PDF
Abstract
Froth flotation is the most effective industrial method used to separate fine-grained minerals. The main problem of complex ore flotation is the negative effect of interactions among minerals in slurry, leading to variation in surface properties during separation. In this review, studies on the interactive effect among minerals on the flotation of iron ores, magnesite ores, and scheelite ores are summarized, and the main problems and mechanisms that diminish the separation efficiency of minerals are revealed in detail. Recent research progress on the flotation of these ores has confirmed that mineral aggregation, coating, and dissolution, as well as other factors caused by interacting behavior, explain the depressing effects of fine particles on mineral separation. Solvable methods for these effects are further discussed. Novel flotation processes and more selective reagents are critical for further investigations on various approaches to improve the beneficiation efficiency of these ores. This review aims to provide a good reference for conducting studies related to complex ore flotation.
Keywords
interactive effect
/
flotation
/
iron ores
/
magnesite ores
/
scheelite ores
Cite this article
Download citation ▾
Wan-zhong Yin, Yuan Tang.
Interactive effect of minerals on complex ore flotation: A brief review.
International Journal of Minerals, Metallurgy, and Materials, 2020, 27(5): 571-583 DOI:10.1007/s12613-020-1999-y
| [1] |
Ndlovu S. Biohydrometallurgy for sustainable development in the African minerals industry. Hydrometallurgy, 2008, 91(1–4): 20.
|
| [2] |
Chen RH, Lin Y, Tseng ML. Multicriteria analysis of sustainable development indicators in the construction minerals industry in China. Resour. Policy, 2015, 46(Part1): 123.
|
| [3] |
Lin QQ, Gu GH, Wang H, Liu YC, Fu JG, Wang CQ. Flotation mechanisms of molybdenite fines by neutral oils. Int. J. Miner. Metall. Mater., 2018, 25(1): 1.
|
| [4] |
Harris C T. The Selective Sulphation and Physical Upgrading of Nickel From a Nickeliferous Lateritic Ore, 2012, Ontario, Queen’s University, 3.
|
| [5] |
Hernáinz F, Calero M, Blázquez G. Flotation of low-grade phosphate ore. Adv. Powder Technol., 2004, 15(4): 421.
|
| [6] |
Veasey TJ, Wills BA. Review of methods of improving mineral liberation. Miner. Eng., 1991, 4, 747.
|
| [7] |
Sbárbaro D, del Villar R. Advanced Control and Supervision of Mineral Processing Plants, 2010, London, Springer, 4.
|
| [8] |
He DS, Chen Y, Xiang P, Yu ZJ, Potgieter JH. Study on the pre-treatment of oxidized zinc ore prior to flotation. Int. J. Miner. Metall. Mater., 2018, 25(2): 117.
|
| [9] |
Quast K. Literature review on the use of natural products in the flotation of iron oxide ores. Miner. Eng., 2017, 108, 12.
|
| [10] |
Wang L, Peng Y, Runge K, Bradshaw D. A review of entrainment: Mechanisms, contributing factors and modelling in flotation. Miner. Eng., 2015, 70, 77.
|
| [11] |
Botero AEC, Torem ML, Souza de Mesquita LM. Fundamental studies of Rhodococcus opacus as a biocollector of calcite and magnesite. Miner. Eng., 2007, 20(10): 1026.
|
| [12] |
Grano S. The critical importance of the grinding environment on fine particle recovery in flotation. Miner. Eng., 2009, 22(4): 386.
|
| [13] |
Forbes E. Shear selective and temperature responsive flocculation: A comparison of fine particle flotation techniques. Int. J. Miner. Process., 2011, 99(1–4): 1.
|
| [14] |
Ng WS, Sonsie R, Forbes E, Franks GV. Flocculation/flotation of hematite fines with anionic temperature-responsive polymer acting as a selective flocculant and collector. Miner. Eng., 2015, 77, 64.
|
| [15] |
Song SX, Lu SC. Hydrophobic flocculation of fine hematite, siderite, and rhodochrosite particles in aqueous solution. J. Colloid Interface Sci., 1994, 166(1): 35.
