Review of recent advances in ferrite-based materials: From synthesis techniques to electromagnetic wave absorption performance
Xingliang Chen , Di Lan , Luoting Zhou , Hailing Liu , Xiyu Song , Shouyu Wang , Zhuanyong Zou , Guanglei Wu
International Journal of Minerals, Metallurgy, and Materials ›› 2025, Vol. 32 ›› Issue (3) : 591 -608.
Review of recent advances in ferrite-based materials: From synthesis techniques to electromagnetic wave absorption performance
With the booming development of electronic information science and 5G communication technology, electromagnetic radiation pollution poses a huge threat and damage to humanity. Developing novel and high-performance electromagnetic wave (EMW) absorbers is an effective method to solve the above issue and has attracted the attention of many researchers. As a typical magnetic material, ferrite plays an important role in the design of high-performance EMW absorbers, and related research focuses on diversified synthesis methods, strong absorption performance, and refined microstructure development. Herein, we focus on the synthesis of ferrites and their composites and introduce recent advances in the high-temperature solid-phase method, sol–gel method, chemical coprecipitation method, and solvent thermal method in the preparation of high-performance EMW absorbers. This review aims to help researchers understand the advantages and disadvantages of ferrite-based EMW absorbers fabricated through these methods. It also provides important guidance and reference for researchers to design high-performance EMW absorption materials based on ferrite.
| [1] |
S.J. Zhang, D. Lan, J.J. Zheng, et al., Perspectives of nitrogen-doped carbons for electromagnetic wave absorption, Carbon, 221(2024), art. No. 118925. |
| [2] |
X.G. Su, J. Wang, T. Liu, et al., Controllable atomic migration in microstructures and defects for electromagnetic wave absorption enhancement, Adv. Funct. Mater., 34(2024), No. 39, art. No. 2403397. |
| [3] |
Z.R. Jia, X.Y. Zhang, Z. Gu, and G.L. Wu, MOF-derived Ni–Co bimetal/porous carbon composites as electromagnetic wave absorber, Adv. Compos. Hybrid Mater., 6(2022), No. 1, art. No. 28. |
| [4] |
|
| [5] |
J.P. Li, X.P. Liu, H.Y. Zhao, et al., Dual-Phase engineering of Ni3S2/NiCo-MOF nanocomposites for enhanced ion storage and electron migration, Chem. Eng. J., 489(2024), art. No. 151069. |
| [6] |
D.L. Tan, Q. Wang, M.R. Li, et al., Magnetic media synergistic carbon fiber@Ni/NiO composites for high-efficiency electromagnetic wave absorption, Chem. Eng. J., 492(2024), art. No. 152245. |
| [7] |
L.X. Gai, H.H. Zhao, X.A. Li, et al., Shell engineering afforded dielectric polarization prevails and impedance amelioration toward electromagnetic wave absorption enhancement in nested-network carbon architecture, Chem. Eng. J., 501(2024), art. No. 157556. |
| [8] |
L.M. Song, Y.Q. Chen, Q.C. Gao, et al., Low Weight, low thermal Conductivity, and highly efficient electromagnetic wave absorption of three-dimensional graphene/SiC-nanosheets aerogel, Compos. Part A: Appl. Sci. Manuf., 158(2022), art. No. 106980. |
| [9] |
F.Y. Hu, X.H. Wang, S. Bao, et al., Tailoring electromagnetic responses of delaminated Mo2TiC2Tx MXene through the decoration of Ni particles of different morphologies, Chem. Eng. J., 440(2022), art. No. 135855. |
| [10] |
|
| [11] |
D.S. Wang, A. Mukhtar, K.M. Wu, L.Y. Gu, and X.M. Cao, Multi-segmented nanowires: A high tech bright future, Materials, 12(2019), No. 23, art. No. 3908. |
| [12] |
Z.H. Zhou, X.F. Zhou, D. Lan, et al., Modulation engineering of electromagnetic wave absorption performance of layered double hydroxides derived hollow metal carbides integrating corrosion protection, Small, 20(2024), No. 8, art. No. 2305849. |
| [13] |
|
| [14] |
|
| [15] |
|
| [16] |
|
| [17] |
D.D. Xiang, Q.C. He, D. Lan, Y.Q. Wang, and X.M. Yin, Regulating the phase composition and microstructure of Fe3Si/SiC nanofiber composites to enhance electromagnetic wave absorption, Chem. Eng. J., 498(2024), art. No. 155406. |
