Reducing bentonite usage in iron ore pelletization through synergistic modification with mechanical force and DMSO: Effects and mechanisms

Yinrui Dong , Yongbin Yang , Lin Wang , Qianqian Duan , Qian Li , Yan Zhang , Tao Jiang

International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (1) : 177 -190.

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International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (1) :177 -190. DOI: 10.1007/s12613-025-3182-y
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Reducing bentonite usage in iron ore pelletization through synergistic modification with mechanical force and DMSO: Effects and mechanisms

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Abstract

Bentonite is a necessary binder in producing pellets. Its excessive use reduces the iron grade of pellets and increases production costs. Minimizing bentonite dosage is essential for producing high-quality iron ore pellets. Addressing the gap in the application of organically-intercalated modified bentonite in the pelletizing field, this study introduces an innovative modification process for bentonite that employs the synergistic effect of mechanical force and dimethyl sulfoxide to enhance the intercalation of organic compounds within bentonite, thus significantly enhancing its binding performance. The colloid value and swell capacity of modified bentonite (98.5 mL/3g and 55.0 mL/g) were much higher than the original bentonite (90.5 mL/3g and 17.5 mL/g). With the decrease of bentonite dosage from 1.5wt% to 1.0wt%, the drop number of green pellets from a height of 0.5 m and the compressive strengths of roasted pellets using the modified bentonite (6.0 times and 2916 N per pellet) were significantly higher than those of the original bentonite (4.0 times and 2739 N per pellet). This study provides a comprehensive analysis of the intercalation modification mechanism of bentonite, offering crucial technical insights for the development of high-performance modified bentonite as iron ore pellet binders.

Keywords

pellets / bentonite modification / mechanical force / dimethyl sulfoxide / organic intercalation

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Yinrui Dong, Yongbin Yang, Lin Wang, Qianqian Duan, Qian Li, Yan Zhang, Tao Jiang. Reducing bentonite usage in iron ore pelletization through synergistic modification with mechanical force and DMSO: Effects and mechanisms. International Journal of Minerals, Metallurgy, and Materials, 2026, 33(1): 177-190 DOI:10.1007/s12613-025-3182-y

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References

[1]

Kotta AB, Patra A, Kumar M, Karak SK. Effect of molasses binder on the physical and mechanical properties of iron ore pellets. Int. J. Miner. Metall. Mater., 2019, 26(1): 41.

[2]

Mishra B, Singh AK, Rao LS, Mahobia GS. Reducibility and kinetic studies of pellets made from a novel multimetallic magnetite ore. Trans. Indian Inst. Met., 2023, 76(1): 77.

[3]

Kawatra SK, Ripke SJ. Laboratory studies for improving green ball strength in bentonite-bonded magnetite concentrate pellets. Int. J. Miner. Process., 2003, 72(1–4): 429.

[4]

H. Liu, B. Xie, and Y.L. Qin, Effect of bentonite on the pelleting properties of iron concentrate, J. Chem., 2017(2017), No. 1, art. No. 7639326.

[5]

Basha SM, Ramesh MSS, Dwarapudi S, et al. . Influence of sodium hydroxide (NaOH) on green and fired pellet properties. Metall. Mater. Trans. B, 2024, 55(4): 2079.

[6]

Feng JG, Tang J, Zhao ZC, et al. . Effect of titanium on the sticking of pellets based on hydrogen metallurgy shaft furnace: Behavior analysis and mechanism evolution. Int. J. Miner. Metall. Mater., 2024, 31(2): 282.

[7]

Ma YH, Li Q, Zhang Y, Yang YB, Tang YH, Jiang T. A novel polymer-type binder to decrease bentonite dosage during iron ore pelletizing: Performance and mechanisms. J. Mater. Res. Technol., 2023, 27: 6900.

[8]

Guo YF, Zhang JL, Wang S, et al. . Diffusion and reaction mechanism of limestone and quartz in fluxed iron ore pellet roasting process. Int. J. Miner. Metall. Mater., 2024, 31(3): 485.

[9]

Sivrikaya O, Arol AI. Pelletization of magnetite ore with colemanite added organic binders. Powder Technol., 2011, 210(1): 23.

[10]

Tian HY, Zhu DQ, Pan J, Yang CC, Huang WQ, Chu MS. Effect mechanism of aluminum occurrence and content on the induration characteristics of iron ore pellets. Int. J. Miner. Metall. Mater., 2023, 30(12): 2334.

[11]

Linhares FM, Victor CCF, Lemos LR, Bagatini MC. Effect of three different binders and pellet feed on granulation behaviour of sintering mixtures. Ironmaking Steelmaking, 2020, 47(9): 991.

[12]

H.X. Zhao, F.S. Zhou, H.Y. Zhao, C.F. Ma, and Y. Zhou, A review on the effect of the mechanism of organic polymers on pellet properties for iron ore beneficiation, Polymers, 14(2022), No. 22, art. No. 4874.

[13]

K. Manu, E. Mousa, H. Ahmed, M. Elsadek, and W.H. Yang, Maximizing the recycling of iron ore pellets fines using innovative organic binders, Materials, 16(2023), No. 10, art. No. 3888.

[14]

Claremboux V, Kawatra SK. Iron ore pelletization: Part III. organic binders. Miner. Process. Extr. Metall. Rev., 2023, 44(2): 138.