|
| [16] |
Sivamohan R. The problem of recovering very fine particles in mineral processing—A review. Int. J. Miner. Process., 1990, 28, 247.
|
| [17] |
Lu SC, Ding YQ, Guo JY. Kinetics of fine particle aggregation in turbulence. Adv. Colloid Interface Sci., 1998, 78(3): 197.
|
| [18] |
Yin WZ, Tang Y, Yao J, Luo XM, Wang JZ. Interactive effects in mineral flotation process. Conserv. Util. Miner. Resour., 2018, 3, 55.
|
| [19] |
Luo XM, Yin WZ, Wang YF, Sun CY, Ma YQ, Liu J. Effect and mechanism of siderite on reverse anionic flotation of quartz from hematite. J. Cent. South Univ., 2016, 23(1): 52.
|
| [20] |
Ateşok G, Boylu F, Çelĭk MS. Carrier flotation for desulfurization and deashing of difficult-to-float coals. Miner. Eng., 2001, 14(6): 661.
|
| [21] |
W.B. Hu, D.Z. Wang, and H.A. Jin, Flotation of wolframite slime-practice and technological innovation, [in] Proceedings of XIV International Mineral Processing Congress, Toronto, 1982, p. 5.
|
| [22] |
W.B. Hu, D.Z. Wang, and G.Z. Qiu, Autogenous carrier flotation, [in] K.S. Eric Forssberg, ed., Proceedings of XVI International Mineral Processing Congress, Stockholm, 1988, p. 445.
|
| [23] |
Luo N, Wei DZ, Shen YB, Han C, Zhang CE. Elimination of the adverse effect of calcium ion on the flotation separation of magnesite from dolomite. Minerals, 2017, 7(8): 150.
|
| [24] |
Luo XM, Ma MZ, Sun CY, Yin WZ, Zhang Y, Song SX. Interaction forms among minerals in iron ore flotation system. J. China Univ. Min. Technol., 2018, 47(3): 645.
|
| [25] |
Sivamohan R, Forssberg E. Recovery of heavy minerals from slimes. Int. J. Miner. Process., 1985, 15(4): 297.
|
| [26] |
Miettinen T, Ralston J, Fornasiero D. The limits of fine particle flotation. Miner. Eng., 2010, 23(5): 420.
|
| [27] |
Peleka EN, Gallios GP, Matis KA. A perspective on flotation: A review. J. Chem. Technol. Biotechnol., 2018, 93(3): 615.
|
| [28] |
Subrahmanyam TV, Eric Forssberg KS. Fine particles processing: Shear-flocculation and carrier flotation—A review. Int. J. Miner. Process., 1990, 30(3–4): 265.
|
| [29] |
Chen W, Feng QM, Zhang GF, Li LF, Jin SZ. Effect of energy input on flocculation process and flotation performance of fine scheelite using sodium oleate. Miner. Eng., 2017, 112, 27.
|
| [30] |
Rulyov NN. Combined microflotation of fine minerals: Theory and experiment. Trans. Inst. Min. Metall., Sect. C, 2016, 125(2): 81.
|
| [31] |
Trahar WJ, Warren LJ. The flotability of very fine particles—A review. Int. J. Miner. Process., 1976, 3(2): 103.
|
| [32] |
Bournival G, Ata S, Wanless EJ. The roles of particles in multiphase processes: Particles on bubble surfaces. Adv. Colloid Interface Sci., 2015, 225, 114.
|
| [33] |
Li L, Liu JT, Wang LJ, Yu HS. Numerical simulation of a self-absorbing microbubble generator for a cyclonic-static microbubble flotation column. Min. Sci. Technol., 2010, 20(1): 88 (China)
|
| [34] |
Qiu GZ, Hu YH, Wang DZ. Interparticle Interaction and Fine Particle Flotation, 1993, Changsha, Central South University Press
|
| [35] |
Filippov LO, Severov VV, Filippova IV. An overview of the beneficiation of iron ores via reverse cationic flotation. Int. J. Miner. Process., 2014, 127, 62.
