Effect of chemical activation process on adsorption of As(V) ion from aqueous solution by mechano-thermally synthesized zinc ferrite nanopowder

Abstract

Nanostructured ZnFe₂O₄ was synthesized by the heat treatment of a mechanically activated mixture of ZnO/α-Fe₂O₃. X-ray diffraction (XRD) and differential thermal analysis (DTA) results demonstrated that, after 5 h of the mechanical activation of the mixture, ZnFe₂O₄ was formed by heat treatment at 750°C for 2 h. To improve the characteristics of ZnFe₂O₄ for adsorption applications, the chemical activation process was performed. The 2 h chemical activation with 1 mol·L^-1 HNO₃ and co-precipitation of 52%-57% dissolved ZnFe₂O₄ led to an increase in the saturated magnetization from 2.0 to 7.5 emu·g^-1 and in the specific surface area from 5 to 198 m²·g^-1. In addition, the observed particle size reduction of chemically activated ZnFe₂O₄ in field emission scanning electron microscopy (FESEM) micrographs was in agreement with the specific surface area increase. These improvements in ZnFe₂O₄ characteristics considerably affected the adsorption performance of this adsorbent. Adsorption results revealed that mechano-thermally synthesized ZnFe₂O₄ had the maximum arsenic adsorption of 38% with the adsorption capacity of 0.995 mg·g^-1 in a 130 mg·L^-1 solution of As(V) after 30 min of agitation. However, chemically activated ZnFe₂O₄ showed the maximum arsenic adsorption of approximately 99% with the adsorption capacity of 21.460 mg·g^-1 under the same conditions. These results showed that the weak adsorption performance of mechano-thermally synthesized ZnFe₂O₄ was improved by the chemical activation process.

Keywords

zinc ferrite / mechano-thermal / chemical activation / adsorption / arsenic(V)

References

[1] Karakaş ZK, Boncukcuoğlu R, Karakaş IH. Adsorptive properties of As(III) from aqueous solution using magnetic nickel ferrite (NiFe₂O₄) nanoparticles: Isotherm and kinetic studies. Sep. Sci. Technol, 2017, 52, 21.

[2] Abdul KSM, Jayasinghe SS, Chandana EPS, Jayasumana C, De Silva PMCS. Arsenic and human health effects: A review. Environ. Toxicol. Pharmacol, 2015, 40, 828.

[3] Burakov AE, Galunin EV, Burakova Kucherova AE, Agarwal S, Tkachev AG, Gupta VK. Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: A review. Ecotoxicol. Environ. Saf, 2018, 148, 702.

[4] Gómez-Pastora J, Bringas E, Ortiz I. Recent progress and future challenges on the use of high performance magnetic nano-adsorbents in environmental applications. Chem. Eng. J, 2014, 256, 187.

[5] Tu YJ, Chan TS, Tu HW, Wang SL, You CF, Chang CK. Rapid and efficient removal/recovery of molybdenum onto ZnFe₂O₄ anoparticles. Chemosphere, 2016, 148, 452.

[6] Parsons JG, Lopez ML, Peralta-Videa JR, Gardea-Torresdey JL. Determination of arsenic(III) and arsenic(V) binding to microwave assisted hydrothermal synthetically prepared Fe₃O₄, Mn₃O₄, and MnFe₂O₄ nanoadsorbents. Microchem. J, 2009, 91, 100.

[7] Martinez-Vargas S, Martínez AI, Hernández-Beteta EE, Mijangos-Ricardez OF, Vázquez-Hipólito V, Patiño-Carachure C, López-Luna J. As(III) and As(V) adsorption on manganese ferrite nanoparticles. J. Mol. Struct, 2018, 1154, 524.

[8] Martinez-Vargas S, Martínez AI, Hernández-Beteta EE, Mjangos-Ricardez OF, Vázquez-Hipólito V, Patiño-Carachure C, Hernandez-Flores H, López-Luna J. Arsenic adsorption on cobalt and manganese ferrite nanoparticles. J. Mater. Sci, 2017, 52, 6205.

[9] Druska P, Steinike U, Šepelák V. Surface structure of mechanically activated and of mechanosynthesized zinc ferrite. J. Solid State Chem, 1999, 146, 13.

[10] Hu J, Lo IMC, Chen GH. Comparative study of various magnetic nanoparticles for Cr(VI) removal. Sep. Purif. Technol, 2007, 56, 249.

