Cell morphology, porosity, microstructure and mechanical properties of porous Fe-C-P alloys

Hamid Sazegaran , Seyyed Mohsen Moosavi Nezhad

International Journal of Minerals, Metallurgy, and Materials ›› 2021, Vol. 28 ›› Issue (2) : 257 -265.

PDF
International Journal of Minerals, Metallurgy, and Materials ›› 2021, Vol. 28 ›› Issue (2) : 257 -265. DOI: 10.1007/s12613-020-1995-2
Article

Cell morphology, porosity, microstructure and mechanical properties of porous Fe-C-P alloys

Author information +
History +
PDF

Abstract

Open cell steel foams were successfully fabricated through the powder metallurgy route using urea granules as the water leachable space holder in the present study. The influence of different amounts of phosphorus (0, 0.5wt%, 1wt%, 2wt%, and 4wt%) was investigated on the cell morphology, porosity, microstructure of cell walls, and mechanical properties of steel foams. The cell morphology and microstructure of the cell walls were evaluated using an optical microscope equipped with image processing software and a scanning electron microscope equipped with an energy dispersive X-ray spectrometer. In addition, the compression tests were conducted on the steel foams using a universal testing machine. Based on microscopic images, the porous structure consists of spherical cells and irregularly shaped pores that are distributed in the cell walls. The results indicated that by increasing the phosphorus content, the porosity increases from 71.9% to 83.2%. The partially distributed ferrite and fine pearlite was observed in the microstructure of the cell walls, and α-Fe and Fe3P eutectic extended between the boundaries of agglomerated iron particles. Furthermore, elastic and long saw-toothed plateau regions were observed before fracture in the compressional stress—strain curves. According to the results, by increasing the phosphorus content from 0 to 4wt%, the plateau region of the stress—strain curves shifts to the right and upward. Therefore, increasing phosphorus content causes improvement in the mechanical properties of steel foams.

Keywords

steel foam / phosphorus / space holder technique / microstructure / compressive behavior

Cite this article

Download citation ▾
Hamid Sazegaran, Seyyed Mohsen Moosavi Nezhad. Cell morphology, porosity, microstructure and mechanical properties of porous Fe-C-P alloys. International Journal of Minerals, Metallurgy, and Materials, 2021, 28(2): 257-265 DOI:10.1007/s12613-020-1995-2

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

M. Ashby, T. Evans, N.A. Fleck, J.W. Hutchinson, H.N.G. Wadley, and L.J. Gibson, Metal Foams: A Design Guide, Elsevier Inc, Butterworth-Heinemann, 2000.

[2]

Degischer HP, Kriszt B. Handbook of Cellular Metals, Production, Processing, Applications, 2002, Weinheim, Wiley-VCH Verlag GmbH

[3]

Banhart J. Manufacture, characterization and application of cellular metals and metal foams. Prog. Mater. Sci., 2001, 46(6): 559.

[4]

Bienvenu Y. Application and future of solid foams. C.R. Phys., 2014, 15(8–9): 719.

[5]

N. Gupta and P.K. Rohatgi, Metal Matrix Syntactic Foams: Processing, Microstructure, Properties and Applications, DEStech Publications, 2014.

[6]

Otaru AJ. Review on processing and fluid transport in porous metals with a focus on bottleneck structures. Met. Mater. Int., 2020, 26(4): 510.

[7]

R. Kumar, H. Jain, S. Sriram, A. Chaudhary, A. Khare, V.A.N. Ch, and D.P. Mondal, Lightweight open cell aluminum foam for superior mechanical and electromagnetic interference shielding properties, Mater. Chem. Phys., 240(2020), art. No. 122274.

[8]

Liu CJ, Zhang YX, Li J. Impact responses of sandwich panels with fibre metal laminate skins and aluminium foam core. Compos. Struct., 2017, 182, 183.

[9]

Liu C, Zhang YX, Ye L. High velocity impact responses of sandwich panels with metal fibre laminate skins and aluminium foam core. Int. J. Impact Eng., 2017, 100, 139.

[10]

Duarte I, Vesenjak M, Krstulović-Opara L, Ren Z. Crush performance of multifunctional hybrid foams based on an aluminium alloy open-cell foam skeleton. Polym. Test., 2018, 67, 246.

[11]

Fan JH, Zhang JJ, Wang ZH, Li ZQ, Zhao LM. Dynamic crushing behavior of random and functionally graded metal hollow sphere foams. Mater. Sci. Eng. A, 2013, 561, 352.

[12]

Li LB, Zheng ZJ, Yu JL, Lu FY. Deformation and perforation of sandwich panels with aluminum-foam core at elevated temperatures. Int. J. Impact Eng., 2017, 109, 366.

