Flotation separation depressants for scheelite and calcium-bearing minerals: A review
Ziming Wang , Bo Feng , Yuangan Chen
International Journal of Minerals, Metallurgy, and Materials ›› 2023, Vol. 30 ›› Issue (9) : 1621 -1632.
Flotation separation depressants for scheelite and calcium-bearing minerals: A review
Owing to the depletion of wolframite, the focus of tungsten extraction has gradually shifted to scheelite. However, separating the associated minerals (e.g., apatite, fluorite, and calcite) and scheelite is challenging because their surface physicochemical properties are similar to those of scheelite. Fortunately, researchers have made substantial progress in separating the minerals of scheelite by using depressants. This study reviews the application and inhibition mechanism of inorganic depressants in obtaining tungsten from its calcium-bearing minerals. The application of new organic depressants in obtaining tungsten from its calcium-bearing minerals and the associated mechanisms are also summarized. After an objective assessment of inorganic and organic depressants’ advantages and disadvantages, possible future research directions for inorganic and organic depressants are proposed. Herein, we provide a theoretical basis for developing scheelite flotation depressants.
scheelite / calcium-bearing minerals / flotation / depressant
| [1] |
|
| [2] |
J.Z. Kuang, Z.L. Zou, Z.Y. Huang, P.F. Liu, W.Q. Yuan, and L.P. Zhu, Surface dissolution of scheelite under different regulators and its effect on flotation behavior, Miner. Eng., 164(2021), art. No. 106811. |
| [3] |
C. Liu, C.Q. Ni, J.X. Yao, et al., Hydroxypropyl amine surfactant: A novel flotation collector for efficient separation of scheelite from calcite, Miner. Eng., 167(2021), art. No. 106898. |
| [4] |
Z.Q. Huang, S.Y. Shuai, V.E. Burov, et al., Application of a new amidoxime surfactant in flotation separation of scheelite and calcite: Adsorption mechanism and DFT calculation, J. Mol. Liq, 364(2022), art. No. 120036. |
| [5] |
|
| [6] |
Y. Foucaud, R.L.S. Canevesi, A. Celzard, V. Fierro, and M. Badawi, Hydration mechanisms of scheelite from adsorption isotherms and ab initio molecular dynamics simulations, Appl. Surf. Sci., 562(2021), art. No. 150137. |
| [7] |
|
| [8] |
L.Y. Dong, Q. Wei, W.Q. Qin, and F. Jiao, Effect of iron ions as assistant depressant of citric acid on the flotation separation of scheelite from calcite, Chem. Eng. Sci., 241(2021), art. No. 116720. |
| [9] |
H.S. Han, Y. Xiao, Y.H. Hu, et al., Replacing Petrov’s process with atmospheric flotation using Pb-BHA complexes for separating scheelite from fluorite, Miner. Eng., 145(2020), art. No. 106053. |
| [10] |
J.J. Wang, Z.Y. Gao, and W. Sun, Desorption and reuse of Pb-BHA-NaOL collector in scheelite flotation, Minerals, 13(2023), No. 4, art. No. 538. |
| [11] |
|
| [12] |
|
| [13] |
|
| [14] |
D.P. Patil and U.B. Nayak, Selective flotation of scheelite and calcite, [in] Proceeedings of National Seminar on Mineral Processing and IX Annual Technical Convention of Indian Institute of Mineral Engineers, Jamshedpur, 1985. |
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
|
| [19] |
|
| [20] |
|
| [21] |
|
| [22] |
|
| [23] |
|
| [24] |
|
| [25] |
|
| [26] |
X. Wang, Q. Song, R.Q. Xie, J. Liu, and Y.M. Zhu, Selective flotation separation of scheelite from apatite by application of ATMP as an efficient depressant, J. Mol. Liq., 378(2023), art. No. 121604. |
| [27] |
|
| [28] |
|
| [29] |
W. Yao, M.L. Li, M. Zhang, R. Cui, J. Shi, and J.F. Ning, Effects of Pb2+ ions on the flotation behavior of scheelite, calcite, and fluorite in the presence of water glass, Colloids Surf. A, 632(2022), art. No. 127826. |
| [30] |
|
| [31] |
|
| [32] |
|
| [33] |
|
| [34] |
|
| [35] |
|
| [36] |
|
| [37] |
