Sacrificial strategy to fabricate durable superhydrophobic wood via hierarchical roughness and elastic crosslinking^✩

Abstract

With growing demand for renewable resources, superhydrophobic wood is widely regarded as leading candidate for outdoor construction applications. However, superhydrophobic wood still suffers from insufficient mechanical strength and durability under long-term abrasion and ultraviolet (UV) exposure. Herein, a sacrificial synergy strategy combining elastic cross-linked network and hierarchical roughness was proposed to enhance both toughness and durability, and its toughening mechanism is clarified. Specifically, a flexible room temperature vulcanized (RTV) silicone rubber matrix was cross-linked with vinyltriethoxysilane (VTES) to construct an elastomeric interphase, while ZnO nanorods arrays were in situ grown to generate micro/nano-scale roughness and simultaneously act as a sacrificial barrier against external abrasion. The modified wood exhibited water contact angle over 154°. Furthermore, the expected excellent robustness toward water impact (continuous 66 h), sand impingement (100 g, 35 cm, 25 cycles), mechanical abrasion (1000 peeling cycles; sandpaper abrasion 400 cm), along with desirable chemical and environmental durability (48 h immersion in acidic and alkaline solution) of the modified wood was achieved as well. Moreover, the modified wood demonstrated multifunctional performance including self-cleaning, anti-fouling, humidity resistance (28 ℃, 85% relative humidity (RH), 15 days and 35 ℃, 90% RH, 6 days), and UV resistance (340 nm, 40 W, 33 days). This integrated approach not only proposed to construct mechanically resilient and environmentally durable superhydrophobic surfaces but also offered an effective design strategy for wood outdoor applications as construction material in long-term.

Keywords

Superhydrophobic wood / Structural toughening / Micro/nano structure / Durability

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