Role of multicomponent nanoprecipitates on strength and low-temperature toughness of simulated heat-affected zone (HAZ) in high-strength low-carbon steel
Tingwei Yin , Yongfeng Shen , Nan Jia , Xin Sun , Wenying Xue
International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (2) : 579 -594.
Role of multicomponent nanoprecipitates on strength and low-temperature toughness of simulated heat-affected zone (HAZ) in high-strength low-carbon steel
This study investigates the microstructure and co-precipitation behavior of multicomponent (Ni(Al,Mn) and Cu) nanoparticles in the weld heat-affected zones of high-strength low-carbon steel. Through thermal simulations, the intercritical, fine-grained, and coarse-grained heat-affected zones were systematically characterized to elucidate the interplay between the microstructure, precipitation, and mechanical properties. At a heat input of 30 kJ·cm−1, Ni(Al,Mn) nanoparticles dissolve in the intercritical heat-affected zone, followed by dense reprecipitation coupled with significant coarsening of Cu particles during cooling, thereby retaining high strength but reducing impact toughness to (142 ± 10) J (compared to (205 ± 8) J of the base metal). The fine-grained heat-affected zone, under the same heat input, exhibits a refined ferritic–bainite matrix with a few fine Ni(Al,Mn) and slightly coarsened Cu particles, thus enhancing plastic deformation capacity and resulting in superior impact toughness of (196 ± 7) J. Despite complete dissolution of original precipitates at peak temperatures in the coarse-grained heat-affected zone, re-precipitated nanoparticles provide effective strengthening effect, compensating for grain coarsening and dislocation recovery and resulting in an impressive impact toughness of (186 ± 6) J. The toughening mechanism is primarily attributed to the synergistic actions of the matrix, precipitates, and deformation twins. These findings provide mechanistic and quantitative insights for developing processing–microstructure–property relationships in different welding heat-affected zones, and this framework can be further utilized to optimize welding parameters for tailored applications.
high-strength low-carbon steel / heat-affected zones / multicomponent nanoparticles / strengthening / toughening
| [1] |
J. Moon, G. Bae, B.Y. Jeong, et al., Ultrastrong and ductile steel welds achieved by fine interlocking microstructures with filmlike retained austenite, Nat. Commun., 15(2024), No. 1, art. No. 1301. |
| [2] |
|
| [3] |
|
| [4] |
X.C. Yang, X.J. Di, J.S. Wang, et al., The co-precipitation evolution of NiAl and Cu nanoparticles and its influence on strengthening and toughening mechanisms in low-carbon ultrahigh strength martensite seamless tube steel, Int. J. Plast., 166(2023), art. No. 103654. |
| [5] |
F.L. Ding, Q.Y. Guo, B. Hu, et al., Influences of Cu alloying on precipitation, austenitic reversion and mechanical properties of NiAl-strengthened medium-Mn steels, Acta Mater., 284(2025), art. No. 120623. |
| [6] |
|
| [7] |
M.Z. Wang, Y.F. Shen, N. Jia, W.Y. Xue, and X.L. Wang, Multistage precipitation triggering 3 GPa compressive strength and superior corrosion resistance in a FeCrVNiAl alloy, Mater. Futur., 4(2025), No. 3, art. No. 035004. |
| [8] |
B.C. Zhou, T. Yang, G. Zhou, H. Wang, J.H. Luan, and Z.B. Jiao, Mechanisms for suppressing discontinuous precipitation and improving mechanical properties of NiAl-strengthened steels through nanoscale Cu partitioning, Acta Mater., 205(2021), art. No. 116561. |
| [9] |
|
| [10] |
|
| [11] |
|
| [12] |
|
| [13] |
J. Wang, Y.F. Shen, W.Y. Xue, N. Jia, and R.D.K. Misra, The significant impact of introducing nanosize precipitates and decreased effective grain size on retention of high toughness of simulated heat affected zone (HAZ), Mater. Sci. Eng. A, 803(2021), art. No. 140484. |
| [14] |
|
| [15] |
|
| [16] |
W. Fu, C.N. Li, X.J. Di, et al., Effect of peak temperature on nanoscale Cu-rich re-precipitation behavior and strength-toughness of welding heat affected zones for Cu-bearing high strength steel, Mater. Charact., 199(2023), art. No. 112809. |
| [17] |
|
| [18] |
|
| [19] |
X.Y. Qi, L.X. Du, J. Hu, and R.D.K. Misra, Enhanced impact toughness of heat affected zone in gas shield arc weld joint of low-C medium-Mn high strength steel by post-weld heat treatment, Steel Res. Int., 89(2018), No. 4, art. No. 1700422. |
| [20] |
R.M. Geng, J. Li, C.B. Shi, J.G. Zhi, and B. Lu, Effect of Ce on microstructures, carbides and mechanical properties in simulated coarse-grained heat-affected zone of 800-MPa high-strength low-alloy steel, Mater. Sci. Eng. A, 840(2022), art. No. 142919. |
