PDF
Abstract
The alkali-rich rocks, spreading along the suture zone of Jingsha River, refer to the alkali-rich porphyry rocks, which emplace during the Himalaya epoch in northwest of Yunnan Province, and consist of syenit, syenit porphyry, monzonite porphyry and granite porphyry. Petrological chemical analysis results suggest that silica is poor and aluminum is rich, and high potassium large ion lithophile elements (LILE), light rare earth element (LREE) and Sr are obviously detracted in these rocks. High field strength elements (HFSE) and heavy rare earth element (HREE) are depleted, especially Nb, Ta, P and Ti. δEu: 0.09–1.64 shows that plagioclase does not appear fractional crystallization during the formation of alkali-rich rocks. δ34S, H and O isotopes and Pb isotopes suggest that ore-forming fluid is derived from the mantle, and Pb is possibly mixed by mantle, wall rock and crust. The age of Pb in alkali-rich rocks is about 250–220 Ma. The age of alkali porphyry rock (dykes) varies from 30 Ma to 50 Ma. Alkali rocks have strong metallogenetic relation. Au mineralization is associated to the alkali magmatic activities with a relatively high temperature, low pressure and high oxygen fugacity. However, copper mineralization is mainly associated with alkali-sub-alkali magmatic activities in a process of relatively low temperature, high pressure and lower oxygen fugacity.
Keywords
alkali-rich porphyry rocks
/
Sanjiang metallogenetic belt
/
geochemistry
/
metallogenetic relation
Cite this article
Download citation ▾
De-xian Zhang, Ta-gen Dai.
Petrological characteristics, geochemical feature and metallogenetic relation of alkaline-rich rocks in northwest of Yunan Province, China.
Journal of Central South University, 2011, 18(4): 1217-1225 DOI:10.1007/s11771-011-0825-0
| [1] |
BiX.-w., HuR.-z., PengJ.-t., WuK.-x., SuW.-c., ZhanX.-zhi.. Geochemical characteristics of the Yao’an and Machangqing alkali-rich intrusions [J]. Acta Geologica Sinica, 2005, 21(1): 113-124
|
| [2] |
ChenK.-x., LuY.-f., WeiJ.-q., DongF.-l., FanY.-hua.. Petrological and geochemical feature of alkali-rich complex in Yao’an of Yunnan Province [J]. Mineral Deposit, 2002, 21(Supplement): 361-364
|
| [3] |
WeiJ.-q., CehnK.-x., HeL.-qin.. Discussion on Tectonic setting of volcanic rocks in Yanla district of Deqin country [J]. Yunnan Geology, 1998, 18(1): 53-62
|
| [4] |
FanY.-h., LiW.-chang.. Geological characteristics of Pulang porphyry Cu deposit in Yunnan province [J]. Geology in China, 2006, 33(4): 352-362
|
| [5] |
ZengP.-s., WangH.-p., MoX.-x., YuX.-h., LiW.-c., LiT.-g., LiH., YangC.-zhi.. Tectonic setting and prospects of porphyry copper deposits in Zhongdian island arc belt [J]. Acta Geoscientia Sinica, 2004, 2(5): 535-540
|
| [6] |
ChungS.-l., LeeT. Y., LoC. H., WangP.-l., ChenC. Y., YemN. T., HoaT. T., WuG.-yao.. Intraplate extension prior to continental extrusion along the Ailao Shan Red River shear zone [J]. Geology, 1997, 25(4): 311-314
|
| [7] |
ChungS.-l., LiuD.-y., JiJ.-q., ChuM.-f., LeeH.-y., WenD. J., LoC. H., LeeT. Y., QianQ., ZhangQi.. Adakites from continental collision zones: Melting of thickened lower crust beneath southern Tibet [J]. Geology, 2003, 31(11): 1021-1024
|
| [8] |
HouZ.-q., ZawK., PanG.-t., MoX.-x., XuQ., HuY.-z., LiX.-zhen.. The Himalayan Yulong porphyry copper belt: Product of large-scale strike-slip faulting in eastern Tibet [J]. Economic Geology and the Bulletin of the Society of Economic Geologists, 2003, 98(1): 125-145