|
| [36] |
Haselhuhn HJ, Kawatra SK. Effects of water chemistry on hematite selective flocculation and dispersion. Miner. Process. Extr. Metall. Rev., 2015, 36(5): 305.
|
| [37] |
Eisele TC, Kawatra SK. A review of binders in iron ore palletization. Miner. Process. Extr. Metall. Rev., 2003, 24(1): 1.
|
| [38] |
Zhang Q, Zhao XY, Lu HY, Ni TJ, Li Y. Waste energy recovery and energy efficiency improvement in China’s iron and steel industry. Appl. Energy, 2017, 191, 502.
|
| [39] |
Li GR. Shatokha V. The chinese iron ore deposits and ore production. Iron Ores and Iron Oxide Materials, 2018, London, IntechOpen Press, 3.
|
| [40] |
Nakhaei F, Irannajad M. Reagents types in flotation of iron oxide minerals: A review. Miner. Process. Extr. Metall. Rev., 2018, 39(2): 89.
|
| [41] |
U. S. Geological Survey. Iron ore. Mineral Commodity Summaries 2019, 2019, Virginia, U. S. Geological Survey [2020-4-6]
|
| [42] |
Ma M. Froth flotation of iron ores. Int. J. Min. Eng. Miner. Process., 2012, 1(2): 56.
|
| [43] |
Rocha L, Cançado RZL, Peres AEC. Iron ore slimes flotation. Miner. Eng., 2010, 23(11–13): 842.
|
| [44] |
Araujo AC, Viana PRM, Peres AEC. Reagents in iron ores flotation. Miner. Eng., 2005, 18(2): 219.
|
| [45] |
Sun BQ. Progress in China’s beneficiation technology for complex refractory iron ore. Met. Mine, 2006, 3, 11.
|
| [46] |
Svoboda J. Magnetic Methods for the Treatment of Minerals, 1987, South Africa, Elsevier, 692.
|
| [47] |
D. David, M. Larson, and M. Li, Optimising Western Australia magnetite circuit design, [in] METPLANT 2011- Metallurgical Plant Design and Operating Strategies, Perth, 2011, p. 552.
|
| [48] |
Pradip, S.A. Ravishankar, T.A.P. Sankar, and N.K. Khosla, Beneficiation studies on alumina-rich Indian iron ore slimes using selective dispersants, flocculants and flotation collectors, [in] Proceedings XVIII International Mineral Processing Congress, Sydney, 1993, p. 1289.
|
| [49] |
Lima NP, Valadão GES, Peres AEC. Effect of amine and starch dosages on the reverse cationic flotation of an iron ore. Miner. Eng., 2013, 45, 180.
|
| [50] |
P.R.G. Brandão, Selectivity in reverse iron ore flotation: reagents adsorption, [in] Proceedings XXI Encontro Nacional de Tratamento de Minérios e Metalurgia Extrativa, Natal, 2005. p. 22.
|
| [51] |
Meech JA. Feasibility of iron recovery from Mount Wright tailing material. Can. Min. Metall. Bull., 1981, 74(826): 115.
|
| [52] |
Luo XM, Wang YF, Wen SM, Ma MZ, Sun CY, Yin WZ, Ma YQ. Effect of carbonate minerals on quartz flotation behavior under conditions of reverse anionic flotation of iron ores. Int. J. Miner. Process., 2016, 152, 1.
|
| [53] |
Luo XM. Research on Interactive Effect Among Minerals in Flotation System of Carbonate-Containing Iron Ore, 2014, Shenyang, Northeastern University, 122.
|
| [54] |
Yu YX, Cheng G, Ma LQ, Huang G, Wu L, Xu HX. Effect of agitation on the interaction of coal and kaolinite in flotation. Powder Technol., 2017, 313, 122.
|
| [55] |
Li D, Yin WZ, Liu Q, Cao SH, Sun QY, Zhao C, Yao J. Interactions between fine and coarse hematite particles in aqueous suspension and their implications for flotation. Miner. Eng., 2017, 114, 74.
