Structure characteristics and adhesive property of humic substances extracted with different methods

Yuan-bo Zhang , Gui-hong Han , Tao Jiang , Yan-fang Huang , Guang-hui Li , Yu-feng Guo , Yong-bin Yang

Journal of Central South University ›› 2011, Vol. 18 ›› Issue (4) : 1041 -1046.

PDF
Journal of Central South University ›› 2011, Vol. 18 ›› Issue (4) : 1041 -1046. DOI: 10.1007/s11771-011-0801-8
Article

Structure characteristics and adhesive property of humic substances extracted with different methods

Author information +
History +
PDF

Abstract

The structure characteristics and adhesive property of humic substance (HS) extracted with different methods were mainly studied by terms of elementary analysis, visible spectrum, FT-IR spectroscopy, viscosity, adsorption and pelletizing experiments. The results show that HSs extracted with new method (HS-a) own higher degree of aromatization and polymerization, larger relative molecular mass and more polar functional groups than HS extracted with usual method (HS-b). The viscosity of HS-b is about 30–40 mPa·s lower than that of HS-a. The maximum adsorption amounts of HS-a and HS-b onto iron concentrates are 9.11 mg/g and 8.08 mg/g, respectively. Meanwhile, HS-a has a better performance than HS-b in the practical application for pelletizing of iron concentrates. The difference in agglomeration behaviors with iron concentrates lies in the differences of the structure characteristics of HSs. With higher content of polar functional groups, larger relative molecular mass and viscosity of HSs, the agglomeration behavior is improved.

Keywords

humic substances / structure characteristic / agglomeration behaviour / green ball

Cite this article

Download citation ▾
Yuan-bo Zhang, Gui-hong Han, Tao Jiang, Yan-fang Huang, Guang-hui Li, Yu-feng Guo, Yong-bin Yang. Structure characteristics and adhesive property of humic substances extracted with different methods. Journal of Central South University, 2011, 18(4): 1041-1046 DOI:10.1007/s11771-011-0801-8

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

ALLEN A P. The role of binders in the agglomeration of minerals [C]// Proceeding of 5th International Symposium on Agglomeration, UK, 1989: 215–223.

[2]

SUZUKI S, GOMI S. New organic pellet binder from bituminous materials [C]// Symposium on Pellets and Granules. Newcastle, 1994, 157–169.

[3]

HEERMA R H, KORTMAN H, KATER T. Improvements of acid, olivine and dolomite fluxed iron ore pellets using an organic binder [C]// Proceeding of 5th International Symposium on Agglomeration, UK, 1998: 227–239.

[4]

JIANG Tao, QIU Guan-zhou, ZHU De-qing, FAN Xiao-hui, HUANG Zhu-cheng. A new process of coal-based direct reduction of iron concentrates pellets-CBP process [C]// Proceeding of 60th Iron-making Conference. Baltimore, 2001: 803.

[5]

HAN Gui-hong, ZHANG Yuan-bo, HUANG Yan-fang, LI Guang-hui, JIANG Tao. Adsorption behaviours of humic substances onto iron ore particle surface [C]// XXV Internal Mineral Processing Congress. Brisbane, 2010: 163–171.

[6]

JiangT., HanG.-h., ZhangY.-b., HuangY.-f., LiG.-h., GuoY.-f., YangY.-bin.. Improving the extraction yield of humic substances (HS) from lignite with anthraquinone (AQ) in alkaline solution [J]. Journal of Central South University of Technology, 2011, 18(1): 68-72

[7]

LiangC.-s., DangZ., LiuC.-qiang.. Structure characterization of soil humic acids and adsorption equilibria on phenanthrene [J]. Chinese Journal of Analytical Chemistry, 2006, 3(24): 288-292

[8]

PeuravuoriJ., ZbankovaP., PihlajA. K.. Aspects of structural features in lignite and lignite humic acids [J]. Fuel Processing Technology, 2006, 87: 829-839

[9]

Be’atriceA.. A comparative study on the chemical composition of humic acids from forest soil, agricultural soil and lignite deposit Bound lipid, carbohydrate and amino acid distributions [J]. Gendarme, 2006, 130: 77-96

[10]

HenriqueR.. Oxidation of humic substances of peat during alkaline extraction: Infrared and visible spectroscopic study [J]. Quim Nova, 1998, 47(1): 25-28

[11]

LiuG.-g., QiuG.-z., HuY.-hua.. Study on infrared spectra of coals [J]. Journal of Central South University: Science and Technology, 1999, 30(4): 371-373

[12]

LiuG.-g., QiuG.-z., XuJ.-cang.. Study on spectroscopy of HA type binder [J]. Journal of Central South University: Science and Technology, 2003, 34(3): 238-241

[13]

LiH.-x., JiangT., QiuG.-z., WangD.-zuo.. Molecular structure model and selecting criterion of organic binder for iron ore pellet [J]. Journal of Central South University: Science and Technology, 2000, 31(1): 17-20

[14]

QiuG.-z., JiangT., LiH.-x., WangD.-zuo.. Functions and molecular structure of organic binders for iron ore pelletization [J]. Colloids and Surfaces A: Physicochemistry, 2003, 224: 11-22

[15]

PeuravuoriJ., PihlajaK.. Molecular size distribution and spectroscopic properties of aquatic humic substances [J]. Analytica Chimica Acta, 1997, 337: 133-149

[16]

LiuG.-gen.A study on HA-type binders for direct reduction of cold bond pellets and its raw material characteristics [D], 1997, Changsha, Central South University

[17]

QiuG.-z., JiangT., XuJ.-cang.Direct reduction of cold-Bonded pellets [M], 2001, Changsha, Central South University Press: 115-120

[18]

QiuG.-z., JiangT., FaK.-q., ZhuD.-q., WangD.-z.. Interfacial characterizations of iron ore concentrates affected by binders [J]. Powder Technology, 2004, 139: 1-6

AI Summary AI Mindmap
PDF

108

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/