An ultra thin, bright, and sensitive interactive tactile display based on organic mechanoluminescence for dual-mode handwriting identification
Tingting Hou, Wenlang Li, Haoyu Wang, Yuantian Zheng, Chaojie Chen, Haoran Zhang, Kai Chen, Huilin Xie, Xin Li, Shaoshuai He, Siwei Zhang, Dengfeng Peng, Cheng Yang, Jacky W. Y. Lam, Ben Zhong Tang, Yunlong Zi
An ultra thin, bright, and sensitive interactive tactile display based on organic mechanoluminescence for dual-mode handwriting identification
Visible light-based human–machine interactive media is capable of transmitting electrical readouts to machines and providing intuitive feedback to users simultaneously. Currently, many inorganic mechanoluminescent (ML) materials-based interactive media, typically ZnS-loaded phosphors (ZLPs), have been successfully demonstrated. However, organic ML materials-based solutions were rarely exploited despite their huge merits of strong structural modification, abundant luminescence property, low cost, easy preparation, and so on. Here, we propose a novel interactive tactile display (ITD) based on organic ML materials (Cz-A6-dye) and triboelectric nanogenerator, with ultra-brightness (130% enhancement) and ultra-low threshold pressure (57% reduction) as compared to ZLPs. The proposed ITD achieves the conversion of weak mechanical stimuli into visible light and electrical signals simultaneously, without extra power supplies. Furthermore, the relationship between the luminous performance of organic ML materials and mechanical force is quantified, benefiting from the uniform ML layer prepared. Enabled by convolutional neural networks, the high-accuracy recognition (97.1%) for handwriting and identity of users is realized at the same time. Thus, the ITD has great potential for intelligent wearable electronics and classified military applications.
interactive media / organic mechanoluminescence / triboelectric nanogenerators
[1] |
Araromi OA, Graule MA, Dorsey KL, et al. Ultra-sensitive and resilient compliant strain gauges for soft machines. Nature. 2020;587(7833):219-224.
|
[2] |
Chortos A, Liu J, Bao Z. Pursuing prosthetic electronic skin. Nat Mater. 2016;15(9):937-950.
|
[3] |
Wang J, Lin M, Park S, Lee P. Deformable conductors for human–machine interface. Mater Today. 2018;21(5):508-526.
|
[4] |
Kim J, Salvatore G, Araki H, et al. Battery-free, stretchable optoelectronic systems for wireless optical characterization of the skin. Sci Adv. 2016;2(8):e1600418.
|
[5] |
Zhao X, Kang Z, Liao Q, et al. Ultralight, self-powered and self-adaptive motion sensor based on triboelectric nanogenerator for perceptual layer application in Internet of things. Nano Energy. 2018;48:312-319.
|
[6] |
Kang J, Tok J, Bao Z. Self-healing soft electronics. Nat Electron. 2019;2(4):144-150.
|
[7] |
Pu X, Guo H, Chen J, et al. Eye motion triggered self-powered mechnosensational communication system using triboelectric nanogenerator. Sci Adv. 2017;3(7):e1700694.
|
[8] |
Ding W, Wu C, Zi Y, et al. Self-powered wireless optical transmission of mechanical agitation signals. Nano Energy. 2018;47:566-572.
|
[9] |
Lin Z, Zhang G, Xiao X, et al. A personalized acoustic interface for wearable human–machine interaction. Adv Funct Mater. 2022;32(9):2109430.
|
[10] |
Zhang C, Wang H, Guan S, et al. Self-powered optical switch based on triboelectrification-triggered liquid crystal alignment for wireless sensing. Adv Funct Mater. 2019;29(13):1808633.
|
[11] |
Tee BCK, Chortos A, Berndt A, et al. A skin-inspired organic digital mechanoreceptor. Science. 2015;350(6258):313-316.
|
[12] |
Zhao X, Zhang Z, Liao Q, et al. Self-powered user-interactive electronic skin for programmable touch operation platform. Sci Adv. 2020;6(28):eaba4294.
|
[13] |
Eddingsaas NC, Suslick KS. Mechanoluminescence: light from sonication of crystal slurries. Nature. 2006;444(7116):163.
|
[14] |
Wang X, Zhang H, Yu R, et al. Dynamic pressure mapping of personalized handwriting by a flexible sensor matrix based on the mechanoluminescence process. Adv Mater. 2015;27(14):2324-2331.
|
[15] |
Liu S, Zheng Y, Peng D, Zhao J, Song Z, Liu Q. Near-infrared mechanoluminescence of Cr3+ doped gallate spinel and magnetoplumbite smart materials. Adv Funct Mater. 2022;33(3):2209275.
|
[16] |
Zhuang Y, Xie R. Mechanoluminescence rebrightening the prospects of stress sensing: a review. Adv Mater. 2021;33(50):2005925.
|
[17] |
Li W, Huang Q, Mao Z, et al. Alkyl chain introduction: in situ solar-renewable colorful organic mechanoluminescence materials. Angew Chem Int ed. 2018;57(39):12727-12732.
|
[18] |
Li W, Huang Q, Yang Z, et al. Activating versatile mechanoluminescence in organic host-guest crystals by controlling exciton transfer. Angew Chem Int Ed. 2020;59(50):22645-22651.
|
[19] |
Gong Y, Zhang P, Gu Y, et al. The influence of molecular packing on the emissive behavior of pyrene derivatives: mechanoluminescence and mechanochromism. Adv Opt Mater. 2018;6(16):1800198.
|
[20] |
Yang J, Gao X, Xie Z, et al. Elucidating the excited state of mechanoluminescence in organic luminogens with room-temperature phosphorescence. Angew Chem Int Ed. 2017;129(48):15501-15505.
