Unraveling the significance of cobalt on transformation kinetics, crystallography and impact toughness in high-strength steels

Yishuang Yu , Jingxiao Zhao , Xuelin Wang , Hui Guo , Zhenjia Xie , Chengjia Shang

International Journal of Minerals, Metallurgy, and Materials ›› 2025, Vol. 32 ›› Issue (2) : 380 -390.

PDF
International Journal of Minerals, Metallurgy, and Materials ›› 2025, Vol. 32 ›› Issue (2) :380 -390. DOI: 10.1007/s12613-024-2935-3
Research Article
research-article
Unraveling the significance of cobalt on transformation kinetics, crystallography and impact toughness in high-strength steels
Author information +
History +
PDF

Abstract

This work reveals the significant effects of cobalt (Co) on the microstructure and impact toughness of as-quenched high-strength steels by experimental characterizations and thermo-kinetic analyses. The results show that the Co-bearing steel exhibits finer blocks and a lower ductile–brittle transition temperature than the steel without Co. Moreover, the Co-bearing steel reveals higher transformation rates at the intermediate stage with bainite volume fraction ranging from around 0.1 to 0.6. The improved impact toughness of the Co-bearing steel results from the higher dense block boundaries dominated by the V1/V2 variant pair. Furthermore, the addition of Co induces a larger transformation driving force and a lower bainite start temperature (BS), thereby contributing to the refinement of blocks and the increase of the V1/V2 variant pair. These findings would be instructive for the composition, microstructure design, and property optimization of high-strength steels.

Keywords

high-strength steel / cobalt / transformation kinetics / crystallography / impact toughness

Cite this article

Download citation ▾
Yishuang Yu, Jingxiao Zhao, Xuelin Wang, Hui Guo, Zhenjia Xie, Chengjia Shang. Unraveling the significance of cobalt on transformation kinetics, crystallography and impact toughness in high-strength steels. International Journal of Minerals, Metallurgy, and Materials, 2025, 32(2): 380-390 DOI:10.1007/s12613-024-2935-3

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Garcia CI. Rana R, Singh SB. High strength low alloyed (HSLA) steels. Automotive Steels: Design, Metallurgy, Processing and Applications. 2017, Duxford, Woodhead Publishing: 145

[2]

G. Krauss, Tempering of lath martensite in low and medium carbon steels: Assessment and challenges, Steel Res. Int., 88(2017), No. 10, art. No. 1700038.

[3]

Han P, Liu ZP, Xie ZJ, et al. . Influence of band microstructure on carbide precipitation behavior and toughness of 1 GPa-grade ultra-heavy gauge low-alloy steel. Int. J. Miner. Metall. Mater.. 2023, 30(7): 1329

[4]

Krauss G. Steels: Processing, Structure, and Performance. 20152nd ed.Materials Park, Ohio, ASM International

[5]

G. Huang, X.L. Wan, K.M. Wu, H.Z. Zhao, and R.D.K. Misra, Effects of small Ni addition on the microstructure and toughness of coarse-grained heat-affected zone of high-strength low-alloy steel, Metals, 8(2018), No. 9, art. No. 718.

[6]

Wang ZQ, Wang XL, Nan YR, et al. . Effect of Ni content on the microstructure and mechanical properties of weld metal with both-side submerged arc welding technique. Mater. Charact.. 2018, 138: 67

[7]

Wang XL, Ma XP, Wang ZQ, et al. . Carbon microalloying effect of base material on variant selection in coarse grained heat affected zone of X80 pipeline steel. Mater. Charact.. 2019, 149: 26

[8]

M.Y. Sun, Z.Q. Wang, X.M. Wang, and R.D.K. Misra, The significance of variant pairing in governing toughness of coarsegrained heat affected zone (CGHAZ) in Nb-bearing high strength structural steels, Mater. Lett., 260(2020), art. No. 126974.

[9]

Liu XQ, Zhou SS, Liu ZL, Hou ZG, Tian QC. Effect of 0.1 wt.% Co on the hot deformation and toughness of finegrained low-carbon steel at sub-zero temperatures. J. Mater. Eng. Perform.. 2018, 27(1): 155

[10]

Davis JR. Metals Handbook Desk Edition. 19982nd ed.Materials Park, Ohio, ASM International

[11]

Yu YS, Wang ZQ, Wu BB, et al. . Tailoring variant pairing to enhance impact toughness in high-strength low-alloy steels via trace carbon addition. Acta Metall. Sin. Engl. Lett.. 2021, 34(6): 755

[12]

X.L. Wang, Z.J. Xie, W.J. Su, and C.J. Shang, Role of carbon content on microstructure evolution and impact toughness in coarse-grained heat-affected zone of high-strength steel, Metals, 13(2023), No. 1, art. No. 106.

[13]

S. Huang, Y.S. Yu, Z.Q. Wang, et al., Crystallographic insights into the role of nickel on hardenability of wear-resistant steels, Mater. Lett., 306(2022), art. No. 130961.

