Towards understanding and prediction of corrosion degradation of organic coatings under tropical marine atmospheric environment via a data-driven approach
Shaopeng Liu , Lingwei Ma , Jinke Wang , Yiran Li , Haiyan Gong , Haitao Ren , Xiaogang Li , Dawei Zhang
International Journal of Minerals, Metallurgy, and Materials ›› 2025, Vol. 32 ›› Issue (5) : 1151 -1161.
Towards understanding and prediction of corrosion degradation of organic coatings under tropical marine atmospheric environment via a data-driven approach
The corrosion degradation of organic coatings in tropical marine atmospheric environments results in substantial economic losses across various industries. The complexity of a dynamic environment, combined with high costs, extended experimental periods, and limited data, places a limit on the comprehension of this process. This study addresses this challenge by investigating the corrosion degradation of damaged organic coatings in a tropical marine environment using an atmospheric corrosion monitoring sensor and a random forest (RF) model. For damage simulation, a polyurethane coating applied to a Fe/graphite corrosion sensor was intentionally scratched and exposed to the marine atmosphere for over one year. Pearson correlation analysis was performed for the collection and filtering of environmental and corrosion current data. According to the RF model, the following specific conditions contributed to accelerated degradation: relative humidity (RH) above 80% and temperatures below 22.5°C, with the risk increasing significantly when RH exceeded 90%. High RH and temperature exhibited a cumulative effect on coating degradation. A high risk of corrosion occurred in the nighttime. The RF model was also used to predict the coating degradation process using environmental data as input parameters, with the accuracy showing improvement when the duration of influential environmental ranges was considered.
organic coating degradation / atmospheric corrosion / machine learning / exposure test / random forest / coating sensor
| [1] |
|
| [2] |
T. Grøntoft, A. Verney-Carron, and J. Tidblad, Cleaning costs for European sheltered white painted steel and modern glass surfaces due to air pollution since the year 2000, Atmosphere, 10(2019), No. 4, art. No. 167. |
| [3] |
J.L. Song, X. Liu, W. Hu, T.Y. Zhu, K. Xiao, and J. Gao, Corrosion and aging behavior of epoxy/polyurethane coatings on carbon steel in a subhumid environment, Int. J. Electrochem. Sci., 17(2022), No. 6, art. No. 22063. |
| [4] |
|
| [5] |
|
| [6] |
|
| [7] |
X. Cheng, M.Y. Fu, W.W. Dou, S.Q. Chen, and G.Z. Liu, Accelerated degradation of cathodic protected epoxy coating by Pseudomonas aeruginosa in seawater, Constr. Build. Mater., 408(2023), art. No. 133640. |
| [8] |
D.W. Zhou, Z.Y. Wang, Y. Zhang, et al., Stimulated corrosion damage of Ti–Al–N multilayer coatings under interval salt spray and hot condition, Corros. Sci., 222(2023), art. No. 111431. |
| [9] |
|
| [10] |
|
| [11] |
X.B. Dai, J.S. Qian, J.H. Qin, X.W. Jia, and H. Tang, Preparation and properties of gradient fire & corrosion protection magnesium phosphate cement coatings, Dev. Built Environ., 17(2024), art. No. 100327. |
| [12] |
Y. Huang, T. Liu, L.W. Ma, J.K. Wang, D.W. Zhang, and X.G. Li, Saline-responsive triple-action self-healing coating for intelligent corrosion control, Mater. Des., 214(2022), art. No. 110381. |
| [13] |
|
| [14] |
J.K. Wang, L.W. Ma, Y. Huang, et al., Photothermally activated self-healing protective coating based on the “close and seal” dual-action mechanisms, Compos. B Eng., 231(2022), art. No. 109574. |
| [15] |
J.Q. Feng, Y.B. Wang, X.L. Lin, M.H. Bian, and Y.Z. Wei, SECM in situ investigation of corrosion and self-healing behavior of trivalent chromium conversion coating on the zinc, Surf. Coat. Technol., 459(2023), art. No. 129411. |
| [16] |
M. Razizadeh, M. Mahdavian, B. Ramezanzadeh, E. Alibakhshi, and S. Jamali, Synthesis of hybrid organic–inorganic inhibitive pigment based on basil extract and zinc cation for application in protective construction coatings, Constr. Build. Mater., 287(2021), art. No. 123034. |
| [17] |
J.K. Wang, L.W. Ma, Z.B. Chen, et al., Multi-channel preparation and high-throughput screening of coating fillers with optimized corrosion sensing and inhibition properties for smart protective coatings, Corros. Sci., 222(2023), art. No. 111390. |
