Optimizing the overall performance of Cu-Ni-Si alloy via controlling nanometer-lamellar discontinuous precipitation structure
Jinyu Liang , Guoliang Xie , Feixiang Liu , Wenli Xue , Rui Wang , Xinhua Liu
International Journal of Minerals, Metallurgy, and Materials ›› 2025, Vol. 32 ›› Issue (4) : 915 -924.
Optimizing the overall performance of Cu-Ni-Si alloy via controlling nanometer-lamellar discontinuous precipitation structure
Simultaneously achieving high strength and high electrical conductivity in Cu-Ni-Si alloys pose a significant challenge, which greatly constrains its applications in the electronics industry. This paper offers a new pathway to improve properties, by preparation of nanometer lamellar discontinuous precipitates (DPs) arranged with the approximate same direction through a combination of deformation-aging and cold rolling process. The strengthening effect is primarily attributed to nanometer-lamellar DPs strengthening and dislocation strengthening mechanism. The accumulation of dislocations at the interface between nanometer lamellar DPs and matrix during cold deformation process can results in the decrease of dislocation density inside the matrix grains, leading to the acceptably slight reduction of electrical conductivity during cold rolling. The alloy exhibits an electrical conductivity of 45.32%IACS (international annealed copper standard, IACS), a tensile strength of 882.67 MPa, and a yield strength of 811.33 MPa by this method. This study can provide a guidance for the composition and microstructure design of a Cu-Ni-Si alloy in the future, by controlling the morphology and distribution of DPs.
Cu-Ni-Si alloys / discontinuous precipitates / nanometer-lamellar strengthening / dislocation strengthening
| [1] |
F.X. Liu, G.L. Xie, S.J. Wang, J. Yang, C.G. Chen, and X.H. Liu, Excellent combination of mechanical properties and electrical conductivity obtained by minute addition of alloying elements and nanometer scaled Al2O3 in copper alloy, Mater. Sci. Eng. A, 867(2023), art. No. 144689. |
| [2] |
|
| [3] |
C.S. Wang, H.D. Fu, H.T. Zhang, X.Q. He, and J.X. Xie, Simultaneous enhancement of mechanical and electrical properties of Cu-Ni-Si alloys via thermo-mechanical process, Mater. Sci. Eng. A, 838(2022), art. No. 142815. |
| [4] |
W.N. Liao, H.Q. Yang, C. Yi, and J.H. Zheng, Effect and mechanism of cold rolling and aging process on microstructure and properties of columnar grain C70250 copper alloy, Mater. Sci. Eng. A, 833(2022), art. No. 142577. |
| [5] |
|
| [6] |
|
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
|
| [11] |
K. Fukamachi and M. Kimura, Age-hardening structure and mechanism of Cu-3at%Ni-1.5at%Si Corson alloy, Mater. Sci. Eng. A, 831(2022), art. No. 142220. |
| [12] |
|
| [13] |
|
| [14] |
|
| [15] |
Q.R. Yang, Q. Liu, X.H. Liu, et al., Microstructure and mechanical properties of Cu-Ni-Si alloy plate produced by HCCM horizontal continuous casting, J. Alloy. Compd., 893(2022), art. No. 162302. |
| [16] |
K. Yang, Y.H. Wang, M.X. Guo, et al., Recent development of advanced precipitation-strengthened Cu alloys with high strength and conductivity: A review, Prog. Mater. Sci., 138(2023), art. No. 101141. |
| [17] |
W.N. Liao, H. Qiang, W.F. Song, Y.Y. Hu, and C.X. Zhang, Effect and mechanism of room temperature rolling, cryogenic rolling and heat treatment on mechanical properties and electrical conductivity of Cu-Ni-Si alloy with continuous directional solidification, J. Alloy. Compd., 949(2023), art. No. 169748. |
