Characterization of Arroyo Verde Epithermal Deposit: Paragenesis, Mineral Geochemistry, Geochronology and Fluid Inclusions in Lower Chon Aike Volcanism, Argentina

Cecilia Pavón Pivetta, Leonardo Benedini, Paulo Marcos, Ma. Agustina Cócola, Mercedes Virginia Barros, Daniel Gregori, Leonardo Strazzere, Anderson Costa dos Santos, Mauro C. Geraldes

Journal of Earth Science ›› 2024, Vol. 35 ›› Issue (1) : 62-84. DOI: 10.1007/s12583-023-1823-5
Geochemistry and Mineral Deposits

Characterization of Arroyo Verde Epithermal Deposit: Paragenesis, Mineral Geochemistry, Geochronology and Fluid Inclusions in Lower Chon Aike Volcanism, Argentina

Author information +
History +

Abstract

Arroyo Verde epithermal deposit, in the North Patagonia region of Argentina, is located within the Lower Chon Aike volcanism and is developed between 192.6 ± 2.5 Ma (mineralization host rock) and 189.5 ± 2.6 Ma (overlying lava). Marifil volcanic complex is the host rock for these veins, veinlets and breccias. This particular small deposit has developed low to intermediate sulphidation characteristics, with gangue mineral textures associated with several ore minerals. Electron probe microanalysis determines electrum, silver minerals such as acanthite, and tetrahedrite, related Ag-Cu minerals like jalpaite, mckinstryite, stromeyerite, and base metals like chalcopyrite, sphalerite, galena and pyrite. Fluid inclusions in quartz of two out of five events indicate that these Low Jurassic veins were formed due to subtle boiling and dilution mechanisms and by low-salinity (3.4 wt.% to 6.7 wt.% NaCl Eq) magmatic-hydrothermal fluid at 225 to 310 °C. The fluid inclusion measurements that indicate boiling (Event 3) were plotted, and based on this data, we interpret that the Arroyo Verde deposit has been eroded between 550 and 700 m. This particular character has not been previously recorded for other sectors of the eastern north Patagonian region.

Keywords

epithermal deposit / Ag minerals / mineral geochemistry / fluid inclusions / Chon Aike geo-chronology

Cite this article

Download citation ▾
Cecilia Pavón Pivetta, Leonardo Benedini, Paulo Marcos, Ma. Agustina Cócola, Mercedes Virginia Barros, Daniel Gregori, Leonardo Strazzere, Anderson Costa dos Santos, Mauro C. Geraldes. Characterization of Arroyo Verde Epithermal Deposit: Paragenesis, Mineral Geochemistry, Geochronology and Fluid Inclusions in Lower Chon Aike Volcanism, Argentina. Journal of Earth Science, 2024, 35(1): 62‒84 https://doi.org/10.1007/s12583-023-1823-5