| [21] |
X.C. Yang, C.N. Li, J.Y. Han, et al., Effect of welding state on the re-precipitation behavior of Cu-rich and NiAl nanoparticles in HAZ of 1100 MPa grade low carbon ultra-high strength steel, Mater. Sci. Eng. A, 897(2024), art. No. 146334. |
| [22] |
|
| [23] |
Y.Z. Li, S.L. Zhao, S.H. He, C.P. Huang, and M.X. Huang, Enhancing yield stress and uniform elongation in an ultrathin packaging steel via controlling dislocation density, Int. J. Plast., 155(2022), art. No. 103334. |
| [24] |
T. Masumura, K. Inami, K. Matsuda, T. Tsuchiyama, S. Nanba, and A. Kitahara, Quantitative evaluation of dislocation density in as-quenched martensite with tetragonality by X-ray line profile analysis in a medium-carbon steel, Acta Mater., 234(2022), art. No. 118052. |
| [25] |
|
| [26] |
|
| [27] |
T.W. Yin, Y.F. Shen, N. Jia, Y.J. Li, and W.Y. Xue, Controllable selection of martensitic variant enables concurrent enhancement of strength and ductility in a low-carbon steel, Int. J. Plast., 168(2023), art. No. 103704. |
| [28] |
|
| [29] |
J. Mola, S. Scherbring, U. Lienert, A. Zargaran, H. Biermann, and P. Sahu, Size-dependent stress response of nanoscale B2 intermetallic precipitates revealed by in-situ high-energy X-ray diffraction, Acta Mater., 291(2025), art. No. 120967. |
| [30] |
|
| [31] |
Z.X. Guo, X.C. Lu, C. Paramatmuni, et al., Slip system-resolved GNDs and SEDs: A multi-scale framework for predicting crack nucleation in single-crystal metals, Acta Mater., 288(2025), art. No. 120853. |
| [32] |
S.S. Xu, J.P. Li, Y. Cui, et al., Mechanical properties and deformation mechanisms of a novel austenite-martensite dual phase steel, Int. J. Plast., 128(2020), art. No. 102677. |
| [33] |
|
| [34] |
|
| [35] |
X.N. Xu, P. Kumar, R.Q. Cao, et al., Exceptional cryogenic-to-ambient impact toughness of a low carbon micro-alloyed steel with a multi-heterogeneous structure, Acta Mater., 274(2024), art. No. 120019. |
| [36] |
Q. Zhu, Z.L. Pan, Z.Y. Zhao, et al., Defect-driven selective metal oxidation at atomic scale, Nat. Commun., 12(2021), No. 1, art. No. 558. |
| [37] |
|
| [38] |
N. Zhao, Q.Q. Zhao, Y.L. He, et al., Strengthening-toughening mechanism of cost-saving marine steel plate with 1000 MPa yield strength, Mater. Sci. Eng. A, 831(2022), art. No. 142280. |
| [39] |
|
| [40] |
C.W. He, Y.F. Shen, W.Y. Xue, Z.J. Fan, and Y.R. Zhou, Nanosized κ-carbide and B2 boosting strength without sacrificing ductility in a low-density Fe-32Mn–11Al steel, Nanomaterials, 15(2024), No. 1, art. No. 48. |
| [41] |
|
| [42] |
L.F. Sun, Z.F. He, N. Jia, et al., Local chemical order enables an ultrastrong and ductile high-entropy alloy in a cryogenic environment, Sci. Adv., 10(2024), No. 48, art. No. eadq6398. |
| [43] |
|
| [44] |
Z.P. Xiong, I. Timokhina, and E. Pereloma, Clustering, nanoscale precipitation and strengthening of steels, Prog. Mater. Sci., 118(2021), art. No. 100764. |
| [45] |
X.C. Yang, X.J. Di, Q.Y. Duan, W. Fu, L.Z. Ba, and C.N. Li, Effect of precipitation evolution of NiAl and Cu nanoparticles on strengthening mechanism of low carbon ultra-high strength seamless tube steel, Mater. Sci. Eng. A, 872(2023), art. No. 144939. |
| [46] |
Y.L. Wang, Y.F. Shen, N. Jia, J.J. Wang, and S.X. Zhao, Acicular martensite induced superior strength-ductility combination in a 20Cr2Ni2MoV steel, Mater. Sci. Eng. A, 848(2022), art. No. 143400. |
| [47] |
X.X. Dong, B. Gao, L.R. Xiao, et al., Heterostructured metallic structural materials: Research methods, properties, and future perspectives, Adv. Funct. Mater., 34(2024), No. 51, art. No. 2410521. |
| [48] |
|
| [49] |
|
| [50] |
|
| [51] |
X.Y. Zhang, J.L. Wang, T. Zhou, L. Yan, and H. Yu, Impact toughness and fracture propagation mechanism of NiAl precipitation-strengthened HSLA steels, Mater. Des., 241(2024), art. No. 112927. |
| [52] |
|
| [53] |
|
| [54] |
M. Shih, J.S. Miao, M. Mills, and M. Ghazisaeidi, Stacking fault energy in concentrated alloys, Nat. Commun., 12(2021), No. 1, art. No. 3590. |
| [55] |
X.Y. Li, Z. Zhang, and J.W. Wang, Deformation twinning in body-centered cubic metals and alloys, Prog. Mater. Sci., 139(2023), art. No. 101160. |
| [56] |
|
| [57] |
T.J. Chen, E.X. Cui, Y.F. Shen, N. Jia, Z.D. Wang, and Z.J. Fan, Superior combination of strength and ductility in Fe–10Mn–0.6C steel trigged by austenite reversion transformation, Mater. Sci. Eng. A, 901(2024), art. No. 146579. |
University of Science and Technology Beijing
/
| 〈 |
|
〉 |