N. Kupka, B. Babel, and M. Rudolph, The potential role of colloidal silica as a depressant in scheelite flotation, Minerals, 10(2020), No. 2, art. No. 144. |
| [38] |
|
| [39] |
|
| [40] |
|
| [41] |
|
| [42] |
|
| [43] |
Z.H. Guan, K.W. Lu, Y. Zhang, H. Yang, and X.K. Li, Study of the effect of manganese ion addition points on the separation of scheelite and calcite by sodium silicate, Materials (Basel), 15(2022), No. 13, art. No. 4699. |
| [44] |
|
| [45] |
|
| [46] |
|
| [47] |
|
| [48] |
|
| [49] |
G.F. Zhang, H. Deng, K.S. Wei, and Q. Shi, The effect of acidized sodium silicate on flotation separation of fluorite and calcite, Nonferrous Met. Miner. Process. Sect., 2014, No. 1, p. 80. |
| [50] |
|
| [51] |
J.H. Kang, Y.H. Hu, W. Sun, Z.Y. Gao, and R.Q. Liu, Utilization of sodium hexametaphosphate for separating scheelite from calcite and fluorite using an anionic–nonionic collector, Minerals, 9(2019), No. 11, art. No. 705. |
| [52] |
W.L. Zhu, L.Y. Dong, F. Jiao, W.Q. Qin, and Q. Wei, Use of sodium hexametaphosphate and citric acid mixture as depressant in the flotation separation of scheelite from calcite, Minerals, 9(2019), No. 9, art. No. 560. |
| [53] |
X. Wang, W.H. Jia, C.R. Yang, et al., Innovative application of sodium tripolyphosphate for the flotation separation of scheelite from calcite, Miner. Eng., 170(2021), art. No. 106981. |
| [54] |
|
| [55] |
|
| [56] |
|
| [57] |
H.Q. Zhang, F. Zhou, H. Yu, and M.X. Liu, Double roles of sodium hexametaphosphate in the flotation of dolomite from apatite, Colloids Surf. A, 626(2021), art. No. 127080. |
| [58] |
|
| [59] |
|
| [60] |
|
| [61] |
W. Yao, M.L. Li, M. Zhang, R. Cui, J. Shi, and J.F. Ning, Effect of Zn2+ and its addition sequence on flotation separation of scheelite from calcite using water glass, Colloids Surf. A, 588(2020), art. No. 124394. |
| [62] |
|
| [63] |
|
| [64] |
|
| [65] |
X.Y. Yu, R.R. Zhang, S.Y. Yang, et al., A novel decanedioic hydroxamic acid collector for the flotation separation of bastnäsite from calcite, Miner. Eng., 151(2020), art. No. 106306. |
| [66] |
X.Y. Zhu, Y. Huang, Y.G. Zhu, N. Sun, and W.Q. Wang, Investigating the performance of oxalic acid for separating bast-naesite from calcium-bearing gangue minerals based on experiment and theoretical calculation, Miner. Eng., 170(2021), art. No. 107047. |
| [67] |
|
| [68] |
|
| [69] |
|
| [70] |
L.Y. Dong, L.D. Qiao, Q.F. Zheng, et al., Enhanced adsorption of citric acid at the calcite surface by adding copper ions: Flotation separation of scheelite from calcite, Colloids Surf. A, 663(2023), art. No. 131036. |
| [71] |
|
| [72] |
L.Y. Dong, F. Jiao, W.Q. Qin, and Q. Wei, New insights into the depressive mechanism of citric acid in the selective flotation of scheelite from fluorite, Miner. Eng., 171(2021), art. No. 107117. |
| [73] |
|
| [74] |
J.H. Fu, H.S. Han, Z. Wei, et al., Selective separation of scheelite from calcite using tartaric acid and Pb–BHA complexes, Colloids Surf. A, 622(2021), art. No. 126657. |
| [75] |
L.Y. Dong, F. Jiao, W.Q. Qin, and Q. Wei, Utilization of iron ions to improve the depressive efficiency of tartaric acid on the flotation separation of scheelite from calcite, Miner. Eng., 168(2021), art. No. 106925. |
| [76] |
|
| [77] |
Y.P. Qian, X.A. Qiu, T.W. Shen, Y.Y. Huai, B. Chen, and Z. Wang, Effect of calcium ion on the flotation of fluorite and calcite using sodium oleate as collector and tannic acid as depressant, Minerals, 12(2022), No. 8, art. No. 996. |
| [78] |
M. Fraga-Corral, P. García-Oliveira, A.G. Pereira, et al., Technological application of tannin-based extracts, Molecules, 25(2020), No. 3, art. No. 614. |
| [79] |
|
| [80] |
|
| [81] |
|
| [82] |
S.Y. Yang, Y.L. Xu, C. Liu, L.Y. Huang, Z.Q. Huang, and H.Q. Li, The anionic flotation of fluorite from barite using gelatinized starch as the depressant, Colloids Surf. A, 597(2020), art. No. 124794. |