|
| [56] |
Greaves D, Boxall J, Mulligan J, Montesi A, Creek J, Sloan ED, Koh CA. Measuring the particle size of a known distribution using the focused beam reflectance measurement technique. Chem. Eng. Sci., 2008, 63(22): 5410.
|
| [57] |
Zhang M, Liu MB, Yin WZ, Han YX, Li YJ. Investigation on stepped-flotation process for Dong’anshan carbonate-containing refractory iron ore. Met. Mine, 2007, 9, 62.
|
| [58] |
Yin WZ, Ma YQ, Liu MB, Zhang M, Li LX. Industrial tests on step-flotation of iron ore containing high ferric carbonate in Dong’anshan. Met. Mine, 2011, 8, 64.
|
| [59] |
Bhondayi C, Moys MH. Effects of gas distribution profile on flotation cell performance: An experimental investigation. Int. J. Miner. Process., 2015, 135, 20.
|
| [60] |
Girgin EH, Do S, Gomez CO, Finch JA. Bubble size as a function of impeller speed in a self-aeration laboratory flotation cell. Miner. Eng., 2006, 19(2): 201.
|
| [61] |
Luo XM, Yin WZ, Yao J, Sun CY, Cao Y, Ma YQ, Hou Y. Flotation separation of magnetic separation concentrate of refractory hematite containing carbonate with enhanced dispersion. Chin. J. Nonferrous Met., 2013, 23(1): 238.
|
| [62] |
Li JG, Zhang GH, Shang T, Zhu JF. Synthesis, characterization and application of a dispersant based on rosin for coal-water slurry. Int. J. Min. Sci. Technol., 2014, 24(5): 695.
|
| [63] |
Han HL. Research on the Synergy and its Mechanisms of Step-by-Step Flotation and Dispersing Flotation for Carbonate-Containing, 2016, Shenyang, Northeastern University, 48.
|
| [64] |
Al Omari MMH, Rashid IS, Qinna NA, Jaber AM, Badwan AA. Calcium Carbonate. Profiles of Drug Substances, Excipients and Related Methodology, 2016, Salt Lake City, Academic Press, 31.
|
| [65] |
Deer WA, Howie RA, Zussman J. An Introduction to the Rock-Forming Minerals, 2013, 3rd eds, London, The Mineralogical Society of Great Britain and Ireland
|
| [66] |
Zhang H, Liu WG, Han C, Hao HQ. Effects of monohydric alcohols on the flotation of magnesite and dolomite by sodium oleate. J. Mol. Liq., 2018, 249, 1060.
|
| [67] |
L. Momenzadeh, B. Moghtaderi, X.F. Liu, S.W. Sloan, I.V. Belova, and G.E. Murch, The thermal conductivity of magnesite, dolomite and calcite as determined by molecular dynamics simulation, [in] Diffusion Foundation, L.J. Zhang ed., Trans Tech Publications, 2018, p. 18.
|
| [68] |
Zhou F, Wang LX, Xu ZH, Liu QX, Chi R. Reactive oily bubble technology for flotation of apatite, dolomite and quartz. Int. J. Miner. Process., 2015, 134, 74.
|
| [69] |
Y. Tang, W.Z. Yin, and S. Kelebek, Selective flotation of magnesite from calcite using potassium cetyl phosphate as a collector in the presence of sodium silicate, Miner. Eng., 146(2020), art. No. 106154.
|
| [70] |
E. Dimopoulos and G.N. Anastassakis, Recovery of magnesite from fine waste material rejected before hand-sorting, [in] Proceedings of XV Balkan Mineral Processing Congress, Sozopol, 2013, p. 213.
|
| [71] |
Anastassakis GN. A study on the separation of magnesite fines by magnetic carrier methods. Colloids Surf. A, 1999, 149(1–3): 585.
|
| [72] |
Li GF. Development of magnesite concentration and success in its flotation technology. China Min. Mag., 1995, 4(2): 64.
|
| [73] |
Raschman P. Leaching of calcined magnesite using ammonium chloride at constant pH. Hydrometallurgy, 2000, 56(1): 109.
