Performance of rice-hull-PE composite exposed to natural weathering

Wei-hong Wang , Fan-hua Bu , Zheng-ming Zhang , Shu-juan Sui , Qing-wen Wang

Journal of Forestry Research ›› 2010, Vol. 21 ›› Issue (2) : 219 -224.

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Journal of Forestry Research ›› 2010, Vol. 21 ›› Issue (2) : 219 -224. DOI: 10.1007/s11676-010-0036-9
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Performance of rice-hull-PE composite exposed to natural weathering

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Abstract

Rice-hull powder is widely used in manufacturing reinforced plastic composites. However, its weathering ability is rarely considered. We studied the performance of two types of rice-hull-polyethylene (RH-PE) composites after they were exposed outdoor to natural weathering for two years. The samples did not change in bending strength and elasticity modulus. At the end of the testing period, colour lightness had increased by more than 23% and total colour had changed by more than 9 units. This means the colour evidently differentiate from the original colour that the customers choose. The analyses of Fourier-transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) showed that oxidation had occurred on sample surfaces. Red lumber presented an obvious C=O peak after weathering, while yellow lumber did not present an obvious peak as evidence of oxidation. Both types of lumbers showed a reduction of lignocellulosic groups and amorphous regions of PE.

Keywords

rice-hull / polyethylene / composites / weathering

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Wei-hong Wang, Fan-hua Bu, Zheng-ming Zhang, Shu-juan Sui, Qing-wen Wang. Performance of rice-hull-PE composite exposed to natural weathering. Journal of Forestry Research, 2010, 21(2): 219-224 DOI:10.1007/s11676-010-0036-9

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References

[1]

Castellan A., Nourmamode A., Jaeger C., Forsskahl I.. Photochemistry of methoxy-p-benzoquinone and methoxyhydroquinone in solid 2-hydropxypropyl cellulose films and on filter paper: UV/ VIS (UV/visible light) absorption and diffuse reflectance spectroscopy studies. Nord Pulp Paper Res, 1993, 8: 239-244.

[2]

Colom X., Canavate J., Page’s P., Saurina J., Carrasco F.. Changes in crystallinity of the HDPE matrix in composites with cellulosic fiber using DSC and FTIR. J Rein Plas Comp, 2000, 19(10): 818-830.

[3]

Falk RH, Lundin T, Felton C. 2000. The effects of weathering on wood-thermoplastic composites intended for outdoor applications. In: Proceedings of the 2nd Annual conference on durability and disaster mitigation in wood-frame housing. Madison, WI, USA, pp. 175–179.

[4]

Heitner C.. Light induced yellowing of wood containing papers. Photochemistry of lignocellulosic materials. 1993, New York, USA: American Chemical Society, 3 25

[5]

Hon D.-S.. Hon D.-S., Shiraishi N.. Weathering and photochemistry of wood. Wood and cellulostic chemistry. 2001, New York: Marcel Dekker, 513 546

[6]

Klyosov A.A.. Wood-Plastic Composite. 2007, New Jersey, USA: John Wiley & Sons, Inc., Publication. Hoboken

[7]

Li C., Ragauskas A.J.. Brightness reversion of mechanical pulps. Part XVII: diffuse reflectance study on brightness stabilization by additives under various atmospheres. Cellulose, 2000, 7(4): 369-385.

[8]

Matuana L.M., Kamdem D.P., Zhang J.. Photoaging and stabilization of rigid PVC/woodfiber composites. J Appl Polym. Sci., 2001, 80(11): 1943-1950.

[9]

Muasher M., Sain M.. The efficacy of photostabilizers on the color change of wood filled plastic composites. Polym Degradation Stab, 2006, 91(5): 1156-1165.

[10]

Ragauskas A.J.. Heitner C., Scaiano J.C.. Photoreactivity of lignin like quinoid structures. Photochemistry of lignocellulostic materials. 1993, Washington, USA: American Chemical Society, 77 85

[11]

Seldén R., Nystrom B., La ngström R.. UVaging of poly (propylene)/woodfiber composites. Polym Compos, 2004, 25(5): 543-553.

[12]

Stark N.M., Matuana L.M.. Characterization of weathered wood-plastic composite surfaces using FTIR spectroscopy, contact angle, and XPS. Polym Degradation Stab, 2007, 92(10): 1883-1890.

[13]

Stark N.M., Matuana L.M., Clemons C.M.. Effect of processing method on surface and weathering characteristics of wood-flour/HDPE composites. J Appl Polym Sci, 2004, 93(3): 1021-1030.

[14]

Stark N.M., Matuana L.M.. Surface chemistry changes of weathered HDPE/wood-flour composites studied by XPS and FTIR spectroscopy. Polym Degradation Stab, 2004, 86(1): 1-9.

[15]

Stark N.M.. Effect of weathering cycle and manufacturing method on performance of wood flour and high-density polyethylene composites. J. Appl Polym Sci, 2006, 100(4): 3131-3140.

[16]

Zhang L, Gellerstedt G. 1998. Quinone formation and their contribution to photoyellowing in lignin. In: Fifth European workshop on lignocellulostics and pulp proceedings. Averio, Portugal, pp. 285–289.

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