Development of calcium coke for CaC2 production using calcium carbide slag and coking coal

Xu-zhong Gong , Jun-qiang Zhang , Zhi Wang , Dong Wang , Jun-hao Liu , Xiao-dong Jing , Guo-yu Qian , Chuan Wang

International Journal of Minerals, Metallurgy, and Materials ›› 2021, Vol. 28 ›› Issue (1) : 76 -87.

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International Journal of Minerals, Metallurgy, and Materials ›› 2021, Vol. 28 ›› Issue (1) : 76 -87. DOI: 10.1007/s12613-020-2049-5
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Development of calcium coke for CaC2 production using calcium carbide slag and coking coal

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Abstract

A type of calcium coke was developed for use in the oxy-thermal process of calcium carbide production. The calcium coke was prepared by the co-pyrolysis of coking coal and calcium carbide slag, which is a solid waste generated from the chlor-alkali industry. The characteristics of the calcium cokes under different conditions were analyzed experimentally and theoretically. The results show that the thermal strength of calcium coke increased with the increase in the coking coal proportion, and the waterproof property of calcium coke also increased with increased carbonation time. The calcium coke can increase the contact area of calcium and carbon in the calcium carbide production process. Furthermore, the pore structure of the calcium coke can enhance the diffusion of gas inside the furnace, thus improving the efficiency of the oxy-thermal technology.

Keywords

calcium carbide slag / calcium carbide production / calcium coke / thermal strength / waterproof property

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Xu-zhong Gong, Jun-qiang Zhang, Zhi Wang, Dong Wang, Jun-hao Liu, Xiao-dong Jing, Guo-yu Qian, Chuan Wang. Development of calcium coke for CaC2 production using calcium carbide slag and coking coal. International Journal of Minerals, Metallurgy, and Materials, 2021, 28(1): 76-87 DOI:10.1007/s12613-020-2049-5

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