| [18] |
|
| [19] |
X.L. Chen, F. Zhang, D. Lan, et al., State-of-the-art synthesis strategy for nitrogen-doped carbon-based electromagnetic wave absorbers: From the perspective of nitrogen source, Adv. Compos. Hybrid Mater., 6(2023), No. 6, art. No. 220. |
| [20] |
S.J. Zhang, Z.G. Gao, Z.B. Sun, et al., Solid solution strategy for bimetallic metal-polyphenolic networks deriving electromagnetic wave absorbers with regulated heterointerfaces, Appl. Surf. Sci., 611(2023), art. No. 155707. |
| [21] |
|
| [22] |
G.H. Wang, Y. Zhao, F. Yang, Y. Zhang, M. Zhou, and G.B. Ji, Multifunctional integrated transparent film for efficient electromagnetic protection, Nano Micro Lett., 14(2022), No. 1, art. No. 65. |
| [23] |
Y.F. He, Q. Su, D.D. Liu, et al., Surface engineering strategy for MXene to tailor electromagnetic wave absorption performance, Chem. Eng. J., 491(2024), art. No. 152041. |
| [24] |
L. Wang, X. Li, Q.Q. Li, et al., Oriented polarization tuning broadband absorption from flexible hierarchical ZnO arrays vertically supported on carbon cloth, Small, 15(2019), No. 18, art. No. 1900900. |
| [25] |
S.J. Zhang, J.J. Zheng, D. Lan, et al., Hierarchical engineering on built-in electric field of bimetallic zeolitic imidazolate derivatives towards amplified dielectric loss, Adv. Funct. Mater., (2024), art. No. 2413884. |
| [26] |
L.M. Song, F. Zhang, Y.Q. Chen, et al., Multifunctional SiC@SiO2 nanofiber aerogel with ultrabroadband electromagnetic wave absorption, Nano Micro Lett., 14(2022), No. 1, art. No. 152. |
| [27] |
|
| [28] |
|
| [29] |
|
| [30] |
L.M. Song, C.W. Wu, Q. Zhi, et al., Multifunctional SiC aerogel reinforced with nanofibers and nanowires for high-efficiency electromagnetic wave absorption, Chem. Eng. J., 467(2023), art. No. 143518. |
| [31] |
M. Yuan, M. Zhou, and H.Q. Fu, Synergistic microstructure of sandwich-like NiFe2O4@SiO2@MXene nanocomposites for enhancement of microwave absorption in the whole Ku-band, Compos. Part B: Eng., 224(2021), art. No. 109178. |
| [32] |
X. Yang, L.X. Xuan, W.W. Men, et al., Carbonyl iron/glass fiber cloth composites: Achieving multi-spectrum stealth in a wide temperature range, Chem. Eng. J., 491(2024), art. No. 151862. |
| [33] |
G.X. Ding, C.X. Chen, H.X. Tai, et al., Structural characterization and microwave absorbing performance of CuFe2O4/RGO composites, J. Solid State Chem., 297(2021), art. No. 122051. |
| [34] |
|
| [35] |
J.M. Tang, K.X. Wang, Y.X. Lu, et al., Mesoporous core-shell structure NiFe2O4@polypyrrole micro-rod with efficient electromagnetic wave absorption in C, X, Ku wavebands, J. Magn. Magn. Mater., 514(2020), art. No. 167268. |
| [36] |
|
| [37] |
|
| [38] |
|
| [39] |
|
| [40] |
S. Chen, Y.B. Meng, X.L. Wang, et al., Hollow tubular MnO2/MXene (Ti3C2, Nb2C, and V2C) composites as high-efficiency absorbers with synergistic anticorrosion performance, Carbon, 218(2024), art. No. 118698. |
| [41] |
|
| [42] |
|
| [43] |
|
| [44] |
X.X. Zhao, Y. Huang, J. Yan, et al., Excellent electromagnetic wave absorption properties of the ternary composite ZnFe2O4@PANI–rGO optimized by introducing covalent bonds, Compos. Sci. Technol., 210(2021), art. No. 108801. |
| [45] |
|
| [46] |
J.Y. Hu, X.S. Liu, X.C. Kan, et al., Characterization of texture and magnetic properties of Ni0.5Zn0.5TixFe2−xO4 spinel ferrites, J. Magn. Magn. Mater., 489(2019), art. No. 165411. |
| [47] |
|
| [48] |
|
| [49] |
|
| [50] |
|
| [51] |
|
| [52] |
Z.L. Li, H. Zhu, L.J. Rao, et al., Wrinkle structure regulating electromagnetic parameters in constructed core–shell ZnFe2O4@PPy microspheres as absorption materials, Small, 20(2024), No. 16, art. No. 2308581. |
| [53] |
|
| [54] |
|
| [55] |
|
| [56] |
Z.Q. Guo, D. Lan, Z.R. Jia, et al., Multiple tin compounds modified carbon fibers to construct heterogeneous interfaces for corrosion prevention and electromagnetic wave absorption, Nano Micro Lett., 17(2024), No. 1, art. No. 23. |
| [57] |
|
| [58] |
|
| [59] |
|
| [60] |
|
| [61] |