References

[]
Akizuki M, Sunagawa I. Study of the Sector Structure in Adularia by Means of Optical Microscopy, Infra-Red Absorption, and Electron Microscopy. Mineralogical Magazine, 1978, 42(324): 453-462,
CrossRef Google scholar
[]
Albinson T, Norma D I, Cole D, et al.. Controls on Formation of Low-Sulfidation Epithermal Deposits in Mexico: Constraints from Fluid Inclusion and Stable Isotope Data. Society of Economic Geologist Special Publication, 2001, 8: 1-32
[]
Alric V I, Haller M J, Feraud G, et al.. Cronología 40Ar/39Ar del Volcanismo Jurásico de la Patagonia Extrandina. Actas XIII Congreso GeológicoArgentino, 1996, 5: 243-250
[]
Anthony J W, Bideaux R A, Bladh K W, et al.. Elements, Sulfides, Sulfosalts. Handbook of Mineralogy, 1990 Tucson, Arizona Mineral Data Publishing
[]
Baker P E, Rea W J, Skarmeta J, et al.. Igneous History of the Andean Cordillera and Patagonian Plateau around Latitude 46° S. Philosophical Transactions of the Royal Society of London Series A, Mathematical and Physical Sciences, 1981, 303(1474): 105-149
[]
Barros M, Gregori D, Benedini L, et al.. Evolution of the Jurassic Comallo Volcanic Sedimentary Complex in the Western North Patagonian Massif, Rio Negro Province, Argentina. International Geology Review, 2021, 63(7): 787-809,
CrossRef Google scholar
[]
Benedini L, Barros M, Pavón Pivetta C, et al.. New Insights into the Jurassic Polyphase Strain Partition on the Patagonian Back-Arc; Constraints from Structural Analysis of Ancient Volcanic Structures. Tectonophysics, 2022, 836: 229430,
CrossRef Google scholar
[]
Benedini L, Gregori D. Significance of the Early Jurassic Garamilla Formation in the Western Nordpatagonian Massif. Journal of South American Earth Sciences, 2013, 45: 259-277,
CrossRef Google scholar
[]
Benedini L, Gregori D, Strazzere L, et al.. Lower Pliensbachian Caldera Volcanism in High-Obliquity Rift Systems in the Western North Patagonian Massif, Argentina. Journal of South American Earth Sciences, 2014, 56: 1-19,
CrossRef Google scholar
[]
Benedini L, Pavón Pivetta C, Marcos P, et al.. Lower Jurassic Felsic Diatreme Volcanism Recognized in Central Patagonia as Evidence of Along-Strike Rift Segmentation. Journal of South American Earth Sciences, 2021, 106: 102705,
CrossRef Google scholar
[]
Bodnar R J. Revised Equation and Table for Determining the Freezing Point Depression of H2O-NaCl Solutions. Geochimica et Cosmochimica Acta, 1993, 57(3): 683-684,
CrossRef Google scholar
[]
Bodnar R J, Samson I, Anderson A, et al.. Samson I, Anderson A, Marshall D, et al.. Introduction to Aqueous-Electrolyte Fluid Inclusions. Fluid Inclusions: Analysis and Interpretation, 2003 Canada Mineral. Assoc., Short Course 81-99 32
[]
Bouhier V E, Franchini M B, Caffe P J, et al.. Petrogenesis of Volcanic Rocks that Host the World-Class AgPb Navidad District, North Patagonian Massif: Comparison with the Jurassic Chon Aike Volcanic Province of Patagonia, Argentina. Journal of Volcanology and Geothermal Research, 2017, 338: 101-120,
CrossRef Google scholar
[]
Buchanan L. Precious Metal Deposits Associated with Volcanic Environments in the Southwest. Geological Society of Arizona Digest, 1981, 14: 237-262
[]
Camprubi A. Criterios Para La Exploración Minera Mediante Microtermometría de Inclusiones Fluidas. Boletín De La Sociedad Geológica Mexicana, 2010, 62(1): 25-42,
CrossRef Google scholar
[]
Cas, R., Wright, J. V., 1987. Volcanic Successions, Modern and Ancient: A Geological Approach to Processes, Products, and Successions. Springer Science & Business Media
[]
Cook N J, Ciobanu C L, Pring A, et al.. Trace and Minor Elements in Sphalerite: A LA-ICPMS Study. Geochimica et Cosmochimica Acta, 2009, 73(16): 4761-4791,
CrossRef Google scholar
[]
Cook R B. Handbook of Mineralogy. Rocks and Minerals, 2001, 76(4): 278
[]
Cortés J M. El Sustrato Precretácico del Extremo Nordeste de la Provincia del Chubut. Revista de la Asociaciñn Geolñgica Argentina, 1981, 36(3): 217-235
[]
Cúneo R, Ramezani J, Scasso R, et al.. High-Precision U-Pb Geochronology and a New Chronostratigraphy for the Cañadón Asfalto Basin, Chubut, Central Patagonia: Implications for Terrestrial Faunal and Floral Evolution in Jurassic. Gondwana Research, 2013, 24(3/4): 1267-1275,