|
| [9] |
HouZ.-q., ZengP.-s., GaoY.-f., DuA.-d., FuD.-ming.. Sanjiang Tethyan metallogenesis in SW China: Tectonic setting, metallogenic epochs and deposit types [J]. Ore Geology Reviews, 2007, 31(1/4): 48-87
|
| [10] |
TurnerS., HawkesworthC., LiuJ.-q., RogersN., KelleyS., CalsterenP. V.. Timing of Tibetan uplift constrained by analysis of volcanic rocks [J]. Nature, 1993, 364: 50-54
|
| [11] |
YinA., HarrisonT. M.. Geologic evolution of the Himalayan-Tibetan orogen [J]. Annual Review of Earth and Planetary Sciences, 2000, 28: 211-280
|
| [12] |
ZhangY.-q., XieY.-w., TuG.-chi.. A preliminary study on the relationship between rift and Ailaoshan-Jinshajiang Alkaline intrusive rocks [J]. Acta Petrologica Sinca, 1987, 3(1): 17-25
|
| [13] |
ArnaudN. O., VidalP. H., TapponnierP.. The high-K2O volcanism of northwestern Tibet: Geochemistry and tectonic implications [J]. Earth Planet Science Letter, 1992, 111: 351-367
|
| [14] |
GeL.-s., GuoX.-d., ZouY.-l., LiZ.-h., XinJ.-bing.. Genesis and geochemical characteristics of alkali-rich rock bodies(dykes) in the northwest Yunnan province [J]. Geology and Prospect, 2003, 18: 36-42
|
| [15] |
GeL.-s., GuoX.-d., ZouY.-l., LiZ.-h., XinJ.-bing.. Geology and petrological characteristics of alkali-rich rocks bodies (dykes) in the northwest Yunnan Province [J]. Mineral Resources and Geology, 2002, 16: 147-153
|
| [16] |
TuG.-c., ZhangY.-q., WangZ.-g.Geochemistry of granite in southern of Tibet [M], 1982, Beijing, Science and Tecnology Press: 1-190
|
| [17] |
TuG.-c., ZhangY.-q., ZhaoZ.-hua.A preliminary study on the two alkali-rich intrusive rock belts in south China in geology of granite and its relations with mineralization [M], 1984, Nanjing, Jiangsu Science and Technology Press: 21-37
|
| [18] |
XieY.-w., ZhangY.-q., Zhongs.-lin.. Trace element characteristics of tecenozoic high-k alkaline magmatic rock series in the eastern erhai, Yunnan province [J]. Acta Petrologica Sinica, 1999, 15(1): 75-82
|
| [19] |
HuX.-z., HuangZheng.. Petrology and petrogenesis of the Yangtze platform western margin’s alkali-rich granite porphyry [J]. Geotectonic et Metallogenia, 1997, 21(2): 173-180
|
| [20] |
LaiJ.-q., PengS.-l., ShaoY.-jun.. Tectonic control for petrogenesis and metallogenesis of the alkali-rich porphyry in Central Yunnan [J]. Mineral Resources and Geology, 1998, 12(63): 20-25
|
| [21] |
BiX.-w., CornellD. H., HuR.-zhong.. REE composition of primary and altered feldspar from the mineralized alteration zone of alkaline intrusive rocks, western Yunnan Province, China [J]. Ore Geology Reviews, 2002, 19(1/2): 69-78
|
| [22] |
BiX.-w., HuR.-z., CornellD. H.. The alkaline porphyry associated Yao’an gold deposit, Yunnan, China: Rare earth element and stable isotope evidence for magmatic-hydrothermal ore formation [J]. Mineralium Deposita, 2004, 39(1): 21-30
|
| [23] |
BurnardP. G., HuR.-z., TurnerG., BiX.-wu.. Mantle, crustal and atmospheric noble gases in Ailaoshan Gold deposits, Yunnan Province, China [J]. Geochimica et Cosmochimica Acta, 1999, 63(10): 1595-1604
|
| [24] |
DengW.-m., HuangX., ZhongD.-lei.. Petrological characteristics and genesis of Genozoic alkali-rich porphyry in western Yunnan, China [J]. Science in China Series D: Earth Sciences, 1998, 33(4): 412-424