|
| [74] |
Potapenko VE, Suvorova DI, Tyuryukhanova VV. Beneficiation of magnesite ores by froth separation. Refractories, 1981, 22(3): 146.
|
| [75] |
Y. Tang, W.Z. Yin, and S. Kelebek, Magnesite-dolomite separation using potassium cetyl phosphate as a novel flotation collector and related surface chemistry, Appl. Surf. Sci., 508(2020), art. No. 145191.
|
| [76] |
B.M. Moudgil, Separation of Magnesite from Ores Which Also Contain Calcite or Dolomite, U.S. Patent, Appl. 4207175, 1980.
|
| [77] |
Geological Survey US. Mineral Commodity Summaries (2010–2018), 2010, Virginia, U.S. Geological Survey [2020-04-08]
|
| [78] |
Škvarla J, Kmet’ S. Non-equilibrium electro kinetic properties of magnesite and dolomite determined by the laser-Doppler electrophoretic light scattering (ELS) technique. A solids concentration effect. Colloids Surf. A, 1996, 111(1–2): 153.
|
| [79] |
Bentli I, Erdogan N, Elmas N, Kaya M. Magnesite concentration technology and caustic-calcined product from Turkish magnesite middlings by calcination and magnetic separation. Sep. Sci. Technol., 2017, 52(6): 1129.
|
| [80] |
J.F. Mao, Z.J. Zhang, and H.L. Zhao, Research into the effect of combined modifiers in magnesite flotation, [in] Proceedings XVIII International Mineral Processing Congress, Sydney, 1993, p. 1118.
|
| [81] |
Liu YQ, Liu Q. Flotation separation of carbonate from sulfide minerals, I: Flotation of single minerals and mineral mixtures. Miner. Eng., 2004, 17(7–8): 855.
|
| [82] |
Wonyen DG, Kromah V, Gibson B, Nah S, Chelgani SC. A review of flotation separation of Mg carbonates (dolomite and magnesite). Minerals, 2018, 8(8): 354.
|
| [83] |
Soto H, Iwasaki I. Selective flotation of phosphates from dolomite using cationic collectors. I. Effect of collector and nonpolar hydrocarbons. Int. J. Miner. Process., 1986, 16(1–2): 3.
|
| [84] |
Forbes E, Davey KJ, Smith L. Decoupling rehology and slime coatings effect on the natural flotability of chalcopyrite in a clay-rich flotation pulp. Miner. Eng., 2014, 56, 136.
|
| [85] |
Yao J, Xue JW, Li D, Fu YF, Gong EP, Yin WZ. Effects of fine-coarse particles interaction on flotation separation and interaction energy calculation. Part. Sci. Technol., 2018, 36(1): 11.
|
| [86] |
Yao J. Research on the Reciprocal Influences Among Magnesium-containing Ores in Flotation, 2014, Shenyang, Northeastern University
|
| [87] |
Missana T, Adell A. On the applicability of DLVO theory to the prediction of clay colloids stability. J. Colloid Interface Sci., 2000, 230(1): 150.
|
| [88] |
Yoon RH, Mao LQ. Application of extended DLVO theory, IV: Derivation of flotation rate equation from first principles. J. Colloid Interface Sci., 1996, 181(2): 613.
|
| [89] |
Gallios GP, Matis KA. Mavros P, Matis KA. Flotation of salt-type minerals. Innovations in Flotation Technology. NATO ASI Series, 1992, Dordrecht, Springer
|
| [90] |
Matis KA, Gallios GP. Anionic flotation of magnesium carbonates by modifiers. Int. J. Miner. Process., 1989, 25(3–4): 261.
|
| [91] |
Turrer HDG, Araujo AC, Papini RM, Peres AEC. Iron ore flotation in the presence of polyacrylamides. Trans. Inst. Min. Metall. Sect. C, 2007, 116(2): 81.
|
| [92] |
Yang XS. Beneficiation studies of tungsten ores—A review. Miner. Eng., 2018, 125, 111.