CrossRef Google scholar
[]
Curewitz D, Karson J A. Structural Settings of Hydrothermal Outflow: Fracture Permeability Maintained by Fault Propagation and Interaction. Journal of Volcanology and Geothermal Research, 1997, 79(3/4): 149-168,
CrossRef Google scholar
[]
Davis D W, Lowenstein T K, Spencer R J. Melting Behavior of Fluid Inclusions in Laboratory-Grown Halite Crystals in the Systems NaCl-H2O, NaCl-KCl-H2O, NaCl-MgCl2-H2O, and NaCl-CaCl2-H2O. Geochimica et Cosmochimica Acta, 1990, 54(3): 591-601,
CrossRef Google scholar
[]
Davis, G. H., Reynolds, S. J., 1996. Structural Geology of Rocks and Regions: 2nd Ed. Wiley
[]
del Potro R, Pinkerton H, Hürlimann M. An Analysis of the Morphological, Geological and Structural Features of Teide Stratovolcano, Tenerife. Journal of Volcanology and Geothermal Research, 2009, 181(1): 89-105, 2
CrossRef Google scholar
[]
Dietrich A, Gutierrez R, Nelson E P, et al.. Geology of the Epithermal Ag-Au Huevos Verdes Vein System and San José District, Deseado Massif, Patagonia, Argentina. Mineralium Deposita, 2012, 47(3): 233-249,
CrossRef Google scholar
[]
Dong G Y, Morrison G, Jaireth S. Quartz Textures in Epithermal Veins, Queensland; Classification, Origin and Implication. Economic Geology, 1995, 90(6): 1841-1856,
CrossRef Google scholar
[]
Dong G, Morrison G W. Adularia in Epithermal Veins, Queensland: Morphology, Structural State and Origin. Mineralium Deposita, 1995, 30(1): 11-19,
CrossRef Google scholar
[]
Echeveste H, Fernández R, Bellieni G, et al.. Relaciones Entre las Formaciones Bajo Pobreand Chon Aike (Jurásico Medio a Superior) en el áRea Estancia El Fénix-Cerro Huemul, Zona Centro-Occidental del Macizo del Deseado, Provincia de Santa Cruz. Rev. Asoc. Geol. Argent., 2001, 56: 548-558
[]
Einaudi M T, Hedenquist J W, Esra Inan E. Sulfidation State of Fluids in Active and Extinct Hydrothermal Systems: Transitions from Porphyry to Epithermal Environments. Special Publication of the Society of Economic Geologists, 2003, 10: 285-314
[]
Falco J I, Bodnar J, Del Río D. Revisión Estratigráfica del Grupo Los Menucos, Pérmico tardio-Triásico Inferior del Macizo Nordpatagónico, Provincia de Río Negro, Argentina. Revista de la Asociación Geológica Argentina, 2020, 77(4): 530-550
[]
Féraud G, Alric V, Fornari M, et al.. 40Ar/39Ar Dating of the Jurassic Volcanic Province of Patagonia: Migrating Magmatism Related to Gondwana Break-up and Subduction. Earth and Planetary Science Letters, 1999, 172(1): 83-96, 2
CrossRef Google scholar
[]
Frenzel M, Woodcock N H. Cockade Breccia: Product of Mineralisation along Dilational Faults. Journal of Structural Geology, 2014, 68: 194-206,
CrossRef Google scholar
[]
Ferraris G, Jones D W, Terkess J. “A Neutron-Diffraction Study of the Crystal Structure of Analcime, NaAlSi2O6·H2O” Zeitschrift Für Kristallographie. Crystalline Materials, 1972, 135(1–6): 240-483
[]
Geraldes, M. C., Almeida, B. S., Tavares, A., Jr., et al., 2015. U-Pb and Lu-Hf Calibration of the New LA-ICP-MS Multilab at Rio de Janeiro State University. In: Geoanalysis 2015. Geoanalysis, Leoben. http://2015.geoanalysis.info/documents/abstract_volume_geoanalysis2015.pdf
[]
Goldstein R H. Samson I, Anderson A, Marshall D. Petrographic Analysis of Fluid Inclusions. Fluid Inclusions: Analysis and Interpretation, 2003 Ottawa Mineralogical Association of Canada 9-53
[]
González S N, Greco G A, Galetto A, et al.. A Multi-Method Approach to Constrain the Age of Eruption and Post-Depositional Processes in a Lower Jurassic Ignimbrite from the Marifil Volcanic Complex, Eastern North Patagonian Massif. Journal of South American Earth Sciences, 2022, 114: 103688,
CrossRef Google scholar
[]
Haas J L. The Effect of Salinity on the Maximum Thermal Gradient of a Hydrothermal System at Hydrostatic Pressure. Economic Geology, 1971, 66(6): 940-946,
CrossRef Google scholar
[]
Hatert F, Burke E A J. The ima-CNMNC dominant-Constituent Rule Revisited and Extended. The Canadian Mineralogist, 2008, 46(3): 717-728,
