Constructing Ti3C2T x–MXene-based gradient woodpile structure by direct ink writing 3D printing for efficient microwave absorption
Changtian Zhu , Pei Liu , Jin Chen , Zixuan Ding , Guohui Tang , Qingqing Gao , Yinxu Ni , Kai Xu , Zhilei Hao , Gaojie Xu , Fenghua Liu
International Journal of Minerals, Metallurgy, and Materials ›› 2025, Vol. 32 ›› Issue (3) : 657 -667.
Constructing Ti3C2T x–MXene-based gradient woodpile structure by direct ink writing 3D printing for efficient microwave absorption
As a novel 2D material, Ti3C2T x–MXene has become a major area of interest in the field of microwave absorption (MA). However, the MA effect of common Ti3C2T x–MXene is not prominent and often requires complex processes or combinations of other materials to achieve enhanced performance. In this context, a kind of gradient woodpile structure using common Ti3C2T x–MXene as MA material was designed and manufactured through direct ink writing (DIW) 3D printing. The minimum reflection loss (RLmin) of the Ti3C2T x–MXene-based gradient woodpile structures with a thickness of less than 3 mm can reach −70 dB, showing considerable improvement compared with that of a completely filled structure. In addition, the effective absorption bandwidth (EAB) reaches 7.73 GHz. This study demonstrates that a Ti3C2T x–MXene material with excellent MA performance and tunable frequency band can be successfully fabricated with a macroscopic structural design and through DIW 3D printing without complex material hybridization and modification, offering broad application prospects by reducing electromagnetic wave radiation and interference.
| [1] |
B. Anasori, M.R. Lukatskaya, and Y. Gogotsi, 2D metal carbides and nitrides (MXenes) for energy storage, Nat. Rev. Mater., 2(2017), No. 2, art. No. 16098. |
| [2] |
|
| [3] |
|
| [4] |
M. Naguib, M. Kurtoglu, V. Presser, et al., Two-dimensional nanocrystals: Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2, Adv. Mater., 23(2011), No. 37, art. No. 4207. |
| [5] |
|
| [6] |
L. Li, J. Meng, X.R. Bao, et al., Direct-ink-write 3D printing of programmable micro-supercapacitors from MXene-regulating conducting polymer inks, Adv. Energy Mater., 13(2023), No. 9, art. No. 2203683. |
| [7] |
Z.R. Wang, C.L. Wei, H.Y. Jiang, et al., MXene-based current collectors for advanced rechargeable batteries, Adv. Mater., 36(2024), No. 2, art. No. e2306015. |
| [8] |
|
| [9] |
J.L. Hart, K. Hantanasirisakul, A.C. Lang, et al., Control of MXenes’ electronic properties through termination and intercalation, Nat. Commun., 10(2019), No. 1, art. No. 522. |
| [10] |
|
| [11] |
|
| [12] |
H. Wang, Y. Wu, X. Yuan, et al., Clay-inspired MXene-based electrochemical devices and photo-electrocatalyst: State-of-the-art progresses and challenges, Adv. Mater., 30(2018), No. 12, art. No. e1704561. |
| [13] |
|
| [14] |
|
| [15] |
|
| [16] |
G.Q. Zhou, M.C. Li, C.Z. Liu, Q.L. Wu, and C.T. Mei, 3D printed Ti3C2Tx MXene/cellulose nanofiber architectures for solid-state supercapacitors: Ink rheology, 3D printability, and electrochemical performance, Adv. Funct. Mater., 32(2022), No. 14, art. No. 2109593. |
| [17] |
R. Zhou, Y.S. Wang, Z.Y. Liu, Y.Q. Pang, J.X. Chen, and J. Kong, Digital light processing 3D-printed ceramic metamaterials for electromagnetic wave absorption, Nano Micro Lett., 14(2022), No. 1, art. No. 122. |
| [18] |
|
| [19] |
J.H. Peng, J.H. Guo, S.X. Lv, and X.H. Jiang, Novel ZnFe2O4@MnO2@MXene composites with ultrathin thickness and excellent electromagnetic absorption performance, Compos. Commun., 35(2022), art. No. 101316. |
| [20] |
|
| [21] |
Y.N. Ma, N.S. Liu, L.Y. Li, et al., A highly flexible and sensitive piezoresistive sensor based on MXene with greatly changed interlayer distances, Nat. Commun., 8(2017), art. No. 1207. |
| [22] |
|
| [23] |
S. Patra, N.U. Kiran, P. Mane, et al., Hydrophobic MXene with enhanced electrical conductivity, Surf. Interfaces, 39(2023), art. No. 102969. |
| [24] |
|
| [25] |
|
| [26] |
|
| [27] |
A. Lipatov, M. Alhabeb, M.R. Lukatskaya, A. Boson, Y. Gogotsi, and A. Sinitskii, Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes, Adv. Electron. Mater., 2(2016), No. 12, art. No. 1600255. |