[15]

Mishra B, Dishwar RK, Omar RJ, Mahobia GS. Hardening behaviour of pellets prepared from a novel combination of rare multimetallic magnetite ore and binder. Trans. Indian Inst. Met., 2021, 74(8): 2049.

[16]

Fan XH, Gan M, Jiang T, Chen XL, Yuan LS. Decreasing bentonite dosage during iron ore pelletising. Ironmaking Steelmaking, 2011, 38(8): 597.

[17]

Forsmo SPE, Apelqvist AJ, Björkman BMT, Samskog PO. Binding mechanisms in wet iron ore green pellets with a bentonite binder. Powder Technol., 2006, 169(3): 147.

[18]

Zhou YL, Kawatra SK. Pelletization using humic substance-based binder. Miner. Process. Extr. Metall. Rev., 2017, 38(2): 83.

[19]

Ma YH, Li Q, Chen XL, Zhang Y, Yang YB, Zhong Q. Reducing bentonite usage in iron ore pelletization through a novel polymer-type binder: Impact on pellet induration and metallurgical properties. J. Mater. Res. Technol., 2024, 30: 8019.

[20]

Wang C, Xu CY, Liu ZJ, Wang YZ, Wang RR, Ma LM. Effect of organic binders on the activation and properties of indurated magnetite pellets. Int. J. Miner. Metall. Mater., 2021, 28(7): 1145.

[21]

X.H. Wang, Z.F. Zhang, and H.Q. Xie, Preparation, characterization and intercalation mechanism of bentonite modified with different organic ammonium, Chem. Eng. Sci., 301(2025), art. No. 120758.

[22]

Ouellet-Plamondon CM, Stasiak J, Al-Tabbaa A. The effect of cationic, non-ionic and amphiphilic surfactants on the intercalation of bentonite. Colloids Surf. A, 2014, 444: 330.

[23]

Shamsuddin RM, Verbeek CJR, Lay MC. Producing protein intercalated bentonite: Equilibrium, kinetics and physical properties of gelatin–bentonite system. Appl. Clay Sci., 2014, 87: 52.

[24]

S.L. Balasubramaniam, A.S. Patel, and B. Nayak, Surface modification of cellulose nanofiber film with fatty acids for developing renewable hydrophobic food packaging, Food Packag. Shelf Life, 26(2020), art. No. 100587.

[25]

Jimtaisong A, Sarakonsri T. Chitosan intercalated bentonite as natural adsorbent matrix for water-soluble sappanwood dye. Int. J. Biol. Macromol., 2019, 129: 737.

[26]

Q. Li, R. Berraud-Pache, C. Souprayen, and M. Jaber, Intercalation of lecithin into bentonite: pH dependence and intercalation mechanism, Appl. Clay Sci., 244(2023), art. No. 107079.

[27]

Y.Y. Zhu, Y.M. Cui, Y.M. Peng, R. Dai, H. Chen, and Y.Q. Wang, Preparation of CTAB intercalated bentonite for ultrafast adsorption of anionic dyes and mechanism study, Colloids Surf. A, 658(2023), art. No. 130705.

[28]

X. Li, G.S. Zhang, Y. Jin, et al., Removal of Cd from solution and in situ remediation of Cd-contaminated soil by a mercapto-modified cellulose/bentonite intercalated nanocomposite, Environ. Res., 251(2024), art. No. 118303.

[29]

Feng Z, Qi JQ, Huang X, et al. . Planetary ball-milling of AlON powder for highly transparent ceramics. J. Am. Ceram. Soc., 2019, 102(5): 2377.

[30]

A. Mannu, M. Poddighe, M. Mureddu, et al., Impact of morphology of hydrophilic and hydrophobic bentonites on improving the pour point in the recycling of waste cooking oils, Appl. Clay Sci., 262(2024), art. No. 107607.

[31]

F.J. Shi, S.J. Feng, Q.T. Zheng, X.L. Zhang, and H.X. Chen, Effect of polyanionic cellulose modification on properties and microstructure of calcium bentonite, Appl. Clay Sci., 228(2022), art. No. 106633.

[32]

Y.H. Yi, G.H. Li, P.X. Cao, et al., Effect of humic acid binder on oxidation roasting of vanadium–titanium magnetite pellets via straight-grate process, Crystals, 11(2021), No. 11, art. No. 1283.

[33]

Theng BKG. Clay-polymer interactions: Summary and perspectives. Clays Clay Miner., 1982, 30(1): 1.

[34]

Y.B. Zhang, M.M. Lu, Z.J. Su, et al., Interfacial reaction between humic acid and Ca-Montmorillonite: Application in the preparation of a novel pellet binder, Appl. Clay Sci., 180(2019), art. No. 105177.

[35]

Karelin AI, Kayumov RR, Dobrovolsky YA. FTIR spectroscopic study of the interaction between NH4+ and DMSO in Nafion. Spectrochim. Acta Part A, 2019, 215: 381.

[36]

Yu C, Liao RP, Cai XQ, Yu XN. Sodium polyacrylate modification method to improve the permeant performance of bentonite in chemical resistance. J. Cleaner Prod., 2019, 213: 242.

[37]

Otsuki A, Hayagan NL. Zeta potential of inorganic fine particle: Na-bentonite binder mixture systems. Electrophoresis, 2020, 41(16–17): 1405.

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