[11] Dui JN, Zhu GY, Zhou SM. Facile and economical synthesis of large hollow ferrites and their applications in adsorption for As(V) and Cr(VI). ACS Appl. Mater. Interfaces, 2013, 5, 10081.

[12] Reddy MP, Mohamed AMA, Zhou XB, Du S, Huang Q. A facile hydrothermal synthesis, characterization and magnetic properties of mesoporous CoFe₂O₄ nanospheres. J. Magn. Magn. Mater, 2015, 388, 40.

[13] Anchieta CG, Severo EC, Rigo C, Mazutti MA, Kuhn RC, Muller EI, Flores EMM, Moreira RFPM, Foletto EL. Rapid and facile preparation of zinc ferrite (ZnFe₂O₄) oxide by microwave-solvothermal technique and its catalytic activity in heterogeneous photo-Fenton reaction. Mater Chem. Phys, 2015, 160, 141.

[14] Hosseinzadeh M, Ebrahimi SAS, Raygan S, Masoudpanah SM. Removal of cadmium and lead ions from aqueous solution by nanocrystalline magnetite through mechanochemical activation. J. Ultrafine Grained Nanostruct. Mater, 2016, 49, 72.

[15] Rajput S, Pittman CU Jr Mohan D. Magnetic magnetite (Fe₃O₄) nanoparticle synthesis and applications for lead (Pb²⁺) and chromium (Cr⁶⁺) removal from water. J. Colloid Interface Sci, 2016, 468, 334.

[16] Shen YF, Tang J, Nie ZH, Wang YD, Ren Y, Zuo L. Preparation and application of magnetic Fe₃O₄ nanoparticles for wastewater purification. Sep. Purif. Technol, 2009, 68, 312.

[17] Santona L, Castaldi P, Melis P. Evaluation of the interaction mechanisms between red muds and heavy metals. J. Hazard. Mater, 2006, 136, 324.

[18] Sahu MK, Mandal S, Dash SS, Badhai P, Patel RK. Removal of Pb(II) from aqueous solution by acid activated red mud. J. Environ. Chem. Eng, 2013, 1, 1315.

[19] Sushil S, Batra VS. Catalytic applications of red mud, an aluminium industry waste: A review. Appl. Catal. B, 2008, 81, 64.

[20] Hunter JC. Preparation of a new crystal form of manganese dioxide: λ-MnO₂. J. Solid State Chem, 1981, 39, 142.

[21] Tu YJ, You CF, Chang CK, Wang SL. XANES evidence of arsenate removal from water with magnetic ferrite. J. Environ. Manage, 2013, 120, 114.

[22] Tu YJ, You CF, Chang CK, Wang SL, Chan TS. Arsenate adsorption from water using a novel fabricated copper ferrite. Chem. Eng. J, 2012, 199, 440.

[23] Williamson GK, Hall WH. X-ray line broadening from filed aluminium and wolfram. Acta Metall, 1953, 1, 22.

[24] Hajalilou A, Hashim M, Ebrahimi-Kahrizsangi R, Kamari HM, Sarami N. Synthesis and structural characterization of nano-sized nickel ferrite obtained by mechanochemical process. Ceram. Int, 2014, 40, 5881.

[25] Goya GF, Rechenberg HR. Ionic disorder and Néel temperature in ZnFe₂O₄ nanoparticles. J. Magn. Magn. Mater, 1999, 197, 191.

[26] Bid S, Pradhan SK. Preparation of zinc ferrite by high-energy ball-milling and microstructure characterization by Rietveld's analysis. Mater. Chem. Phys, 2003, 82, 27.

[27] Kleiner S, Bertocco F, Khalid FA, Beffort O. Decomposition of process control agent during mechanical milling and its influence on displacement reactions in the Al-TiO₂ system. Mater. Chem. Phys, 2005, 89, 362.

[28] Zhang SH, Shi RX, Tan Y. Comparison of the solubility of ZnFe₂O₄, Fe₃O₄ and Fe₂O₃ in high temperature water. J. Solution Chem, 2018, 47, 1112.

[29] Shawabkeh RA. Hydrometallurgical extraction of zinc from Jordanian electric arc furnace dust. Hydrometallurgy, 2010, 104, 61.

[30] Hu J, Lo IMC, Chen GH. Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe₂O₄) nanoparticles. Langmuir, 2005, 21, 11173.

[31] Mandaokar SS, Dharmadhikari DM, Dara SS. Retrieval of heavy metal ions from solution via ferritisation. Environ. Pollut, 1994, 83, 277.