[14]

Z.P. Liu, Y.S. Yu, J. Yang, Z.Q. Wang, H. Guo, and C.J. Shang, Morphology and crystallography analyses of HSLA steels with hardenability enhanced by tailored C–Ni collocation, Metals, 12(2022), No. 1, art. No. 32.

[15]

J. Hu, X.Y. Li, Q.W. Meng, L.Y. Wang, Y.Z. Li, and W. Xu, Tailoring retained austenite and mechanical property improvement in Al–Si–V containing medium Mn steel via direct inter-critical rolling, Mater. Sci. Eng. A, 855(2022), art. No. 143904.

[16]

Wang SZ, Gao ZJ, Wu GL, Mao XP. Titanium microalloying of steel: A review of its effects on processing, microstructure and mechanical properties. Int. J. Miner. Metall. Mater.. 2022, 29(4): 645

[17]

Garcia-Mateo C, Caballero FG, Bhadeshia HKDH. Acceleration of low-temperature bainite. ISIJ Int.. 2003, 43(11): 1821

[18]

Samanta S, Das S, Chakrabarti D, Samajdar I, Singh SB, Haldar A. Development of multiphase microstructure with bainite, martensite, and retained austenite in a Co-containing steel through quenching and partitioning (Q&P) treatment. Metall. Mater. Trans. A. 2013, 44(13): 5653

[19]

L.L. Feng, F. Hu, W. Zhou, et al., Influences of alloying elements on continuous cooling phase transformation and microstructures of extremely fine pearlite, Metals, 9(2019), No. 1, art. No. 70.

[20]

General Administration of Quality Supervision, InspectionQuarantine of the People’s Republic of ChinaStandardization Administration of the People’s Republic of ChinaGB/T 228.1-2021. Metallic Materials – Tensile Testing – Part I: Method of Test at Room Temperature. 2021

[21]

General Administration of Quality Supervision, InspectionQuarantine of the People’s Republic of ChinaStandardization Administration of the People’s Republic of ChinaGB/T 229-2020. Metallic Materials – Charpy Pendulum Impact Test Method. 2020

[22]

General Administration of Quality Supervision, InspectionQuarantine of the People’s Republic of ChinaStandardization Administration of the People’s Republic of ChinaGB/T 6394-2017. Determination of Estimating the Average Grain Size of Metal. 2017

[23]

W. Rasband, ImageJ. https://imagej.net/.

[24]

Li XC, Zhao JX, Cong JH, et al. . Machine learning guided automatic recognition of crystal boundaries in bainitic/martensitic alloy and relationship between boundary types and ductile-to-brittle transition behavior. J. Mater. Sci. Technol.. 2021, 84: 49

[25]

C. Celada-Casero, J. Sietsma, and M.J. Santofimia, The role of the austenite grain size in the martensitic transformation in low carbon steels, Mater. Des., 167(2019), art. No. 107625.

[26]

Morito S, Saito H, Ogawa T, Furuhara T, Maki T. Effect of austenite grain size on the morphology and crystallography of lath martensite in low carbon steels. ISIJ Int.. 2005, 45(1): 91

[27]

Lee SJ, Park JS, Lee YK. Effect of austenite grain size on the transformation kinetics of upper and lower bainite in a low-alloy steel. Scripta Mater.. 2008, 59(1): 87

[28]

Morito S, Tanaka H, Konishi R, Furuhara T, Maki T. The morphology and crystallography of lath martensite in Fe–C alloys. Acta Mater.. 2003, 51(6): 1789

[29]

Morito S, Huang X, Furuhara T, Maki T, Hansen N. The morphology and crystallography of lath martensite in alloy steels. Acta Mater.. 2006, 54(19): 5323

[30]

Chatterjee A, Chakrabarti D, Moitra A, Mitra R, Bhaduri AK. Effect of deformation temperature on the ductile–brittle transition behavior of a modified 9Cr–1Mo steel. Mater. Sci. Eng. A. 2015, 630: 58

[31]

Wang XL, Wang ZQ, Dong LL, Shang CJ, Ma XP, Subramanian SV. New insights into the mechanism of cooling rate on the impact toughness of coarse grained heat affected zone from the aspect of variant selection. Mater. Sci. Eng. A. 2017, 704: 448

[32]

Luo HW, Wang XH, Liu ZB, Yang ZY. Influence of refined hierarchical martensitic microstructures on yield strength and impact toughness of ultra-high strength stainless steel. J. Mater. Sci. Technol.. 2020, 51: 130

[33]

van Bohemen SMC. Bainite and martensite start temperature calculated with exponential carbon dependence. Mater. Sci. Technol.. 2012, 28(4): 487

[34]

C. Garcia-Mateo, G. Paul, M.C. Somani, et al., Transferring nanoscale bainite concept to lower C contents: A perspective, Metals, 7(2017), No. 5, art. No. 159.