|
| [93] |
U.S. Geological Survey. Tungsten. Mineral Commodity Summaries 2019, 2019, Virginia, U.S. Geological Survey, 179 [2020-4-6]
|
| [94] |
Pitfield P, Brown T, Gunn G, Rayner D. Mineral Profiles-Tungsten, 2011, Nottingham, British Geological Survey [2020-04-08]
|
| [95] |
Pradip Rai B, Rao TK, Krishnamurthy S, Vetrivel R, Mielczarski J, Cases JM. Molecular modeling of interactions of alkyl hydroxamates with calcium minerals. J. Colloid Interface Sci., 2002, 256(1): 106.
|
| [96] |
Yin WZ, Wang JZ. Effects of particle size and particle interactions on scheelite flotation. Trans. Nonferrous Met. Soc. China, 2014, 24(11): 3682.
|
| [97] |
Gao YS, Gao ZY, Sun W, Hu YH. Selective flotation of scheelite from calcite: a novel reagent scheme. Int. J. Miner. Process., 2016, 154, 10.
|
| [98] |
Angadi SI, Sreenivas T, Jeon HS, Baek SH, Mishra BK. A review of cassiterite beneficiation fundamentals and plant practices. Miner. Eng., 2015, 70, 178.
|
| [99] |
Deng LQ, Zhao G, Zhong H, Wang S, Liu GY. Investigation on the selectivity of N-((hydroxyamino)-alkyl) alkylamide surfactants for scheelite/calcite flotation separation. J. Ind. Eng. Chem., 2016, 33, 131.
|
| [100] |
Kupka N, Rudolph M. Froth flotation of scheelite—A review. Int. J. Min. Sci. Technol., 2018, 28(3): 373.
|
| [101] |
W. Bernhart, Processing of tungsten bearing ores-mineral processing and metallurgy, [in] MultiScience-XXIX. MicroCAD International Multidisciplinary Scientific Conference, University of Miskolc, 2015. http://www.uni-miskolc.hu/~microcad/publikaciok/2015/B4_Bernhart_Wolfram.pdf
|
| [102] |
Li YX, Li CG. Selective flotation of scheelite from calcium minerals with sodium oleate as a collector and phosphates as modifiers. I. Selective flotation of scheelite. Int. J. Miner. Process., 1983, 10(3): 205.
|
| [103] |
Gao ZY, Bai D, Sun W, Cao XF, Hu YH. Selective flotation of scheelite from calcite and fluorite using a collector mixture. Miner. Eng., 2015, 72, 23.
|
| [104] |
Han HS, Hu YH, Sun W, Li XD, Cao CG, Liu RQ, Yue T, Meng XS, Guo YZ, Wang JJ, Gao ZY, Chen P, Huang WS, Liu J, Xie JW, Chen YL. Fatty acid flotation versus BHA flotation of tungsten minerals and their performance in flotation practice. Int. J. Miner. Process., 2017, 159, 22.
|
| [105] |
Gao YS, Gao ZY, Sun W, Yin ZG, Wang JJ, Hu YH. Adsorption of a novel reagent scheme on scheelite and calcite causing an effective flotation separation. J. Colloid Interface Sci., 2018, 512, 39.
|
| [106] |
Wang JJ, Gao ZY, Gao YS, Hu YH, Sun W. Flotation separation of scheelite from calcite using mixed cationic/anionic collectors. Miner. Eng., 2016, 98, 261.
|
| [107] |
Zhao G, Wang S, Zhong H. Study on the activation of scheelite and wolframite by lead nitrate. Minerals, 2015, 5(2): 247.
|
| [108] |
Koh PTL, Warren LJ. Flotation of flocs of ultrafine scheelite. Trans. Inst. Min. Metall. Sect. C, 1977, 86, C93.
|
| [109] |
Wang JZ. Study on Flotation and Separation Intensification of Complex Refractory Scheelite and its Reaction Mechanism, 2015, Shenyang, Northeastern University
|
| [110] |
Wang JZ, Yin WZ, Sun ZM. Effect and mechanism of co-depressant of calcite and sodium hexametaphosphate on scheelite flotation. Chin. J. Nonferrous Met., 2015, 28(8): 1645.
|