|
| [25] |
DongF.-l., MoX.-x., YuX.-h., HouZ.-q., WangYong.. Trace elements geochemical and Nd-Sr-Pb isotopes characteristics of the Zhuopan alkaline complex in Yongping, Yunnan Province and its geological significance [J]. Acta Petrologica Sinica, 2007, 23(5): 986-994
|
| [26] |
HuR.-Z., BurnardP. G., BiX.-w., ZhouM.-F., PenJ.-T., SuW.-C., WuK.-Xing.. Helium and argon isotope geochemistry of alkaline intrusion-associated gold and copper deposits along the Red River-Jinshajiang fault belt, SW China [J]. Chemical Geology, 2004, 203(3/4): 305-317
|
| [27] |
LiuX.-f., ZhanX.-z., GaoZ.-m., LiuJ.-j., LiC., SuW.-chao.. Deep xenoliths in alkalic porphyry, Liuhe, Yunnan, and implications to petrogenesis of alkalic porphyry and associated mineralizations [J]. Science in China Series D: Earth Sciences, 1999, 42(6): 627-635
|
| [28] |
WangJ., LiJ.-p., WangJ.-hai.. Geological implications for the mafic enclaves of deep derivation from cenozoic shashonitic rocks in Jianchuan-Dali area, western Yunnan [J]. Acta Mineralogica Sinica, 2002, 22(2): 113-125
|
| [29] |
RockN. M. S.Lamprophyres [M], 1991, Blackie, Glasgow: 1-157
|
| [30] |
QIN Jian-hua, DIN Jun, ZHANG De-xian, RUSK Brian, LIU Cai-ze, ZHANG Qi-ming. Tectonic settings of porphyry Cu-Mo-Au deposits in the Himalayan-Tibetan orogen, East Tethys [J]. International Geology Review, 2011. (in Press)
|
| [31] |
HouZ.-q., ZengP.-s., GaoY.-f., DuA.-d., FuD.-ming.. Himalayan Cu-Mo-Au mineralization in the eastern Indo-Asian collision zone: Constraints from Re-Os dating of molybdenite [J]. Mineralium Deposita, 2006, 41(1): 33-45
|
| [32] |
XuX.-w., CaiX.-P., XiaoQ.-b., PetersS. G.. Porphyry Cu-Au and associated polymetallic Fe-Cu-Au deposits in the Beiya Area, western Yunnan Province, south China [J]. Ore Geology Reviews, 2007, 31(1/4): 224-246
|
| [33] |
YanM.-h., DengW., ChenP.-qin.. Recent trends of temperature and precipitation disturbed by large-scale reclamation in the sangjiang plain of China [J]. Chinese Geographical Science, 2003, 13(4): 317-321
|
| [34] |
ZhuD.-c., Chungs.-L., MoX.-x., ZhaoZ.-d., NiuY.-l., SongB., YangY.-heng.. The 132 Ma Comei-Bunbury large igneous province: Remnants identified in present-day southeastern Tibet and southwestern Australia [J]. Geology, 2009, 37(7): 583-586
|
| [35] |
KappP., MurphyM. A., YinA., HarrisonT. M., DingL., GuoJ. H.. Mesozoic and Cenozoic tectonic evolution of the Shiquanhe area of western Tibet [J]. Tectonics, 2003, 22(4): 1-24
|
| [36] |
ZhaoW.-j., NelsonK. D., CheJ., QuoJ., LuD., WuC., LiuX.. Deep seismic-reflection evidence for continental underthrusting beneath southern tibet [J]. Nature, 1993, 366(6455): 557-559
|
| [37] |
WangT.-fen.Mesozoic-Cenozoic tectonic deformation and paleo field stress of western China [M], 1992, Beijing, Geology Publishing House: 1-101
|
| [38] |
WuY.-h., GeL.-s., XingJ.-b., ZouY.-l., GuoX.-d., LiZ.-hua.. Metallogenic model of Cenozoic alkali-rich porphyies-related Au deposits in northwest Yunnan Province, China [J]. Geology and Prospect, 2004, 19(3): 159-167
|
| [39] |
ZengP.-s., MoX.-x., YuX.-hui.. Preliminary research on the intermediate acidic porphyries and their ore-bearing feature in Zhongdian island-arc, northwest of Yunnan Province [J]. Acta Geologica Sinica, 1999, 20(Supplement): 359-366
|
| [40] |