[13]

Jing L, Wang ZH, Zhao LM. The dynamic response of sandwich panels with cellular metal cores to localized impulsive loading. Composite Part B, 2016, 94, 52.

[14]

Wu JJ, Li CG, Li DB, Gui MC. Damping and sound absorption properties of particle reinforced Al matrix composite foams. Compos. Sci. Technol., 2003, 63(3–4): 569.

[15]

Huisseune H, de Schampheleire S, Ameel B, de Paepe M. Comparison of metal foam heat exchangers to a finned heat exchanger for low Reynolds number applications. Int. J. Heat Mass Transfer, 2015, 89, 1.

[16]

Kim DY, Sung TH, Kim KC. Application of metal foam heat exchangers for a high-performance liquefied natural gas regasification system. Energy, 2016, 105, 57.

[17]

Tseng CJ, Heush YJ, Chiang CJ, Lee YH, Lee KR. Application of metal foams to high temperature PEM fuel cells. Int. J. Hydrogen Energy, 2016, 41(36): 16196.

[18]

Kolaczkowski ST, Awdry S, Smith T, Thomas D, Torkuhl L, Kolvenbach R. Potential for metal foams to act as structured catalyst supports in fixed-bed reactors. Catal. Today, 2016, 273, 221.

[19]

Seok J, Chun KM, Song S, Lee J. An empirical study of the dry soot filtration behavior of a metal foam filter on a particle number concentration basis. Energy, 2014, 76, 949.

[20]

Garcia I, Gracia-Escosa E, Bayod M, Conde A, Arenas MA, Damborenea J, Romero A, Rodríguez G. Sustainable production of titanium foams for biomedical applications by Concentrated Solar Energy sintering. Mater. Lett., 2016, 185, 420.

[21]

Kashef S, Asgari A, Hilditch TB, Yan WY, Goel VK, Hodgson PD. Fracture toughness of titanium foams for medical applications. Mater. Sci. Eng. A, 2010, 527(29–30): 7689.

[22]

J. Banhart, Production of metal foams, [in] P.W.R. Beaumont and C.H. Zweben, eds., Comprehensive Composite Materials II, 2nd ed., Elsevier, 2018, p. 347.

[23]

Kim S, Lee CW. A review on manufacturing and application of open-cell metal foam. Procedia Mater. Sci., 2014, 4, 305.

[24]

Smith BH, Szyniszewski S, Hajjar JF, Schafer BW, Arwade SR. Steel foam for structures: A review of applications, manufacturing and material properties. J. Constr. Steel. Res., 2012, 71, 1.

[25]

Golabgir MH, Ebrahimi-Kahrizsangi R, Torabi O, Tajizadegan H, Jamshidi A. Fabrication and evaluation of oxidation resistance performance of open-celled Fe(Al) foam by space-holder technique. Adv. Powder. Technol., 2014, 25(3): 960.

[26]

Xie B, Fan YZ, Mu TZ, Deng B. Fabrication and energy absorption properties of titanium foam with CaCl2 as a space holder. Mater. Sci. Eng. A, 2017, 708, 419.

[27]

Li BQ, Li ZQ, Lu X. Effect of sintering processing on property of porous Ti using space holder technique. Trans. Nonferrous Met. Soc. China, 2015, 25(9): 2965.

[28]

Aida SF, Hijrah MN, Amirah AH, Zuhailawati H, Anasyida AS. Effect of NaCl as a space holder in producing open cell A356 aluminium foam by gravity die casting process. Procedia Chem., 2016, 19, 234.

[29]

Jia GZ, Hou Y, Chen CX, Niu JL, Zhang H, Huang H, Xiong MP, Yuan GY. Precise fabrication of open porous Mg scaffolds using NaCl templates: Relationship between space holder particles, pore characteristics and mechanical behavior. Mater. Des., 2018, 140, 106.

[30]

Torres Y, Pavón JJ, Rodríguez JA. Processing and characterization of porous titanium for implants by using NaCl as space holder. J. Mater. Process. Technol., 2012, 212(5): 1061.

[31]

Ruperez E, Manero JM, Riccardi K, Li YP, Aparicio C, Gil FJ. Development of tantalum scaffold for orthopedic applications produced by space-holder method. Mater. Des., 2015, 83, 112.

[32]

Unver I, Gulsoy HO, Aydemir B. Ni-625 superalloy foam processed by powder space-holder technique. J. Mater. Eng. Perform., 2013, 22(12): 3735.

[33]

Tian DR, Pang YH, Yu L, Sun L. Production and characterization of high porosity porous Fe-Cr-C alloys by the space holder leaching technique. Int. J. Miner. Metall. Mater., 2016, 23(7): 793.