CrossRef Google scholar
[]
Hauser N, Cabaleri N G, Gallego O F, et al.. U-Pb and Lu-Hf Zircon Geochronology of the Cañadón Asfalto Basin, Chubut, Argentina: Implications for the Magmatic Evolution in Central Patagonia. Journal of South American Earth Sciences, 2017, 78: 190-212,
CrossRef Google scholar
[]
Jourdan F, Féraud G, Bertrand H, et al.. Distinct Brief Major Events in the Karoo Large Igneous Province Clarified by New 40Ar/39Ar Ages on the Lesotho Basalts. Lithos, 2007, 98(1): 195-209, 2/3/4
CrossRef Google scholar
[]
Lovering T G. Jasperoid in the United States—Its Characteristics, Origin and Economic Significance. U. S. Geological Survey Professional Paper, 1972, 710: 164
[]
Luna, L., Gómez, C., Garrido, et al., 2008. Manifestación de Indio en el Maciso Nordpatagónico: Proyecto San Roque, Provincia de Rio Negro. Actas del XVII Congreso Geológico Argentino, Jujuy
[]
Malvicini L, Llambías E. Geología y Génesis del Depósito de Manganeso Arroyo Verde, Provincia del Chubut, República Argentina. 5°. Congreso Geológico Argentino, Actas, 1974, 2: 185-202
[]
Márquez M, Massaferro G, Fernández M. El Volcanismo Del Complejo Marifil En Arroyo Verde, Vertiente Suroriental Del Macizo de Somún Cura, Chubut. Revista de la Asociación Geológica Argentina, 2010, 66(3): 314-324
[]
Massaferro G I, Haller M J. Textura de las Vetas Epitermales del Macizo Nordpatagónico. V Congreso de Mineralogía y Metalogenia, Actas, 2000, 28: 312-319
[]
Massaferro G I, Haller M J. Vetas Epitermales de la Vertiente Suroriental del Macizo Norpatagónico. Revista de la Asociación Geológica Argentina, 2001, 56(3): 396-399
[]
Moncada D, Mutchler S, Nieto A, et al.. Mineral Textures and Fluid Inclusion Petrography of the Epithermal Ag-Au Deposits at Guanajuato, Mexico: Application to Exploration. Journal of Geochemical Exploration, 2012, 114: 20-35,
CrossRef Google scholar
[]
Montgomery A. . Preliminary Petrology of the High-Grade Ag-Cu-Pb Navidad Project, Northern Patagonia, Argentina, 2003 Kinston Queens University 158
[]
Nullo F E. . Descripción Geológica de la Hoja 39 c, Paso Flores, 1979 Buenos Aires Servicio Geológico Nacional 70
[]
Orberger B, Pasava J, Paul Gallien J, et al.. Se, As, Mo, Ag, Cd, In, Sb, Pt, Au, Tl, Re Traces in Biogenic and Abiogenic Sulfides from Black Shales (Selwyn Basin, Yukon Territories, Canada): A Nuclear Microprobe Study. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions With Materials and Atoms, 2003, 210: 441-448,
CrossRef Google scholar
[]
Padelletti, C., Bouhier, V, Ferracutti, G., 2023. Microtermometría de Inclusiones Fluidas y Análisis Textural en Esfalerita de las Estructuras Mineralizadas del Indio y Griselda, Proyecto San Roque, Patagonia Argentina. Actas del 14° Congreso de Mineralogía, Petrología Ígnea y Metamórfica, y Metalogénesis-14° MinMet y 5° PIMMA. https://revista.geologica.org.ar/seried/issue/view/352
[]
Páez, G. N. 2012. Génesis del yacimiento de metales preciosos Mina Martha, sector sudoccidental del Macizo del Deseado, provincia de Santa Cruz. Doctoral dissertation, Universidad Nacional de La Plata.
[]
Pankhurst R J, Rapela C R. Production of Jurassic Rhyolite by Anatexis of the Lower Crust of Patagonia. Earth and Planetary Science Letters, 1995, 134(1): 23-36, 2
CrossRef Google scholar
[]
Pankhurst R J, Leat P T, Sruoga P, et al.. The Chon Aike Province of Patagonia and Related Rocks in West Antarctica: A Silicic Large Igneous Province. Journal of Volcanology and Geothermal Research, 1998, 81(1): 113-136, 2
CrossRef Google scholar
[]
Pankhurst R J, Riley T R, Fanning C M, et al.. Episodic Silicic Volcanism in Patagonia and the Antarctic Peninsula: Chronology of Magmatism Associated with the Break-up of Gondwana. Journal of Petrology, 2000, 41(5): 605-625,
CrossRef Google scholar
[]
Pavón Pivetta C, Gregori D, Benedini L, et al.. Contrasting Tectonic Settings in Northern Chon Aike Igneous Province of Patagonia: Subduction and Mantle Plume-Related Volcanism in the Marifil Formation. International Geology Review, 2020, 62(15): 1904-1930,
CrossRef Google scholar
[]
