Achieving 2.6 GPa tensile strength with outstanding ductility in high-carbon low-alloy steel
Guoyang Li , Feilong Sun , Guilin Wu , Honghui Wu , Junheng Gao , Haitao Zhao , Yuhe Huang , Jun Lu , Chaolei Zhang , Shuize Wang , Xinping Mao
International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (4) : 1201 -1213.
Increasing the carbon content in low-alloy steels is one of the most cost-effective and efficient methods for enhancing strength, often resulting in a significant reduction in ductility. In this study, a high-carbon low-alloy steel with a tensile strength of about 2.6 GPa and a total elongation of 12% was developed, through the synergistic applications of two key strategies: i) refine prior austenite grains (PAGs) leading to the transition of quenched microstructure from brittle twinned martensite to dislocation martensite; ii) suppress the martensitic transformation finish temperature to sub-room temperature by the combined effect of high content of carbon and alloying elements, i.e., Ni, Mn, Si, Cr, and Mo. After quenching and tempering, the steel retains approximately 15vol% stable retained austenite (RA), which enhances ductility through the transformation-induced plasticity (TRIP) effect. These strategies collectively contribute to both high strength and excellent ductility, enhancing the strength–ductility synergy in ultra-high strength steels.
high-carbon steel / room-temperature quenching and partitioning steel / mechanical property / retained austenite / trip effect
| [1] |
J.K. Li, Z.N. Yang, H. Ma, C. Chen, and F.C. Zhang, A medium-C martensite steel with 2.6 GPa tensile strength and large ductility, Scripta Mater., 228(2023), art. No. 115327. |
| [2] |
G. Liu, T.C. Liao, S.Z. Wang, et al., Revealing the precipitation kinetics of multi-stage and multi-scale Ti-bearing precipitation in a 460 MPa grade HSLA steel, Mater. Sci. Eng. A, 890(2024), art. No. 145941. |
| [3] |
|
| [4] |
|
| [5] |
|
| [6] |
|
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
X.X. Dong, Y.F. Shen, N. Jia, and W.Y. Xue, Simultaneous enhancement of strength and ductility in a medium carbon low-alloy steel induced by secondary martensite and Cu-rich particles, Mater. Sci. Eng. A, 869(2023), art. No. 144791. |
| [11] |
|
| [12] |
|
| [13] |
|
| [14] |
|
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
X.S. Wang and K.H. Spitzer, High-temperature properties of high Mn steel with Al, Si, and C, Steel Res. Int., 93(2022), No. 10, art. No. 2200173. |
| [19] |
G. Gu, J.H. Kim, H.H. Lee, et al., Room temperature quenching and partitioning (RT-Q&P) processed steel with chemically heterogeneous initial microstructure, Mater. Sci. Eng. A, 851(2022), art. No. 143651. |
| [20] |
Q. Zhu, J.H. Gao, H.T. Zhao, et al., Heterostructure mediated high strength and large ductility in novel medium-Mn steels with low Mn content, Acta Mater., 276(2024), art. No. 120092. |
| [21] |
|
| [22] |
|
| [23] |
J. Wang, Q. Tao, J.T. Fan, L.M. Fu, and A.D. Shan, Enhanced mechanical properties of a high-carbon martensite steel processed by heavy warm rolling and tempering, Mater. Sci. Eng. A, 872(2023), art. No. 144958. |
| [24] |
|
| [25] |
|
| [26] |
|
| [27] |
W.Q. Mao, S. Gao, W. Gong, et al., Quantitatively evaluating respective contribution of austenite and deformation-induced martensite to flow stress, plastic strain, and strain hardening rate in tensile deformed TRIP steel, Acta Mater., 256(2023), art. No. 119139. |
