Effects of temperature, particle size, and air humidity on sensibility of typical high-energetic explosives

Sanzhen WU , Mingkun FANG , Xingliang WU , Guangfei GUO , Junhong WANG , Sen XU

Journal of Measurement Science and Instrumentation ›› 2024, Vol. 15 ›› Issue (3) : 408 -416.

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Journal of Measurement Science and Instrumentation ›› 2024, Vol. 15 ›› Issue (3) :408 -416. DOI: 10.62756/jmsi.1674-8042.2024042
Test and detection technology
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Effects of temperature, particle size, and air humidity on sensibility of typical high-energetic explosives

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Abstract

The production and utilization of high-energetic explosives often pose a range of safety hazards, with sensitivity being a key factor in evaluating these risks. To investigate how temperature, particle size, and air humidity affect the responsiveness of commonly used high-energetic explosives, a series of BAM(Bundesanstalt für Materialforschung und-prüfung) impact and friction sensitivity tests were carried out to determine the critical impact energy and critical load pressure of four representative high-energetic explosives (RDX, HMX, PETN and CL-20) under different temperatures, particle sizes, and air humidity conditions. The experimental findings facilitated an examination of temperature and particle size affecting the sensitivity of high-energetic explosives, along with an assessment of the influence of air humidity on sensitivity testing. The results clearly indicate that high-energetic explosives display a substantial decline in critical reaction energy when subjected to micrometre-sized particles and an air humidity level of 45% at a temperature of 90 ℃. Furthermore, it was noted that the critical reaction energy of high-energetic explosives diminishes with an increase in temperature within 25 ℃-90 ℃. In the same vein, as the particle sizes of high-energetic explosives increase, so does the critical reaction energy for micrometre-sized particles. High air humidity significantly affects the sensitivity testing of high-energetic explosives, emphasizing the importance of refraining from conducting sensitivity tests in such conditions.

Keywords

high-energetic explosives / temperature / particle size / air humidity / critical reaction energy

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Sanzhen WU, Mingkun FANG, Xingliang WU, Guangfei GUO, Junhong WANG, Sen XU. Effects of temperature, particle size, and air humidity on sensibility of typical high-energetic explosives. Journal of Measurement Science and Instrumentation, 2024, 15(3): 408-416 DOI:10.62756/jmsi.1674-8042.2024042

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References

[1]

LIANG L, CHANG Z P, ZHANG Z J, et al. Controllable batch preparation and desensitization technology of superfine CL-20. Aerospace Shanghai (Chinese & English), 2020, 37(4): 148-154.

[2]

GUO H L, HUANG Y F, JING P G, et al. Research progress on impact sensitivity of explosive. New Chemical Materials, 2022, 50(5): 10-15.

[3]

HUANG X C, QIN M N, TANG W, et al. Progress of decreasing sensitivity of HMX. New Chemical Materials, 2014, 42(4): 20-23.

[4]

LI G, GENG X H, WANG J Y, et al. Mechanical sensitivity of PETN with different particle sizes. Journal of Ordnance Equipment Engineering, 2009, 30(6): 79-81.

[5]

WANG J L, ZHANG H B, LIU C Z, et al. Production Process to Control Particle Size of Hexanitrohexaazaisowurtzitane. Chinese Journal of Energetic Materials, 2021, 29(4): 285-292.

[6]

LIU D M, XIAO J J, ZHU W, et al. MD study of PETN crystal susceptibility discrimination and mechanical property prediction at different temperatures. Chinese Journal of Energetic Materials, 2013, 21(5): 563-569.

[7]

TANG Y X, GAO H X, MITCHELL L A, et al. Enhancing energetic properties and sensitivity by incorporating amino and nitramino groups into a 1, 2, 4-oxadiazole building block. Angewandte Chemie International Edition, 2016, 55 (3): 1147-1150.

[8]

ZHANG Y X, YANG Y, CHEN S, et al. Effect of moisture content on mechanical sensitivity and thermal decomposition of RDX. Ordnance Industry Automation, 2017 (7): 5-8.

[9]

YIN Y T, LI H, CAO Z H, et al. Crystallographic orientation dependence on nanoscale friction behaviour of energetic β-HMX crystal. Friction, 2023, 11(12): 2264-2277.

[10]

SHA Y, ZHANG X B. Impact sensitivity and moisture adsorption on the surface of CL-20/TNT cocrystal by molecular dynamics simulation. Applied Surface Science, 2019, 483: 91-97.

[11]

LIU C, YE B Y, LIU Q, et al. Preparation and characterization of FOX-7 explosives with different shapes. Chinese Journal of Energetic Materials, 2022, 30(7): 659-665.

[12]

WU X L, WANG H S, LI W H, et al. Experimental study on critical response threshold of RDX and HMX under mechanical Stimulation. Explosive Materials, 2020, 49(6): 9-14.

[13]

WU Y Q, DUAN H Z, YANG K, et al. Ignition and combustion developments of granular explosive (RDX/HMX) in response to mild‐impact loading. Propellants, Explosives, Pyrotechnics, 2020, 45(8): 1250-1268

[14]

WANG X J, GUO W X, LI Y N, et al. Influence of process temperatures on the coating effect and impact sensitivity of F2604 /HMX composite particles. Chinese Journal of Explosives & Propellants, 2020, 43(1): 45-50.

[15]

LAI W P, WEI T, LIAN P, et al. Theoretical study on effects of particle size on impact sensitivities of nitroimines energetic compounds. Computers and Applied Chemistry, 2014, 31(7): 894-896.

[16]

LIU Y C, WANG J H, AN C W, et al. Effect of particle size of RDX on mechanical sensitivity. Chinese Journal of Explosives and Propellants, 2004, 27(2): 7-9.

[17]

YUAN J M, ZHANG Q M, LIU Y. Comparative study of explosive susceptibility test Langley method and elevation method. Chinese Journal of Energetic Materials, 2008(1): 86-89.

[18]

ROBBINS H, MONRO S. A stochastic approximation method. The annals of mathematical statistics, 1951,22(3): 400-407.

[19]

TIAN Y B, WANG D P, FANG Y F. Comparative study of pyrotechnic firing point estimation methods. Chinese Journal of Energetic Materials, 2010, 18(1): 58-62.

[20]

ZEMAN S, JUNGOVÁ M. Sensitivity and performance of energetic materials. Propellants, Explosives, Pyrotechnics, 2016, 41(3): 426-451.

[21]

GRUHNE M S, LOMMEL M, WURZENBERGER M H H, et al. OZM ball drop impact tester (BIT-132) vs. BAM standard method-a comparative investigation. Propellants, Explosives, Pyrotechnics, 2020, 45(1): 147-153.

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