| [28] |
|
| [29] |
|
| [30] |
|
| [31] |
|
| [32] |
|
| [33] |
W. Eom, H. Shin, R.B. Ambade, et al., Large-scale wet-spinning of highly electroconductive MXene fibers, Nat. Commun., 11(2020), No. 1, art. No. 2825. |
| [34] |
N. Bhattacharjee, C. Parra-Cabrera, Y.T. Kim, A.P. Kuo, and A. Folch, Desktop-stereolithography 3D-printing of a poly(dimethylsiloxane)-based material with Sylgard-184 properties, Adv. Mater., 30(2018), No. 22, art. No. 1800001. |
| [35] |
P. Liu, S.Q. Shi, Y.X. Ni, et al., Direct ink writing printed flexible double-layer staggered woodpile structure for multi-band compatible absorption of gigahertz and terahertz waves, Chem. Eng. J., 478(2023), art. No. 147474. |
| [36] |
Y. An, R.Y. Cheng, Q.Y. Du, et al., Designable thermal conductivity and mechanical property of polydimethylsiloxane-based composite prepared by thermoset 3D printing, Compos. Sci. Technol., 241(2023), art. No. 110119. |
| [37] |
P.F. Zhu, W.Y. Yang, R. Wang, S. Gao, B. Li, and Q. Li, Direct writing of flexible Barium titanate/polydimethylsiloxane 3D photonic crystals with mechanically tunable terahertz properties, Adv. Opt. Mater., 5(2017), No. 7, art. No. 1600977. |
| [38] |
Y.C. Shao, F. Long, Z.H. Zhao, et al., 4D printing light-driven soft actuators based on liquid–vapor phase transition composites with inherent sensing capability, Chem. Eng. J., 454(2023), art. No. 140271. |
| [39] |
X. Wu, T. Tu, Y. Dai, et al., Direct ink writing of highly conductive MXene frames for tunable electromagnetic interference shielding and electromagnetic wave-induced thermochromism, Nano Micro Lett., 13(2021), No. 1, art. No. 148. |
| [40] |
M.A.S.R. Saadi, A. Maguire, N.T. Pottackal, et al., Direct ink writing: A 3D printing technology for diverse materials, Adv. Mater., 34(2022), No. 28, art. No. e2108855. |
| [41] |
A. Shahzad and I. Lazoglu, Direct ink writing (DIW) of structural and functional ceramics: Recent achievements and future challenges, Composites Part B, 225(2021), art. No. 109249. |
| [42] |
|
| [43] |
|
| [44] |
H.F. Pang, Y.P. Duan, L.X. Huang, et al., Research advances in composition, structure and mechanisms of microwave absorbing materials, Composites Part B, 224(2021), art. No. 109173. |
| [45] |
|
| [46] |
|
| [47] |
M. Qin, L. Zhang, and H. Wu, Dielectric loss mechanism in electromagnetic wave absorbing materials, Adv. Sci., 9(2022), No. 10, art. No. e2105553. |
| [48] |
|
| [49] |
|
| [50] |
L.H. Cheng, Y. Si, Z.J. Ji, et al., A novel linear gradient carbon fiber array integrated square honeycomb structure with electromagnetic wave absorption and enhanced mechanical performances, Compos. Struct., 305(2023), art. No. 116510. |
| [51] |
W.J. Wang, J.Y. Wen, X.W. Hou, et al., Enhanced microwave absorption of superlattice C–CuS/MXene composites with rich heterogeneous interfaces and conductive network synergies, Mater. Today Phys., 35(2023), art. No. 101108. |
| [52] |
|
| [53] |
X. Wang, L.Y. Zhang, E.J. Ding, X.H. Cao, C.Y. Luo, and L.Q. Huang, Seed-assisted in situ ZIF-8 growth on carbon nanofibers for enhanced microwave absorption, Carbon, 214(2023), art. No. 118316. |
| [54] |
H.R. Cheng, Y.M. Pan, W. Li, et al., Facile design of multifunctional melamine foam with Ni-anchored reduced graphene oxide/MXene as highly efficient microwave absorber, Nano Today, 52(2023), art. No. 101958. |
| [55] |
M. Chang, Z.R. Jia, S.Q. He, et al., Two-dimensional interface engineering of NiS/MoS2/Ti3C2Tx heterostructures for promoting electromagnetic wave absorption capability, Composites Part B, 225(2021), art. No. 109306. |
| [56] |
T.Q. Hou, Z.R. Jia, B.B. Wang, et al., MXene-based accordion 2D hybrid structure with Co9S8/C/Ti3C2Tx as efficient electromagnetic wave absorber, Chem. Eng. J., 414(2021), art. No. 128875. |
| [57] |
Y. Li, C.L. Dong, S.J. Wang, et al., Insight into lightweight MXene/polyimide aerogel with high-efficient microwave absorption, Mater. Today Phys., 42(2024), art. No. 101373. |
University of Science and Technology Beijing
/
| 〈 |
|
〉 |