| [28] |
|
| [29] |
C.H. Song, Z.S. Zhang, W.Y. Wu, et al., Effect of Si on the dislocation state within martensite of ultra-high strength hot-rolled medium Mn steel with good ductility, Mater. Sci. Eng. A, 869(2023), art. No. 144825. |
| [30] |
B.B. He, S. Pan, and M.X. Huang, Extra work hardening in room-temperature quenching and partitioning medium Mn steel enabled by intercritical annealing, Mater. Sci. Eng. A, 797(2020), art. No. 140106. |
| [31] |
|
| [32] |
|
| [33] |
S. Wang, X.H. Xi, Y. Zhao, and L.Q. Chen, Microstructures and mechanical properties of an ultrahigh-strength and ductile medium-carbon high-silicon spring steel, Steel Res. Int., 94(2023), No. 1, art. No. 2200149. |
| [34] |
|
| [35] |
K. Chen, Z.H. Jiang, F.B. Liu, et al., Enhanced mechanical properties by retained austenite in medium–carbon Si-rich microalloyed steel treated by quenching–tempering, austempering and austempering–tempering processes, Mater. Sci. Eng. A 790(2020), art. No. 139742. |
| [36] |
S. Sunil, R. Kapoor, S.K. Sarkar, et al., Ultra-high strength steel made from AISI 304L using a novel thermo-mechanical processing technique, Acta Mater., 221(2021), art. No. 117379. |
| [37] |
|
| [38] |
Z.B. Liu, Z. Yang, X.H. Wang, et al., Enhanced strength-ductility synergy in a new 2.2 GPa grade ultra-high strength stainless steel with balanced fracture toughness: Elucidating the role of duplex aging treatment, J. Alloy. Compd., 928(2022), art. No. 167135. |
| [39] |
|
| [40] |
J.J. Sun, S.W. Guo, S.D. Zhao, M.Y. Ma, and Y.N. Liu, Improving strength of cold-drawn wire by martensitic transformation in a 0.65wt% C low-alloy steel, Mater. Sci. Eng. A, 790(2020), art. No. 139719. |
| [41] |
|
| [42] |
|
| [43] |
F.Y. Zhao, P. Chen, B.Y. Xu, et al., Martensite transformation of retained austenite with diverse stability and strain partitioning during tensile deformation of a carbide-free bainitic steel, Mater. Charact., 179(2021), art. No. 111327. |
| [44] |
|
| [45] |
|
| [46] |
J. Takahashi, K. Kawakami, and S. Teramoto, Difference in hydrogen trapping behaviors between epsilon carbide and cementite in steels, Mater. Charact., 218(2024), art. No. 114557. |
| [47] |
|
| [48] |
|
| [49] |
|
| [50] |
|
| [51] |
|
| [52] |
|
| [53] |
|
| [54] |
|
| [55] |
|
| [56] |
|
| [57] |
G. Park, K. Kim, S. Uhm, and C. Lee, Remarkable improvement in resistance spot weldability of medium-Mn TRIP steel by paint-baking heat treatment, Mater. Sci. Eng. A, 766(2019), art. No. 138401. |
| [58] |
|
| [59] |
|
| [60] |
|
| [61] |
Y. Wang, Y.B. Xu, T.Y. Zhang, J.Y. Li, X.Y. Hou, and W.H. Sun, Effects of quenching temperature on bainite transformation, retained austenite and mechanical properties of hot-galvanized Q&P steel, Mater. Sci. Eng. A, 822(2021), art. No. 141643. |
| [62] |
W.J. Yin, F. Briffod, H.Y. Hu, K. Yamazaki, T. Shiraiwa, and M. Enoki, Role of prior austenite grain boundary and retained austenite in strain localization of medium-carbon high-strength steels, Acta Mater., 281(2024), art. No. 120422. |
| [63] |
|
| [64] |
|
| [65] |
|
| [66] |
|
| [67] |
|
| [68] |
|
| [69] |
G. Liu, Y.Q. Li, T.C. Liao, et al., Revealing the precipitation kinetics and strengthening mechanisms of a 450 MPa grade Nb-bearing HSLA steel, Mater. Sci. Eng. A, 884(2023), art. No. 145506. |
| [70] |
|
University of Science and Technology Beijing
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