S.J. Cheon, J.R. Choi, S.B. Lee, J.I. Lee, and H. Lee, Frequency tunable Ni–Ti-substituted Ba–M hexaferrite for efficient electromagnetic wave absorption in 8.2–75 GHz range, J. Alloy. Compd., 976(2024), art. No. 173019. |
| [62] |
|
| [63] |
|
| [64] |
|
| [65] |
|
| [66] |
|
| [67] |
|
| [68] |
|
| [69] |
|
| [70] |
|
| [71] |
|
| [72] |
F.A. Wahaab, L.L. Adebayo, A.A. Adekoya, I.G. Hakeem, B. Alqasem, and A.M. Obalalu, Physiochemical properties and electromagnetic wave absorption performance of Ni0.5Cu0.5Fe2O4 nanoparticles at X-band frequency, J. Alloy. Compd., 836(2020), art. No. 155272. |
| [73] |
|
| [74] |
|
| [75] |
|
| [76] |
|
| [77] |
J.T. Zhou, B. Wei, M.Q. Wang, et al., Three dimensional flower like ZnFe2O4 ferrite loaded graphene: Enhancing microwave absorption performance by constructing microcircuits, J. Alloy. Compd., 889(2021), art. No. 161734. |
| [78] |
T.T. Zheng, Y. Zhang, Z.R. Jia, J.H. Zhu, G.L. Wu, and P.F. Yin, Customized dielectric-magnetic balance enhanced electromagnetic wave absorption performance in CuxS/CoFe2O4 composites, Chem. Eng. J., 457(2023), art. No. 140876. |
| [79] |
F. Zhang, W. Cui, B.B. Wang, et al., Morphology-control synthesis of polyaniline decorative porous carbon with remarkable electromagnetic wave absorption capabilities, Compos. Part B: Eng., 204(2021), art. No. 108491. |
| [80] |
|
| [81] |
|
| [82] |
|
| [83] |
L.G. Ren, Y.Q. Wang, Z.R. Jia, Q.C. He, and G.L. Wu, Controlling the heterogeneous interfaces of Fe3O4/N-doped porous carbon via facile swelling for enhancing the electromagnetic wave absorption, Compos. Commun., 29(2022), art. No. 101052. |
| [84] |
C.H. Sun, D. Lan, Z.R. Jia, Z.G. Gao, and G.L. Wu, Kirkend-all effect-induced ternary heterointerfaces engineering for high polarization loss MOF–LDH–MXene absorbers, Small, 20(2024), No. 48, art. No. 2405874. |
| [85] |
S. Golchinvafa, S.M. Masoudpanah, and M. Jazirehpour, Magnetic and microwave absorption properties of FeCo/CoFe2O4 composite powders, J. Alloy. Compd., 809(2019), art. No. 151746. |
| [86] |
|
| [87] |
|
| [88] |
|
| [89] |
Y. Yuan, S.C. Wei, Y. Liang, et al., Solvothermal assisted synthesis of CoFe2O4/CNTs nanocomposite and their enhanced microwave absorbing properties, J. Alloy. Compd., 867(2021), art. No. 159040. |
| [90] |
T. Ma, Y. Cui, Y.L. Sha, et al., Facile synthesis of hierarchically porous rGO/MnZn ferrite composites for enhanced microwave absorption performance, Synth. Met., 265(2020), art. No. 116407. |
| [91] |
|
| [92] |
|
| [93] |
|
| [94] |
|
| [95] |
S.Y. Guo, H.L. Guan, Y. Li, et al., Dual-loss Ti3C2Tx MXene/Ni0.6Zn0.4Fe2O4 heterogeneous nanocomposites for highly efficient electromagnetic wave absorption, J. Alloy. Compd., 887(2021), art. No. 161298. |
| [96] |
|
| [97] |
|
| [98] |
H.X. Zhang, Z.R. Jia, B.B. Wang, et al., Construction of remarkable electromagnetic wave absorber from heterogeneous structure of Co–CoFe2O4@mesoporous hollow carbon spheres, Chem. Eng. J., 421(2021), art. No. 129960. |
| [99] |
|
| [100] |
Y.Y. Ma, Y.H. Jiang, C.Y. Wang, S.B. Kang, G.Q. Chen, and B. Zhong, Microwave absorption performance enhancement of NiFe2O4/GNs composite with hollow hexagonal-like structure, J. Magn. Magn. Mater., 565(2023), art. No. 170281. |
| [101] |
M. Liu, B. Zhao, K. Pei, et al., An ion-engineering strategy to design hollow FeCo/CoFe2O4 microspheres for high-performance microwave absorption, Small, 19(2023), No. 25, art. No. 2300363. |
| [102] |
M.Q. Huang, L. Wang, K. Pei, et al., Heterogeneous interface engineering of bi-metal MOFs-derived ZnFe2O4–ZnO-Fe@C microspheres via confined growth strategy toward superior electromagnetic wave absorption, Adv. Funct. Mater., 34(2024), No. 3, art. No. 2308898. |
| [103] |
J.K. Liu, Z.R. Jia, W.H. Zhou, et al., Self-assembled MoS2/magnetic ferrite CuFe2O4 nanocomposite for high-efficiency microwave absorption, Chem. Eng. J., 429(2022), art. No. 132253. |
| [104] |
|
University of Science and Technology Beijing
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