ZengP.-s., MoX.-x., YuX.-h., HouZ.-q., XuQ.-d., WangH.-p., LiH., YangC.-zhi.. Porphyries and porphyry copper deposits in Zhongdian area, northwest of Yunnan, China [J]. Mineral Deposits, 2003, 20(4): 393-400
|
| [41] |
LuoJ.-lie.The division of Unit-sperunit of Himalayan epoch porphyry in western of Yunnan province and relationship between it and Jingding gaint deposit—Study on the Himalayan endogenetic ore-process [M], 2001, Beijing, Seismic Press: 229-242
|
| [42] |
ZhangS.-t., ZhaoP.-da.. The ore-forming spectrum of the Himalayan alkali-rich porphyry in northwestern Yunnan Province [J]. Acta Geologica Sinica, 2003, 24(Supplement): 89-93
|
| [43] |
ZhangY.-q., XieY.-w., LiX.-hua.. The isotopic characteristic of K balsalt magmatic rocks in eastern Tibet platform: Implication for lithoid and tectonic [J]. Science in China Series D: Earth Sciences, 2000, 30(5): 493-498
|
| [44] |
XuX.-w., CaiX.-p., ZhangB. L., YingH. L., XiaoQ.-b., WangJian.. Petrologic, chronological and geochemistry characteristics and formation mechanism of alkaline porphyries in the Beiya gold district, western Yunnan [J]. Acta Geologica Sinica, 2006, 22(3): 631-642
|
| [45] |
WangJ., LiJ.-ping.. High balsalt magmatic process: Implication for geochemistry of magmatic ore process in later collision and strike slip extension setting in Dali-Jiangchuan, western of Yunnan province [J]. Acta Geologica Sinica, 2003, 19(1): 61-69
|
| [46] |
LiangH.-y., MoJ.-h., SunW.-d., ZhangY.-q., ZengT., HuG.-q., CharlloteAllen.. Study on geochemical composition and isotope ages of the Malasongduo porphyry associated with Cu-Mo mineralisation [J]. Acta Geologica Sinica, 2009, 25(2): 385-392
|
| [47] |
PangZ.-s., DuY.-s., WangG.-w., GuoX., CaoY., LiQing.. Single-grain Zircon U-pb isotopic ages, geochemistry and its implication of the Pulang complex in Yunnan province, China [J]. Acta Geologica Sinica, 2009, 25(1): 159-165
|
| [48] |
WangS.-x., ZhangX.-c., LengC.-b., QinC.-j., WangW.-q., ZhaoM.-chun.. stable isotopic composition of the Hongshan skarn copper deposit in the zhongdian area and its implication for the copper mineralization process [J]. Acta Geologica Sinica, 2008, 24(3): 480-488
|
| [49] |
ZengP.-s., LiW.-c., WangH.-p., LiHong.. The Indosinian Pulang superlarge porphyry copper deposit in Yunnan, China: Petrology and chronology [J]. Acta Geologica Sinica, 2006, 22(4): 989-1000
|
| [50] |
DengW.-m., HuangX., ZhongD.-lei.. Alkali-rich porphyry and its relation with intraplate deformation of north part of Jinsha River belt in western Yunnan, China [J]. Science in China Series D: Earth Sciences, 1998, 41(3): 297-305
|
| [51] |
ChappellB. W., WhiteA. J. R., HineR.. Granite provinces and basement terranes in the Lachlan Fold Belt, southeastern Australia [J]. Australian Journal of Earth Sciences: An International Geoscience Journal of the Geological Society of Australia, 1988, 35(4): 505-521
|
| [52] |
CornellD. H., SchutteS. S., EglingtonB. L.. Ongeluk basaltic andesite formation in Griqualand West, South Africa: Submarine alteration in a 2 222 Ma Proterozoic sea [J]. Precambrian Research, 1995, 79: 101-123
|
| [53] |
SunS. S., McdonoughW. F.. Chemical and isotopic systematics of oceanic basalts: Implications for mantle composition and processes [M]. Magmatism in the ocean basins, 1989, London, Geological Society: 313-345
|
| [54] |
