Corrosion behavior of 650 MPa high strength low alloy steel in industrial polluted environments containing different concentrations of Cl−
Lianjun Hao , Xiaokun Cai , Tianqi Chen , Chenyu Zhang , Chao Liu , Xuequn Cheng , Xiaogang Li
International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (1) : 228 -241.
Corrosion behavior of 650 MPa high strength low alloy steel in industrial polluted environments containing different concentrations of Cl−
This study utilizes wet/dry cyclic corrosion testing combined with corrosion big data technology to investigate the mechanism by which chloride ions (Cl−) influence the corrosion behavior of 650 MPa high-strength low-alloy (HSLA) steel in industrially polluted environments. The corrosion process of 650 MPa HSLA steel occurred in two distinct stages: an initial corrosion stage and a stable corrosion stage. During the initial phase, the weight loss rate increased rapidly owing to the instability of the rust layer. Notably, this study demonstrated that 650 MPa HSLA steel exhibited superior corrosion resistance in Cl-containing environments. The formation of a corrosion-product film eventually reduced the weight-loss rate. However, the intrusion of Cl− at increasing concentrations gradually destabilized the α/γ* phases of the rust layer, leading to a looser structure and lower polarization resistance (Rp). The application of corrosion big data technology in this study facilitated the validation and analysis of the experimental results, offering new insights into the corrosion mechanisms of HSLA steel in chloride-rich environments.
HSLA steel / chlorine / corrosion behavior / corrosion big data
| [1] |
|
| [2] |
R.C. Chen, L.Y. Chen, Z.G. Wang, R.G. Guan, and H.J. Kang, Heterogeneous nucleation of carbides attached to Y2O3 in Y-modified H13 steel, Mater. Charact., 200(2023), art. No. 112891. |
| [3] |
X.P. Guo, M. Tan, T. Li, et al., Formation mechanisms and three-dimensional characterization of composite inclusion of MnS–Al2O3 in high speed wheel steel, Mater. Charact., 197(2023), art. No. 112669. |
| [4] |
|
| [5] |
|
| [6] |
W.Z. Yan, X. Luo, G. Xu, H.H. Wang, Z.D. Wang, and X.H. Chen, Significant improvement in CGHAZ toughness of HSLA steel via welding with trailing mechanical treatment, Mater. Sci. Eng. A, 837(2022), art. No. 142725. |
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
|
| [11] |
|
| [12] |
|
| [13] |
|
| [14] |
D.N. Staicopolus, The role of cementite in the acidic corrosion of steel, J. Electrochem. Soc., 110(1963), No. 11, art. No. 1121. |
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
|
| [19] |
|
| [20] |
|
| [21] |
J.A. Rodríguez, J. Cruz-Borbolla, P.A. Arizpe-Carreón, and E. Gutiérrez, Mathematical models generated for the prediction of corrosion inhibition using different theoretical chemistry simulations, Materials, 13(2020), No. 24, art. No. 5656. |
| [22] |
N. Van den Steen, Y. Gonzalez-Garcia, J.M.C. Mol, H. Terryn, and Y. Van Ingelgem, Predicting the effect of droplet geometry and size distribution on atmospheric corrosion, Corros. Sci., 202(2022), art. No. 110308. |
| [23] |
|
| [24] |
|
| [25] |
|
| [26] |
|
| [27] |
|
| [28] |
B.Q. Wang, Y.R. Li, X.Q. Cheng, et al., Data-driven optimization model customization for atmospheric corrosion on low-alloy steel: Incorporating the dynamic evolution of the surface rust layer, Corros. Sci., 221(2023), art. No. 111349. |
| [29] |
|
| [30] |
|
| [31] |
M. Zhu, B.Z. Zhao, Y.F. Yuan, S.Y. Guo, and G.Y. Wei, Study on corrosion behavior and mechanism of CoCrFeMnNi HEA interfered by AC current in simulated alkaline soil environment, J. Electroanal. Chem., 882(2021), art. No. 115026. |
| [32] |
Y.M. Fan, W. Liu, Z.T. Sun, et al., Effect of chloride ion on corrosion resistance of Ni-advanced weathering steel in simulated tropical marine atmosphere, Constr. Build. Mater., 266(2021), art. No. 120937. |
| [33] |
Z.H. Jiang, T.Q. Chen, Z.C. Che, et al., Effect of Ca–Mg microalloying on corrosion behavior and corrosion resistance of low alloy steel in the marine atmospheric environment, Corros. Sci., 234(2024), art. No. 112134. |
| [34] |
T.Y. Zhang, Y.L. Li, X. Li, et al., Integral effects of Ca and Sb on the corrosion resistance for the high strength low alloy steel in the tropical marine environment, Corros. Sci., 208(2022), art. No. 110708. |
| [35] |
T.Q. Chen, X.K. Cai, Y.B. Zhong, et al., Assessing the durability of low-alloy rebars in China plateau environment by outdoor exposure and on-site online monitoring, Constr. Build. Mater., 468(2025), art. No. 140475. |
| [36] |
Z.B. Pei, D.W. Zhang, Y.J. Zhi, et al., Towards understanding and prediction of atmospheric corrosion of an Fe/Cu corrosion sensor via machine learning, Corros. Sci., 170(2020), art. No. 108697. |
| [37] |
|
| [38] |
|
| [39] |
|
| [40] |
|
| [41] |
R. Díaz-Uriarte and S. Alvarez de Andrés, Gene selection and classification of microarray data using random forest, BMC Bioinformatics, 7(2006), art. No. 3. |
| [42] |
|
| [43] |
|
| [44] |
|
| [45] |
|
| [46] |
|
| [47] |
|
| [48] |
W. Wu, Z.Y. Liu, Q.Y. Wang, and X.G. Li, Improving the resistance of high-strength steel to SCC in a SO2− polluted marine atmosphere through Nb and Sb microalloying, Corros. Sci., 170(2020), art. No. 108693. |
| [49] |
H.X. Liu, F. Huang, W. Yuan, Q. Hu, J. Liu, and Y.F. Cheng, Essential role of element Si in corrosion resistance of a bridge steel in chloride atmosphere, Corros. Sci., 173(2020), art. No. 108758. |
| [50] |
|
| [51] |
Y. Yang, X.Q. Cheng, J.B. Zhao, Y. Fan, and X.G. Li, A study of rust layer of low alloy structural steel containing 0.1% Sb in atmospheric environment of the Yellow Sea in China, Corros. Sci., 188(2021), art. No. 109549. |
| [52] |
|
| [53] |
H. Chen, H.Y. Cui, Z.B. He, L. Lu, and Y.H. Huang, Influence of chloride deposition rate on rust layer protectiveness and corrosion severity of mild steel in tropical coastal atmosphere, Mater. Chem. Phys., 259(2021), art. No. 123971. |
| [54] |
|
| [55] |
|
| [56] |
|
| [57] |
|
| [58] |
|
| [59] |
Y.F. Wang, J.G. Li, Q.F. Wang, and T.S. Wang, Some new discoveries on the structure of the rust layer of weathering steel in a simulated industrial atmosphere by STEM-EDS and HRTEM, Corros. Sci., 183(2021), art. No. 109322. |
| [60] |
|
| [61] |
W. Wu, Z.Y. Dai, Z.Y. Liu, C. Liu, and X.G. Li, Synergy of Cu and Sb to enhance the resistance of 3% Ni weathering steel to marine atmospheric corrosion, Corros. Sci., 183(2021), art. No. 109353. |
| [62] |
|
| [63] |
|
| [64] |
|
| [65] |
|
| [66] |
|
| [67] |
|
University of Science and Technology Beijing
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