|
[21] |
Xu S, Liu T, Mu Y, et al. An organic molecule with asymmetric structure exhibiting aggregation-induced emission, delayed fluorescence, and mechanoluminescence. Angew Chem Int Ed. 2015;127(3):888-892.
|
[22] |
Luo J, Xie Z, Lam JWY, et al. Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole. Chem Commun. 2001;18(18):1740-1741.
|
[23] |
Zhou S, Cheng Y, Xu J, Lin H, Wang Y. Ratiometric mechanoluminescence of double-activator doped phosphatic phosphors: color-resolved visualization of stress-sensing and quantified evaluation for sensing performance. Adv Funct Mater. 2022;32(52):2208919.
|
[24] |
Wang X, Ling R, Zhang Y, Que M, Peng Y, Pan C. Oxygen-assisted preparation of mechanoluminescent ZnS:Mn for dynamic pressure mapping. Nano Res. 2018;11(4):1967-1976.
|
[25] |
Zhan L, Chen Z, Gong S, Xiang Y, et al. A simple organic molecule realizing simultaneous TADF, RTP, AIE, and mechanoluminescence: understanding the mechanism behind the multifunctional emitter. Angew Chem Int Ed. 2019;131(49):7815-17819.
|
[26] |
Li J, Zhou J, Mao Z, et al. Transient and persistent room-temperature mechanoluminescence from a white-light-emitting AIEgen with tricolor emission switching triggered by light. Angew Chem Int Ed. 2018;130(22):6559-6563.
|
[27] |
Wang C, Yu Y, Yuan Y, et al. Heartbeat-sensing mechanoluminescent device based on a quantitative relationship between pressure and emissive intensity. Matter. 2020;2(1):181-193.
|
[28] |
Li L, Liu J, Zeng M, Fu L. Space-confined growth of metal halide perovskite crystal films. Nano Res. 2020;14(6):1609-1624.
|
[29] |
Shi Y, Zhang Z, Huang Q, Lin Y, Zheng Z. Wearable sweat biosensors on textiles for health monitoring. J Semicond. 2023;44(2):021601.
|
[30] |
Yang Y, Zhou Y, Zhang H, Liu Y, Lee S, Wang Z. A single-electrode based triboelectric nanogenerator as self-powered tracking system. Adv Mater. 2013;25(45):6594-6601.
|
[31] |
Meng B, Tang W, Too Z, et al. A transparent single-friction-surface triboelectric generator and self-powered touch sensor. Energ Environ Sci. 2013;6(11):3235-3240.
|
[32] |
Chen J, Huang Y, Zhang N, et al. Micro-cable structured textile for simultaneously harvesting solar and mechanical energy. Nat Energy. 2016;1(10):1-8.
|
[33] |
Dong K, Wang Z. Self-charging power textiles integrating energy harvesting triboelectric nanogenerators with energy storage batteries/supercapacitors. J Semicond. 2021;42(10):101601.
|
[34] |
Pu X, Liu M, Chen X, et al. Ultrastretchable, transparent triboelectric nanogenerator as electronic skin for biomechanical energy harvesting and tactile sensing. Sci Adv. 2017;3(5):e1700015.
|
[35] |
Zhang P, Chen Y, Guo Z, Guo W, Pu X, Wang Z. Stretchable, transparent, and thermally stable triboelectric nanogenerators based on solvent-free ion-conducting elastomer electrodes. Adv Funct Mater. 2020;30(15):1909252.
|
[36] |
Wang F, Wang F, Wang X, et al. Mechanoluminescence enhancement of ZnS:Cu,Mn with piezotronic effect induced trap-depth reduction originated from PVDF ferroelectric film. Nano Energy. 2019;63:103861.
|
[37] |
Qiu X, Liu J, Zhou B, Zhang X. Bioinspired bimodal mechanosensors with real-time, visualized information display for intelligent control. Adv Funct Mater. 2023;33(21):2300321.
|
[38] |
Wang X, Que M, Chen M, Han X, Li X, Pan C. Full dynamic-range pressure sensor matrix based on optical and electrical dual-mode sensing. Adv Mater. 2017;29(15):1605817.
|
[39] |
Hou B, Yi L, Li C, et al. An interactive mouthguard based on mechanoluminescence-powered optical fibre sensors for bite-controlled device operation. Nat Electron. 2022;5(10):682-693.
|
[40] |
Zhang N, Tian B, Wang Z, et al. Intense mechanoluminescence in undoped LiGa5O8 with persistent and recoverable behaviors. Adv Opt Mater. 2021;9(13):2100137.
|
[41] |
Qian X, Cai Z, Su M, et al. Printable skin-driven mechanoluminescence devices via nanodoped matrix modification. Adv Mater. 2018;30(25):1800291.
|
[42] |
Liu Y, Chen S, Lam JWY, et al. Tuning the electronic nature of aggregation-induced emission luminogens with enhanced hole-transporting property. Chem Mater. 2011;23(10):2536-2544.
|
[43] |
Li W, Huang Q, Mao Z, et al. A dish-like molecular architecture for dynamic ultralong room-temperature phosphorescence through reversible guest accommodation. Nat Commun. 2022;13(1):7423.
|
[44] |
Feng G, Mao D, Liu J, et al. Polymeric nanorods with aggregation-induced emission characteristics for enhanced cancer targeting and imaging. Nanoscale. 2018;10(13):5869-5874.
|
[45] |
Chen X, Yang Z, Li W, et al. Nondoped red fluorophores with hybridized local and charge-transfer state for high-performance fluorescent white organic light-emitting diodes. ACS Appl Mater Inter. 2019;11(42):39026-39034.
|
[46] |
Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR. Gaussian 09, Revision D1. Gaussian Inc; 2016.
|
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