[35]

Zheng YF, Wu RM, Li XC, Wu XC. Continuous cooling transformation behaviour and bainite formation kinetics of new bainitic steel. Mater. Sci. Technol.. 2017, 33(4): 454

[36]

Bhadeshia H, Honeycombe R. Steels: Microstructure and Properties. 20174th ed.Oxford, Butterworth-Heinemann

[37]

Aaronson HI, Enomoto M, Lee JK. Mechanisms of Diffusional Phase Transformations in Metals and Alloys. 2010, Boca Raton, CRC Press

[38]

Stormvinter A, Miyamoto G, Furuhara T, Hedström P, Borgenstam A. Effect of carbon content on variant pairing of martensite in Fe–C alloys. Acta Mater.. 2012, 60(20): 7265

[39]

Takayama N, Miyamoto G, Furuhara T. Effects of transformation temperature on variant pairing of bainitic ferrite in low carbon steel. Acta Mater.. 2012, 60(5): 2387

[40]

H. Yu, Y.S. Yu, Z.Q. Wang, F. Li, B. Hu, and S.L. Liu, On the variant pairing in transformation product of high strength low alloy steel depending on cooling rate, Mater. Lett., 326(2022), art. No. 132953.

[41]

Ståhlkrantz A, Hedström P, Sarius N, Borgenstam A. Effect of carbon content on variant pairing in bainitic low alloy steel. Metall. Mater. Trans. A. 2022, 53(9): 3418

[42]

T.W. Yin, Y.F. Shen, N. Jia, Y.J. Li, and W.Y. Xue, Controllable selection of martensitic variant enables concurrent enhancement of strength and ductility in a low-carbon steel, Int. J. Plast., 168(2023), art. No. 103704.

[43]

Z. Gao, X.M. Dong, J.R. Yu, et al., Unraveling the mechanism of toughness fluctuation in ultra-high-strength casing from the perspective of crystallography, Metals, 14(2024), No. 2, art. No. 208.

[44]

Kawata H, Sakamoto K, Moritani T, Morito S, Furuhara T, Maki T. Crystallography of ausformed upper bainite structure in Fe–9Ni–C alloys. Mater. Sci. Eng. A. 2006, 438–440: 140

[45]

X.L. Wang, Z.J. Xie, Z.Q. Wang, Y.S. Yu, L.Q. Wu, and C.J. Shang, Crystallographic study on microstructure and impact toughness of coarse grained heat affected zone of ultra-high strength steel, Mater. Lett., 323(2022), art. No. 132552.

[46]

Chen QY, Zhang WN, Wang PJ, Mao QJ, Liu ZY. Crystallography of transformation products with different cooling rates in low-carbon alloy steel and its effect on low-temperature toughness uniformity of heavy plates. J. Mater. Res. Technol.. 2024, 28: 2077

[47]

Furuhara T, Kawata H, Morito S, Maki T. Crystallography of upper bainite in Fe–Ni–C alloys. Mater. Sci. Eng. A. 2006, 431(1–2): 228

[48]

Filippov SA, Zolotorevsky NY. Orientation relationship and variant pairing in bainite of low carbon steels depending on thermomechanical treatment. Mater. Lett.. 2018, 214: 130

[49]

Lambert-Perlade A, Gourgues AF, Pineau A. Austenite to bainite phase transformation in the heat-affected zone of a high strength low alloy steel. Acta Mater.. 2004, 52(8): 2337

[50]

Huang S, Wu BB, Wang ZQ, et al. . EBSD study on the significance of carbon content on hardenability. Mater. Lett.. 2019, 254: 412

[51]

Wu BB, Wang ZQ, Yu YS, Wang XL, Shang CJ, Misra RDK. Thermodynamic basis of twin-related variant pair in high strength low alloy steel. Scripta Mater.. 2019, 170: 43

[52]

Y.S. Yu, Z.Q. Wang, B.B. Wu, et al., New insight into the hardenability of high strength low alloy steel from the perspective of crystallography, Mater. Lett., 292(2021), art. No. 129624.

[53]

Gourgues AF. Electron backscatter diffraction and cracking. Mater. Sci. Technol.. 2002, 18(2): 119

[54]

Zhao Y, Tong X, Wei XH, et al. . Effects of microstructure on crack resistance and low-temperature toughness of ultra-low carbon high strength steel. Int. J. Plast.. 2019, 116: 203

[55]

Fan ED, Li Y, You Y, XW. Effect of crystallographic orientation on crack growth behaviour of HSLA steel. Int. J. Miner. Metall. Mater.. 2022, 29(8): 1532

[56]

Morris JW, Lee CS, Guo Z. The nature and consequences of coherent transformations in steel. ISIJ Int.. 2003, 43(3): 410

RIGHTS & PERMISSIONS

University of Science and Technology Beijing

PDF

2

Accesses

0

Citation

Detail

Sections
Recommended

/