BiX.-w., HuR.-z., CornelD. H.. Trace element and isotope evidence for the evolution of ore-forming fluid of Yao’an gold deposit, Yunnan province, China [J]. Geochemistry, 2001, 30(1): 264-272
|
| [55] |
ChengJ., XiaB., ZhangY.-quang.. Petrological and geochemical characteristics of Yao’an alkaline complex in Yunnan Province [J]. Geotectonica et Metallogenia, 2007, 31(1): 118-125
|
| [56] |
QianX.-g., LiZ.-w., BaiJian.. A preliminary study on the genetic mechanism of Yao’an Au deposit [J]. Yunnan Geology, 2000, 21(1): 42-49
|
| [57] |
LeeH.-y., ChungS.-l., WangJ.-r., WenD.-j., LuoC.-h., YangT. F., ZhangY.-q., XieY.-w., LeeT.-Y., WuG.-y., JiJ.-qing.. Miocene Jiali faulting and its implications for Tibetan tectonic evolution [J]. Earth and Planetary Science Letters, 2003, 205(3/4): 185-194
|
| [58] |
LiuX.-f., YangZ.-x., LiuJ.-d., WuD.-c., ZhangC.-j., LiY.-guo.. Geochemical trace of silicon isotopes of intrusions and ore veins related to alkali-rich porphyry deposits in western Yunnan, China [J]. Acta Geologica Sinica, 2004, 78(2): 459-462
|
| [59] |
WangA.-j., CaoD.-h., GaoL., WangG.-shan.. A proble into the genesis of Jinding supper-large lead-zinc ore deposit [J]. Acta Geologica Sinica, 2009, 83(1): 43-54
|
| [60] |
XueC.-d., HouZ.-q., LiuX., YangZ.-m., LiuY.-q., HaoB.-wu.. Petrogenesis and metallogenesis of the Beiya gold-polymetallic ore district, northwestern Yunnan province, China: Responses to the Indo-Asian collisional processes [J]. Acta Petrologica Sinica, 2008, 24(3): 457-472
|
| [61] |
XueC.-j., ZengR., LiuS.-w., ChiG.-x., QingH.-r., ChenY.-c., YangJ.-m., WangD.-hong.. Geologic, fluid inclusion and isotopic characteristics of the Jinding Zn-Pb deposit, western Yunnan, South China: A review [J]. Ore Geology Reviews, 2007, 31(1/4): 337-359
|
| [62] |
GongR.-x., LuC.-zhong.. Petrogeochemistry of Late Mesozoic alkali-rich potassium-high granitoid in western Zhejiang and its tectonic significance [J]. Acta Petrologica Sinica, 2008, 24(10): 2343-2351
|
| [63] |
LuF.-x.The petrology of Mantle [M], 1988, Wuhan, Press of China University of Geoscience: 1-346
|
| [64] |
ZhengY.-fei.Chemical geodynamics [M], 1999, Beijing, Science Press: 1-392
|
| [65] |
ColemanM., HodgesK.. Evidence for Tibetan plateau uplift before 14-Myr ago from a New Minimum Age for east-west extension [J]. Nature, 1995, 374(6517): 49-52
|
| [66] |
WangJ., LiJ.-p., WangJ.-h., MaZ.-hong.. Gelogical implications for the mafic envlaves of deep derivation from cenozoic shoshonitic rocks in Jianchuan-Dali area, western Yunnan [J]. Acta Geologica Sinica, 2001, 22(2): 113-125
|
| [67] |
ZhangY.-q., XieY.-w., TuG.-chi.. Nd, Sr isotopic character and chronology of Ailaoshan-Jinshajiang alkali-rich intrusive rocks [J]. Science in China Series D: Earth Sciences, 1997, 27: 289-293
|
| [68] |
PengJ.-t., BiX.-w., HuR.-z., WuK.-x., SanH.-qing.. Determination of ore- and rock-forming time of the machgqing porphyry Cu(Mo) deposit, western Yunnan province [J]. Acta Mineralogica Sinica, 2005, 25(1): 69-74
|
| [69] |
WengH.-j., QiuY.-z., HuY.-g., YuG.-jun.. Geological character and ore-control condition of porphyry gold deposits in western-northwestern Yunnan [J]. Geology and Prospecting, 2003, 39(3): 14-19
|
| [70] |
ChuM.-f., ChungS.-l., SongB., LiuD.-y., O’ReillyS. Y., PearsonN. J., JiJ.-q., WenD.-jen.. Zircon U-Pb and Hf isotope constraints on the Mesozoic tectonics and crustal evolution of southern Tibet [J]. Geology, 2006, 34(9): 745-748
|