| [18] |
Y. Wang, W.M. Tan, X.L. Luo, et al., A novel self-healing coating with mechanically-triggered self-reporting properties: Color and fluorescence dual damage indications, Prog. Org. Coat., 187(2024), art. No. 108147. |
| [19] |
J.K. Wang, L.W. Ma, X. Guo, et al., Two birds with one stone: Nanocontainers with synergetic inhibition and corrosion sensing abilities towards intelligent self-healing and self-reporting coating, Chem. Eng. J., 433(2022), art. No. 134515. |
| [20] |
A.J. Cornet, A.M. Homborg, P.R. Anusuyadevi, L.’ t Hoen-Velterop, and J.M.C. Mol, Unravelling corrosion degradation of aged aircraft components protected by chromate-based coatings, Eng. Fail. Anal., 159(2024), art. No. 108070. |
| [21] |
C. Xie, P. Zhang, M.S. Xue, et al., Long-lasting anti-corrosion of superhydrophobic coating by synergistic modification of graphene oxide with polydopamine and cerium oxide, Constr. Build. Mater., 418(2024), art. No. 135283. |
| [22] |
|
| [23] |
C. Qiao, Q. Wu, L. Hao, et al., Material selection in making electrochemical impedance spectroscopy sensor for electrolyte thickness measurement in marine atmosphere, Corros. Sci., 221(2023), art. No. 111373. |
| [24] |
X.Z. Ma, L.D. Meng, X.K. Cao, X.X. Zhang, and Z.H. Dong, Investigation on the initial atmospheric corrosion of mild steel in a simulated environment of industrial coastland by thin electrical resistance and electrochemical sensors, Corros. Sci., 204(2022), art. No. 110389. |
| [25] |
|
| [26] |
|
| [27] |
|
| [28] |
F.J. Tang, J.W. Bai, G. Li, Z.B. Lin, and H.N. Li, Monitoring under-coating corrosion of painted structural steel with no-core fiber optic sensors, Measurement, 225(2024), art. No. 114075. |
| [29] |
T. Liu, D.W. Zhang, R.J. Zhang, et al., Self-healing and corrosion-sensing coatings based on pH-sensitive MOF-capped microcontainers for intelligent corrosion control, Chem. Eng. J., 454(2023), art. No. 140335. |
| [30] |
Z.B. Pei, D.W. Zhang, Y.J. Zhi, et al., Towards understanding and prediction of atmospheric corrosion of an Fe/Cu corrosion sensor via machine learning, Corros. Sci., 170(2020), art. No. 108697. |
| [31] |
Q. Li, X.J. Xia, Z.B. Pei, et al., Long-term corrosion monitoring of carbon steels and environmental correlation analysis via the random forest method, npj Mater. Degrad., 6(2022), art. No. 1. |
| [32] |
|
| [33] |
|
| [34] |
|
| [35] |
J. Yang, J.X. Xin, Y.Q. Zhang, X.M. Xiao, and J.C. Xia, Contributions of sea–land breeze and local climate zones to daytime and nighttime heat island intensity, npj Urban Sustain., 2(2022), No. 1, art. No. 12. |
| [36] |
Y.F. Zhou, H.D. Guan, C.Y. Huang, et al., Sea breeze cooling capacity and its influencing factors in a coastal city, Build. Environ., 166(2019), art. No. 106408. |
| [37] |
|
| [38] |
|
| [39] |
Y.J. Zhi, Z.H. Jin, L. Lu, et al., Improving atmospheric corrosion prediction through key environmental factor identification by random forest-based model, Corros. Sci., 178(2021), art. No. 109084. |
| [40] |
M. Hoseinpoor, T. Prošek, L. Babusiaux, and J. Mallégol, Toward more realistic time of wetness measurement by means of surface relative humidity, Corros. Sci., 177(2020), art. No. 108999. |
| [41] |
|
| [42] |
J.H. Chen, J.L. Song, W. Hu, T.Y. Zhu, J. Gao, and K. Xiao, Corrosion behaviour of polyurethane coating containing flurocarbon on carbon steel in tropical marine atmospheric environment, Int. J. Electrochem. Sci., 17(2022), No. 11, art. No. 221160. |
| [43] |
J. Liu, Z. Li, L.W. Zhang, et al., Degradation behavior and mechanism of polyurethane coating for aerospace application under atmospheric conditions in South China Sea, Prog. Org. Coat., 136(2019), art. No. 105310. |
| [44] |
H.C. Bi, C.E. Weinell, R. Agudo de Pablo, et al., Rust creep assessment—A comparison between a destructive method according to ISO 12944 and selected non-destructive methods, Prog. Org. Coat., 157(2021), art. No. 106193. |
| [45] |
S. Li, H.C. Bi, C.E. Weinell, and K. Dam-Johansen, A quantitative real-time evaluation of rust creep propagation in coating systems exposed to field testing and cyclic ageing test, Prog. Org. Coat., 184(2023), art. No. 107866. |
| [46] |
|
University of Science and Technology Beijing
/
| 〈 |
|
〉 |