| [83] |
W.X. Zhu, J.H. Pan, X.Y. Yu, et al., The flotation separation of fluorite from calcite using hydroxypropyl starch as a depressant, Colloids Surf. A: Physicochem. Eng. Aspects, 616(2021), art. No. 126168. |
| [84] |
Y.G. Chen, B. Feng, H.S. Yan, et al., Adsorption and depression mechanism of an eco-friendly depressant dextrin onto fluorite and calcite for the efficiency flotation separation, Colloids Surf. A, 635(2022), art. No. 127987. |
| [85] |
R.F. Sun, D. Liu, X.S. Tian, Q. Zuo, D.Q. Wang, and S.M. Wen, The role of copper ion and soluble starch used as a combined depressant in the flotation separation of fluorite from calcite: New insights on the application of modified starch in mineral processing, Miner. Eng., 181(2022), art. No. 107550. |
| [86] |
|
| [87] |
|
| [88] |
|
| [89] |
|
| [90] |
|
| [91] |
|
| [92] |
C.H. Zhong, H.H. Wang, B. Feng, L.Z. Zhang, Y.G. Chen, and Z.Y. Gao, Flotation separation of scheelite and apatite by polysaccharide depressant xanthan gum, Miner. Eng., 170(2021), art. No. 107045. |
| [93] |
|
| [94] |
|
| [95] |
M.T. Wang, G.H. Huang, G.F. Zhang, Y.F. Chen, D.Z. Liu, and C.B. Li, Selective flotation separation of fluorite from calcite by application of flaxseed gum as depressant, Miner. Eng., 168(2021), art. No. 106938. |
| [96] |
Y.J. Luo, G.F. Zhang, C.B. Li, et al., Flotation separation of smithsonite from calcite using a new depressant fenugreek gum, Colloids Surf. A, 582(2019), art. No. 123794. |
| [97] |
Q. Wei, L.Y. Dong, F. Jiao, and W.Q. Qin, Selective flotation separation of fluorite from calcite by using sesbania gum as depressant, Miner. Eng., 174(2021), art. No. 107239. |
| [98] |
H.P. Zhou, Z.Z. Yang, Y.B. Zhang, F.X. Xie, and X.P. Luo, Flotation separation of smithsonite from calcite by using flaxseed gum as depressant, Miner. Eng., 167(2021), art. No. 106904. |
| [99] |
H.P. Zhou, Z.Z. Yang, X.K. Tang, W. Sun, Z.Y. Gao, and X.P. Luo, Enhancing flotation separation effect of fluorite and calcite with polysaccharide depressant tamarind seed gum, Colloids Surf. A, 624(2021), art. No. 126784. |
| [100] |
H.P. Zhou, Y.B. Zhang, X.K. Tang, Y.J. Cao, and X.P. Luo, Flotation separation of fluorite from calcite by using psyllium seed gum as depressant, Miner. Eng., 159(2020), art. No. 106514. |
| [101] |
Z.J. Wang, H.Q. Wu, J. Yang, et al., Selective flotation separation of bastnaesite from calcite using xanthan gum as a depressant, Appl. Surf. Sci., 512(2020), art. No. 145714. |
| [102] |
C.H. Zhong, B. Feng, L.Z. Zhang, W.P. Zhang, H.H. Wang, and Z.Y. Gao, Flotation separation of apatite and calcite using gum arabic as a depressant, Colloids Surf. A, 632(2022), art. No. 127723. |
| [103] |
|
| [104] |
|
| [105] |
X. Wang, F. Jiao, W.Q. Qin, et al., Sulfonated brown coal: A novel depressant for the selective flotation of scheelite from calcite, Colloids Surf. A, 602(2020), art. No. 125006. |
| [106] |
|
| [107] |
|
| [108] |
Z.Y. Gao, C. Wang, W. Sun, Y.S. Gao, and P.B. Kowalczuk, Froth flotation of fluorite: A review, Adv. Colloid Interface Sci., 290(2021), art. No. 102382. |
| [109] |
|
| [110] |
|
| [111] |
L.Y. Dong, Q. Wei, W.Q. Qin, and F. Jiao, Selective adsorption of sodium polyacrylate on calcite surface: Implications for flotation separation of apatite from calcite, Sep. Purif. Technol., 241(2020), art. No. 116415. |
| [112] |
Y. Zhang, Y.Y. Li, R. Chen, Y.H. Wang, J.S. Deng, and X.M. Luo, Flotation separation of scheelite from fluorite using sodium polyacrylate as inhibitor, Minerals, 7(2017), No. 6, art. No. 102. |
| [113] |
J. Liu, X. Wang, Y.M. Zhu, and Y.X. Han, Flotation separation of scheelite from fluorite by using DTPA as a depressant, Miner. Eng., 175(2022), art. No. 107311. |
/
| 〈 |
|
〉 |