| [18] |
W.N. Liao, C.X. Zhang, H. Qiang, W.F. Song, and Y.Y. Hu, The comprehensive performance and strengthening mechanism of the columnar crystal Cu-Ni-Si alloy after two large deformation rates of cryogenic rolling-aging, J. Alloy. Compd., 936(2023), art. No. 168281. |
| [19] |
|
| [20] |
|
| [21] |
W. Wang, J. Wang, S.J. Li, et al., Effects of Nb addition on the properties and microstructure of Cu-Ni-Si-Mg alloy, Mater. Charact., 194(2022), art. No. 112451. |
| [22] |
|
| [23] |
M.F. Wang, S.F. Chen, S.W. Wang, M.X. Zhang, H.W. Song, and S.H. Zhang, Effects of La addition on microstructure evolution and thermal stability of Cu-2.35Ni-0.59Si sheet, Materials, 16(2023), No. 11, art. No. 4105. |
| [24] |
L. Jia, M.F. Yang, S.P. Tao, et al., Microstructure evolution and reaction behavior of Cu-Ni-Si powder system under solid-state sintering, Mater. Chem. Phys., 271(2021), art. No. 124942. |
| [25] |
|
| [26] |
M. Goto, T. Yamamoto, E.A. Choi, et al., Physical background of significant increase in mechanical properties and fatigue strength of groove-rolled Cu-Ni-Si alloy with discontinuous precipitates, J. Alloy. Compd., 947(2023), art. No. 169569. |
| [27] |
M. Goto, T. Yamamoto, S.Z. Han, et al., Simultaneous increase in electrical conductivity and fatigue strength of Cu-Ni-Si alloy by utilizing discontinuous precipitates, Mater. Lett., 288(2021), art. No. 129353. |
| [28] |
|
| [29] |
|
| [30] |
|
| [31] |
|
| [32] |
R.X. Wang, Y. Tang, S. Li, et al., Effect of lattice distortion on the diffusion behavior of high-entropy alloys, J. Alloy. Compd., 825(2020), art. No. 154099. |
| [33] |
Y.X. Geng, D. Zhang, J.S. Zhang, and L.Z. Zhuang, Early-stage clustering and precipitation behavior in the age-hardened Al-Mg-Zn (-Cu) alloys, Mater. Sci. Eng. A, 856(2022), art. No. 144015. |
| [34] |
K.S. Hu, C.M. Zou, H.W. Wang, and Z.J. Wei, Influence of Ti elements on the evolution of microstructure, mechanical properties and thermal stability of Al-Cu alloy, J. Alloy. Compd., 952(2023), art. No. 169860. |
| [35] |
S.Y. Wang, F.C. Lang, and Y.M. Xing, Geometric phase analysis for characterization of 3D morphology of carbon fiber reinforced composites, Compos. Sci. Technol., 242(2023), art. No. 110215. |
| [36] |
|
| [37] |
|
| [38] |
H.C. Feng, L.F. Wang, S.Y. Cui, N. Hansen, F. Fang, and X.D. Zhang, Microstructure and strengthening mechanisms of nanolamellar structures in ultrastrong drawn iron wires, Scripta Mater., 200(2021), art. No. 113906. |
| [39] |
|
| [40] |
X.H. Meng, G.L. Xie, W.L. Xue, Y.L. Fu, R. Wang, and X.H. Liu, The precipitation behavior of a Cu-Ni-Si alloy with Cr addition prepared by heating-cooling combined mold (HCCM) continuous casting, Materials, 15(2022), No. 13, art. No. 4521. |
| [41] |
|
| [42] |
R. Zhang, Z. Li, X.F. Sheng, Y. Gao, and Q. Lei, Grain refinement and mechanical properties improvements in a high strength Cu-Ni-Si alloy during multidirectional forging, Fusion Eng. Des., 159(2020), art. No. 111766. |
| [43] |
J. Li, G.J. Huang, X.J. Mi, L.J. Peng, H.F. Xie, and Y.L. Kang, Effect of Ni/Si mass ratio and thermomechanical treatment on the microstructure and properties of Cu-Ni-Si alloys, Materials, 12(2019), No. 13, art. No. 2076. |
| [44] |
|
University of Science and Technology Beijing
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