Test Research of High Specific Energy Lithium Carbon-Fluoride (Li/CFx) Batteries as Power Sources for Deep Space Exploration

QIAO Xuerong, GUO Ji, MI Juan

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Journal of Deep Space Exploration ›› 2020, Vol. 7 ›› Issue (1) : 87-92. DOI: 10.15982/j.issn.2095-7777.2020.20191223001
Guest Editor:Professor LUO Zhifu,China Institute of Atomic Energy
Guest Editor:Professor LUO Zhifu,China Institute of Atomic Energy

Test Research of High Specific Energy Lithium Carbon-Fluoride (Li/CFx) Batteries as Power Sources for Deep Space Exploration

  • QIAO Xuerong, GUO Ji, MI Juan
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Abstract

Deep-space exploration missions have limited power options due to weight constraints and reduced light intensity. Lithium-fluorocarbon battery technology is considered a potentially viable option for future deep space probe power supplies. Tests on specific energy,specific heat capacity,calorific value,and low temperature and storage performance of lithium fluorocarbon batteries were carried out. The results show that lithium fluorocarbon batteries have obvious advantages of high specific energy. Its long storage life meets the needs for deep space probes with low self-discharge rates during months or even years of flight. For low-temperature applications,the low-temperature discharge performance is effectively improved by the use of composite electrodes. The trials of specific heat capacity and heat generation for lithium-fluoride carbon batteries provide essential data support for battery thermal simulation analysis.

Keywords

deep space exploration / power sources / Li/CFx-MnO2 cell / Li/CFx cell

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QIAO Xuerong, GUO Ji, MI Juan. Test Research of High Specific Energy Lithium Carbon-Fluoride (Li/CFx) Batteries as Power Sources for Deep Space Exploration. Journal of Deep Space Exploration, 2020, 7(1): 87‒92 https://doi.org/10.15982/j.issn.2095-7777.2020.20191223001

References

[1] KRAUSE F C,JONES J P,JONES S C,et al. High specific energy lithium primary batteries as power sources for deep space exploration[J]. Journal of the Electrochemical Society,2018,165(10):A2312-A2320
[2] 彭思侃,王晨,王楠,等. 锂氟化碳电池用新型高比容量复合正极材料[J]. 航空材料学报,2019,39(4):59-64
PENG S K,WANG C,WANG N,et al. A novel high specific capacity hybrid cathode for lithium fluorocarbon battery[J]. Journal of Aeronautical Materials,2019,39(4):59-64
[3] GIWA C O,RITCHIE A G,BOWLES P G,et al. Scale-up of lithium carbon,monofluoride envelop cells[C]//39th Power Sources Conference. Cherry Hill,NJ,USA:[s. n.]:2000.
[4] RITCHIE A G,GIWA C O,BOWLES P G,et al. Further development of lithium/polycarbon monofluoride envelope cells[J]. Journal of Power Sources,2001,96(1):180-183
[5] GIWA C O,RITCHIE A G,EWEKA E I,et al. Development of 25 and 50 Ah lithium/polycarbon monofluride envelope cells[C]//20th International Seminar and Exhibit on Primary and Secondary Batteries. Fort Lauderdale,FL:[s. n.],2003.
[6] EWEKA E I,GIWA C O,MEPSTED G O,et al. Development of high energy density small flat spiral cells and battery pack based on lithium/carbon monofluoride(Li/CFx)[J]. Journal of Power Sources,2006,162(2):841-846
[7] LINDEN D,REDDY T B. Handbook of batteries[M]. Third ed. New York:McGraw-Hill,2002.
[8] READ J,COLLINS E,PIEKARSKI B,et al. LiF formation and cathode swelling in the Li/CFx battery[J]. Jorunal of The Electrochemical Society,2011,158(5):A504-A510
[9] XU X M,FU J Q,JIANG H B,et al. Research on the heat dissipation performance of lithium-ion cell with different operating conditions[J]. International Journal of Energy Research,2017,41:1642-1654
[10] 卢立丽,王松蕊. 锂氟化碳电池放电热效应的模拟研究[J]. 电源技术,2016,40(5):1098-1102
LU L L,WANG S R. Studies on thermal effects during discharging of lithium carbon fluoride cells by simulation[J]. Chinese Journal of Power Sources,2016,40(5):1098-1102
[11] 牛长冬,陈雪梅,王兴贺,等. Li/(MnO2+CFx)电池放电发热的研究[J]. 电源技术,2015,39(9):1832-1834
NIU C D,CHEN X M,WANG X H,et al. Study on discharge heating of Li/(MnO2+CFx)batteries[J]. Chinese Journal of Power Sources,2015,39(9):1832-1834
[12] NAKAJIMA T,HAGIWARA R,MORIYA K,et al. Discharge characteristics of poly(carbon monofluoride)prepared from the residual carbon obtained by thermal decomposition fo poly(dicarbon monofluoride)and graphite oxide[J]. Journal of the Electrochemical Society,1986,133(9):1761-1766
[13] NAKAJIMA T,MABUCHI A,HAGIWARA R,et al. Discharge characteristics of graphite fluoride prepared via graphite oxide[J]. Journal of the Electrochemical Society,1988,135(2):273-277
[14] LI Y,CHEN Y F,FENG W,et al. The improved discharge performance of Li/CFx batteries by using multi-walled carbon nanotubes as conductive additive[J]. Journal of Power Sources,2011,196:2246-2250
[15] MCKISSOCK B,LOYSELLE P,VOGEL E. Guidelines on Lithium-ion battery use in space applications:06-069-I[R].[S. l.]:NASA Engineering and Safety Center,2008.
[16] WHITACRE J,YAZAMI R,HAMWI A,et al. Low operational temperature Li–CFx batteries using cathodes containing sub-fluorinated graphitic materials[J]. Journal of Power Sources,2006,160:577-584
[17] ZHANG S S,FOSTER D,READ J. A low temperature electrolyte for primary Li/CFx batteries[J]. Journal of Power Sources,2009,188:532-537
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