[34]

Bafti H, Habibolahzadeh A. Production of aluminum foam by spherical carbamide space holder technique-processing parameters. Mater. Des., 2010, 31(9): 4122.

[35]

Hosseini SA, Yazdani-Rad R, Kazemzadeh A, Alizadeh M. A comparative study on the mechanical behavior of porous titanium and NiTi produced by a space holder technique. J. Mater. Eng. Perform., 2014, 23(3): 799.

[36]

Sharma M, Gupta GK, Modi OP, Prasad BK, Gupta AK. Titanium foam through powder metallurgy route using acicular urea particles as space holder. Mater. Lett., 2011, 65(21–22): 3199.

[37]

Adamek G, Jakubowicz J. Tantalum foam made with sucrose as a space holder. Int. J. Refract. Met. Hard Mater., 2015, 53, 51.

[38]

Mansourighasri A, Muhamad N, Sulong AB. Processing titanium foams using tapioca starch as a space holder. J. Mater. Process. Technol., 2012, 212(1): 83.

[39]

Asik EE, Bor Ş. Fatigue behavior of Ti-6Al-4V foams processed by magnesium space holder technique. Mater. Sci. Eng. A, 2015, 621, 157.

[40]

Aydoğmuş T, Bor ET, Bor Ş. Phase transformation behavior of porous TiNi alloys produced by powder metallurgy using magnesium as a space holder. Metall. Mater. Trans. A, 2011, 42(9): 2547.

[41]

Shimizu T, Matsuzaki K, Nagai H, Kanetake N. Production of high porosity metal foams using EPS beads as space holders. Mater. Sci. Eng. A, 2012, 558, 343.

[42]

Kadkhodapour J, Montazerian H, Samadi M, Schmauder S, Abouei Mehrizi A. Plastic deformation and compressive mechanical properties of hollow sphere aluminum foams produced by space holder technique. Mater. Des., 2015, 83, 352.

[43]

Bekoz N, Oktay E. Effect of heat treatment on mechanical properties of low alloy steel foams. Mater. Des., 2013, 51, 212.

[44]

Bekoz N, Oktay E. High temperature mechanical properties of low alloy steel foams produced by powder metallurgy. Mater. Des., 2014, 53, 482.

[45]

Mutlu I, Oktay E. Processing and properties of highly porous 17-4 PH stainless steel. Powder Metall. Met. Ceram., 2011, 50(1–2): 73.

[46]

Mirzaei M, Paydar MH. Fabrication and characterization of core-shell density-graded 316L stainless steel porous structure. J. Mater. Eng. Perform., 2019, 28(1): 221.

[47]

Pang Q, Hu ZL, Wang GR. Effect of Ce content on mechanical properties of Ce/Cr coated open-cell Ni-Cr-Fe alloy foams. Trans. Nonferrous Met. Soc. China, 2017, 27(5): 1052.

[48]

Mirzaei M, Paydar MH. A novel process for manufacturing porous 316L stainless steel with uniform pore distribution. Mater. Des., 2017, 121, 442.

[49]

Bekoz N, Oktay E. Effects of carbamide shape and content on processing and properties of steel foams. J. Mater. Process. Technol., 2012, 212(10): 2109.

[50]

Gulsoy H, German RM. Sintered foams from precipitation hardened stainless steel powder. Powder Metall., 2008, 51(4): 350.

[51]

Sazegaran H, Hojati M. Effects of copper content on microstructure and mechanical properties of open-cell steel foams. Int. J. Miner. Metall. Mater., 2019, 26(5): 588.

[52]

Okamoto H. The Fe-P (iron-phosphorus) system. Bull. Alloy Phase Diagram, 1990, 11(4): 404.

[53]

Yin Y, Li ZM, Zhai SM. The phase diagram of the Fe-P binary system at 3 GPa and implications for phosphorus in the lunar core. Geochim. Cosmochim. Acta, 2019, 254, 54.

[54]

Sazegaran H, Feizi A, Hojati M. Effect of Cr contents on the porosity percentage, microstructure, and mechanical properties of steel foams manufactured by powder metallurgy. Trans. Indian Inst. Met., 2019, 72(10): 2819.

[55]

Abosbaia AAS, Mitchell SC, Youseffi M, Wronski AS. Liquid phase sintering, heat treatment and properties of ultrahigh carbon steel. Powder Metall., 2011, 54(5): 592.

[56]

Turkmen M. Effect of carbon content on microstructure and mechanical properties of powder metallurgy steels. Powder Metall. Met. Ceram., 2016, 55(3–4): 164.

AI Summary AI Mindmap
PDF

171

Accesses

0

Citation

Detail

Sections
Recommended

AI思维导图

/