[32] Shahane GS, Kumar A, Arora M, Pant RP, Lal K. Synthesis and characterization of Ni-Zn ferrite nano particles. J. Magn. Magn. Mater, 2010, 322, 1015.

[33] Green DW, Perry RH. Perry's Chemical Engineers' Handbook, 2007, New York, McGraw-Hill

[34] Li QL, Wang YF, Chang CB. Study of Cu, Co, Mn and La doped NiZn ferrite nanorods synthesized by the coprecipitation method. J. Alloys Compd, 2010, 505, 523.

[35] Gajović A, Šturm S, Jančar B, Šantić A, Žagar K, Čeh M. The synthesis of pure - phase bismuth ferrite in the Bi-Fe-O system under hydrothermal conditions without a mineralizer. J. Am. Ceram. Soc, 2010, 93, 3173.

[36] Hua M, Zhang SJ, Pan BC, Zhang WM, Lv L, Zhang QX. Heavy metal removal from water/wastewater by nanosized metal oxides: A review. J. Hazard. Mater, 2012, 211-212, 317.

[37] Mohan D, Pittman CU Jr. Arsenic removal from water/wastewater using adsorbents—A critical review. J. Hazard. Mater, 2007, 142, 1.

[38] Choi D, Blomgren GE, Kumta PN. Fast and reversible surface redox reaction in nanocrystalline vanadium nitride supercapacitors. Adv. Mater, 2006, 18, 1178.

[39] Mustafa S, Zaman MI, Gul R, Khan S. Effect of Ni²⁺ loading on the mechanism of phosphate anion sorption by iron hydroxide. Sep. Purif. Technol, 2008, 59, 108.

[40] Kefirov R, Ivanova E, Hadjiivanov K, Dzwigaj S, Che M. FTIR characterization of Fe³⁺-OH groups in Fe-H-BEA zeolite: Interaction with CO and NO. Catal. Lett, 2008, 125, 209.

[41] Mariani G, Fabbri M, Negrini F, Ribani PL. High-gradient magnetic separation of pollutant from wastewaters using permanent magnets. Sep. Purif. Technol, 2010, 72, 147.

[42] Shenoy SD, Joy PA, Anantharaman MR. Effect of mechanical milling on the structural, magnetic and dielectric properties of coprecipitated ultrafine zinc ferrite. J Magn. Magn. Mater, 2004, 269, 217.

[43] Chinnasamy CN, Narayanasamy A, Ponpandian N, Chattopadhyay K, Guérault H, Greneche JM. Magnetic properties of nanostructured ferrimagnetic zinc ferrite. J. Phys. Condens. Matter, 2000, 12, 7795.

[44] Cao MH, Liu TF, Gao S, Sun GB, Wu XL, Hu CW, Wang ZL. Single-crystal dendritic micropines of magnetic α-Fe₂O₃: Large-scale synthesis, formation mechanism, and properties. Angew. Chem. Int. Ed, 2005, 44, 4197.

[45] Ahmadzadeh M, Ataie A, Mostafavi E. The effects of mechanical activation energy on the solid-state synthesis process of BiFeO₃. J. Alloys Compd, 2015, 622, 548.

[46] Murad E. Magnetic properties of microcrystalline iron(III) oxides and related materials as reflected in their Mössbauer spectra. Phys. Chem. Miner, 1996, 23, 248.

[47] Atif M, Hasanain SK, Nadeem M. Magnetization of sol-gel prepared zinc ferrite nanoparticles: Effects of inversion and particle size. Solid State Commun, 2006, 138, 416.

[48] Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthès V, Krimissa M. Sorption isotherms: A review on physical bases, modeling and measurement. Appl. Geochem, 2007, 22, 249.

[49] Verburg K, Baveye P. Hysteresis in the binary exchange of cations on 2:1 clay minerals: A critical review. Clays Clay Miner, 1994, 42, 207.

[50] Zhang SX, Niu HY, Cai YQ, Zhao XL, Shi YL. Arsenite and arsenate adsorption on coprecipitated bimetal oxide magnetic nanomaterials: MnFe₂O₄ and CoFe₂O₄. Chem. Eng. J, 2010, 158, 599.

[51] Benavente M, Moreno L, Martinez J. Sorption of heavy metals from gold mining wastewater using chitosan. J. Taiwan Inst. Chem. Eng, 2011, 42, 976.