Permuy Vidal C, Guido D M, Jovic S M, et al.. The Marianas-San Marcos Vein System: Characteristics of a Shallow Low Sulfidation Epithermal Au-Ag Deposit in the Cerro Negro District, Deseado Massif, Patagonia, Argentina. Mineralium Deposita, 2016, 51(6): 725-748,
CrossRef Google scholar
[]
Permuy Vidal C, Guido D M, Moreira P, et al.. Caracteristicas Metalogenéticas de Eureka West, Principal Clavo Mineralizado de La Veta Eureka, Distrito Cerro Negro, Macizo Del Deseado. Revista de la Asociación Geológica Argentina, 2015, 73(1): 64-77
[]
Portal Resources Limited, 2008. Technical Report, a Review of the Arroyo Verde Project, Argentina. Chubut and Rio Negro Provinces, Argentina, Latitude 42°5.6’S, Longitude 65°21.9’ W. Confidential Report. 63
[]
Pugliese F E, Pugliese L E, Dahlquist J A, et al.. Intermediate Sulfidation Epithermal Pb-Zn (± Ag ± Cu ± in) and Low Sulfidation Au (± Pb ± Ag ± Zn) Mineralization Styles in the Gonzalito Polymetallic Mining District, North Patagonian Massif. Journal of South American Earth Sciences, 2021, 110: 103388,
CrossRef Google scholar
[]
Raase P, Morteani G. The Potassic Feldspar in Metamorphic Rocks from the Western Hohe Tauern Area, Eastern Alps. Geologische Rundschau, 1976, 65(1): 422-436,
CrossRef Google scholar
[]
Rapela C W, Pankhurst R J, Fanning C M, et al.. Pacific Subduction Coeval with the Karoo Mantle Plume: The Early Jurasssic Subcordilleran Belt of Northwestern Patagonia. Geological Society, London, Special Publications, 2005, 246(1): 217-239,
CrossRef Google scholar
[]
Riley T R, Knight K B. Age of Pre-Break-up Gondwana Magmatism. Antarctic Science, 2001, 13(2): 99-110,
CrossRef Google scholar
[]
Roedder E. Fluid Inclusions. Reviews in Mineralogy, Mineralogical Society of America, 1984, 12: 644
[]
Schalamuk I B, Zubia M, Genini A, et al.. Jurassic Epithermal Au-Ag Deposits of Patagonia, Argentina. Ore Geology Reviews, 1997, 12(3): 173-186,
CrossRef Google scholar
[]
Schalamuk, I. B., de Barrio, R. E., Zubia, M. A., et al., 1999. Provincia Auroargentifera del Deseado, Santa Cruz. In: En Zappettini, E. O., ed., Recursos Minerales de la República Argentina. Instituto de Geología y Recursos Minerales SEGEMAR, Anales. 35: 1177–1188. http://repositorio.segemar.gov.ar/308849217/2746
[]
Stanton R L. . Ore Petrology, 1972 New York Mc Graw-Hill Book Company 713
[]
Steiner A. Genesis of Hydrothermal K-Feldspar (Adularia) in an Active Geothermal Environment at Wairakei, New Zealand. Mineralogical Magazine, 1970, 37: 916-922,
CrossRef Google scholar
[]
Strazzere L, Gregori D A, Benedini L, et al.. The Puesto Piris Formation: Evidence of Basin-Development in the North Patagonian Massif during Crustal Extension Associated with Gondwana Breakup. Geoscience Frontiers, 2019, 10(1): 299-314,
CrossRef Google scholar
[]
Strazzere L, Pavón Pivetta C, Gregori D A, et al.. The Marifil Volcanic Complex at Sierra de Pailemán: Implications for the Early Jurassic Magmatic Evolution of the Eastern North Patagonian Region. International Geology Review, 2022, 64(6): 844-866,
CrossRef Google scholar
[]
Van der Veen, R. W., 1925. Mineragraphy and Ore-Deposition. G. Naeff
[]
Vinagre da Costa R, Trouw R A J, Mendes J C, et al.. Proterozoic Evolution of Part of the Embu Complex, Eastern São Paulo State, SE Brazil. Journal of South American Earth Sciences, 2017, 79: 170-188,
CrossRef Google scholar
[]
Voudouris P, Melfos V, Mavrogonatos C, et al.. Amethyst Occurrences in Tertiary Volcanic Rocks of Greece: Mineralogical, Fluid Inclusion and Oxygen Isotope Constraints on Their Genesis. Minerals, 2018, 8(8): 324,
CrossRef Google scholar
[]
Zaffarana C B, Somoza R. Palaeomagnetism and 40Ar/39Ar Dating from Lower Jurassic Rocks in Gastre, Central Patagonia: Further Data to Explore Tectonomagmatic Events Associated with the Break-up of Gondwana. Journal of the Geological Society, 2012, 169(4): 371-379,
CrossRef Google scholar
[]
Zubia, M. A., Genini, A. D., Schalamuk, I. B. A., 1999. Yacimiento Cerro Vanguardia, Santa Cruz. Anales del Instituto de Geologia y Recursos Minerales. https://repositorio.segemar.gov.ar//handle/308849217/2746

Accesses

Citations

Detail

Sections
Recommended

/