenB, MachulaT, YangY. Packed bed combustion of non-uniformly sized char particles [J]. Chemical Engineering Science, 2013, 96: 1-9

[26]

WakaoN, KagueiSHeat and mass transfer in packed beds [M], 1982, New York, Gordon and Breach Science Publishers

[27]

NemecD, LevecJ. Flow through packed bed reactors: 1. Single-phase flow [J]. Chemical Engineering Science, 2005, 60(24): 6947-6957

[28]

NemecD, LevecJ. Flow through packed bed reactors: 2. Two-phase concurrent downflow [J]. Chemical Engineering Science, 2005, 60(24): 6958-6970

[29]

XuZ-H, SongY-T, ChengPing. An analysis of compressible flows in a packed bed with gas-solid reactions [J]. International Communications in Heat and Mass Transfer, 2006, 33(3): 278-286

[30]

JiangY-y, XuZ-h, PengX-feng. An analysis for compressible flows in a packed bed with metathesis gas-solid reaction [J]. International Communications in Heat and Mass Transfer, 2011, 38(8): 1033-1040

[31]

ErgunS. Fluid flow through packed columns [J]. Chemical Engineering Progress, 1952, 48(2): 89-94

[32]

WenC W. Noncatalytic heterogeneous solid fluid reaction models [J]. Industrial and Engineering Chemistry, 1968, 60(9): 34-54

[33]

PatankarS VNumerical heat transfer and fluid flow [M], 1980, USA, Hemisphere Publishing Corporation

[34]

TaoW-quanNumerical heat transfer [M], 2001, Xi’an, China, Xi’an Jiaotong University Press

[35]

SohnH Y, WadsworthM ERate processes of extractive metallurgy [M], 1979, New York, Plenum Press

[36]

GeigerG H, PoirierD RTransport phenomena in metallurgy [M], 1973, London, Addison-Wesley Publishing Company

[37]

SohnH Y, ChaubalP C. Rate enhancement of the gaseous reduction of iron oxide pellets by pressure cycling [J]. Transactions ISIJ, 1984, 24: 387-395

[38]

MuchiI, TamuraJ. Reaction kinetics in the blast furnace [J]. Journal of Japan Institute of Metals, 1966, 30(9): 826-831

[39]

SzekelyJ, EvansJ W, SohnH YGas-solid reaction [M], 1976, New York, Academic Press

[40]

FairbanksD F, WilkeC R. Diffusion coefficients in multicomponent gas mixtures [J]. Industrial and Engineering Chemistry, 1950, 42(3): 471-475

[41]

WeltyJ R, WicksC E, WilsonR EFundamentals of momentum, heat, and mass transfer [M], 1983, New York, John Wiley and Sons

AI Summary AI Mindmap
PDF

92

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/