New high-strength Ti–Al–V–Mo alloy: from high-throughput composition design to mechanical properties

Di Wu , Wan-lin Wang , Li-gang Zhang , Zhen-yu Wang , Ke-chao Zhou , Li-bin Liu

International Journal of Minerals, Metallurgy, and Materials ›› 2019, Vol. 26 ›› Issue (9) : 1151 -1165.

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International Journal of Minerals, Metallurgy, and Materials ›› 2019, Vol. 26 ›› Issue (9) : 1151 -1165. DOI: 10.1007/s12613-019-1854-1
Article

New high-strength Ti–Al–V–Mo alloy: from high-throughput composition design to mechanical properties

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Abstract

The high-throughput diffusion-multiple technique and thermodynamics databases were used to design new high-strength Ti alloys. The composition–microstructure–property relationships of the Ti64–xMo alloys were obtained. The phase fraction and composition of the α and β phases of the Ti64–xMo alloys were calculated using the Thermo-Calc software. After aging at 600°C, the Ti64–6Mo alloy precipitated ultrafine α phases. This phenomenon was explained on the basis of the pseudo-spinodal mechanism by calculating the Gibbs energy curves of the α and β phases of the Ti64–xMo alloys at 600°C. Bulk forged Ti64–6Mo alloy exhibited high strength and moderate plasticity after α/β-phase-field solution treatment plus aging. The tensile properties of the alloy were determined by the size and morphology of the primary and secondary α phases and by the β grain size.

Keywords

high-strength titanium alloy / Ti–6Al–4V–xMo / diffusion multiple / Thermo-Calc / microstructure and mechanical properties

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Di Wu, Wan-lin Wang, Li-gang Zhang, Zhen-yu Wang, Ke-chao Zhou, Li-bin Liu. New high-strength Ti–Al–V–Mo alloy: from high-throughput composition design to mechanical properties. International Journal of Minerals, Metallurgy, and Materials, 2019, 26(9): 1151-1165 DOI:10.1007/s12613-019-1854-1

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References

[1]

Li HX, Nie XY, He ZB, Zhao KN, Du Q, Zhang JS, Zhuang LZ. Interfacial microstructure and mechanical properties of Ti–6Al–4V/Al7050 joints fabricated using the insert molding method. Int. J. Miner. Metall. Mater., 2017, 24(12): 1412

[2]

Ibrahim MK, Hamzah E, Saud SN, Bakar ENE A, Bahador A. Microwave sintering effects on the microstructure and mechanical properties of Ti–51at% Ni shape memory alloys. Int. J. Miner. Metall. Mater., 2017, 24(3): 280

[3]

Boyer RR. An overview on the use of titanium in the aerospace industry. Mater. Sci. Eng. A, 1996, 213(1–2): 103

[4]

Prasanthi TN, Sudha C, Saroja S. Effect of alloying elements on interdiffusion phenomena in explosive clads of 304LSS/Ti–5Ta–2Nb alloy. J. Mater. Sci., 2016, 51(11): 5290

[5]

Duan HP, Xu HX, Su WH, Ke YB, Liu ZQ, Song HH. Effect of oxygen on the microstructure and mechanical properties of Ti–23Nb–0.7Ta–2Zr alloy. Int. J. Miner. Metall. Mater., 2012, 19(12): 1128

[6]

Semiatin SL, Fagin PN, Glavicic MG, Sukonnik IM, Ivasishin OM. Influence on texture on beta grain growth during continuous annealing of Ti–6Al–4V. Mater. Sci. Eng. A, 2001, 299(1–2): 225

[7]

Lai YJ, Xin SW, Zhang PX, Zhao YQ, Ma FJ, Liu XH, Feng Y. Recrystallization behavior of Ti40 burn-resistant titanium alloy during hot working process. Int. J. Miner. Metall. Mater., 2016, 23(5): 581

[8]

Seshacharyulu T, Medeiros SC, Morgan JT, Malas JC, Frazier WG, Prasad YVRK. Hot deformation and microstructural damage mechanisms in extra-low interstitial (ELI) grade Ti–6Al–4V. Mater. Sci. Eng. A, 2000, 279(1–2): 289

[9]

Nocivin A, Cinca I, Raducanu D, Cojocaru VD, Popovici IA. Mechanical properties of a Gum-type Ti–Nb–Zr–Fe–O alloy. Int. J. Miner. Metall. Mater., 2017, 24(8): 909

[10]

Raghunathan S, Dashwood RJ, Jackson M, Vogel SC, Dye D. The evolution of microtexture and macrotexture during subtransus forging of Ti–10V–2Fe–3Al. Mater. Sci. Eng. A, 2008, 488(1–2): 8

[11]

Terlinde GT, Duerig TW, Williams JC. Microstructure, tensile deformation, and fracture in aged ti 10V–2Fe–3Al. Metall. Trans. A, 1983, 14(10): 2101

[12]

He B, Tian XJ, Cheng X, Li J, Wang HM. Effect of weld repair on microstructure and mechanical properties of laser additive manufactured Ti-55511 alloy. Mater. Des., 2017, 119, 437

[13]

Nag S, Banerjee R, Hwang JY, Harper M, Fraser HL. Elemental partitioning between α and β phases in the Ti–5Al–5Mo–5V–3Cr–0.5Fe (Ti-5553) alloy. Philos. Mag., 2009, 89(6): 535

[14]

Chen FW, Xu GL, Zhang XY, Zhou KC, Cui YW. Effect of α morphology on the diffusional β↔α transformation in Ti-55531 during continuous heating: Dissection by dilatometer test, microstructure observation and calculation. J. Alloys Compd., 2017, 702(25): 352

[15]

Fan J.K., Li J.S., Kou H.C., Hua K., Tang B. The interrelationship of fracture toughness and microstructure in a new near β titanium alloy Ti–7Mo–3Nb–3Cr–3Al. Materials Characterization, 2014, 96, 93-99.

[16]

Cherukuri B, Srinivasan R, Tamirisakandala S, Miracle DB. The influence of trace boron addition on grain growth kinetics of the beta phase in the beta titanium alloy Ti–15Mo–2.6Nb–3Al–0.2Si. Scripta Mater., 2009, 60(7): 496

[17]

Jones NG, Dashwood RJ, Jackson M, Dye D. Development of chevron-shaped α precipitates in Ti–5Al–5Mo–5V–3Cr. Scripta Mater., 2009, 60(7): 571

[18]

Dehghan-Manshadi Ali, Dippenaar Rian J. Development of α-phase morphologies during low temperature isothermal heat treatment of a Ti–5Al–5Mo–5V–3Cr alloy. Materials Science and Engineering: A, 2011, 528(3): 1833-1839.

[19]

Fan JK, Kou HC, Lai MJ, Tang B, Chang H, Li JS. Characterization of hot deformation behavior of a new near beta titanium alloy: Ti-7333. Mater. Des., 2013, 49, 945

[20]

Qazi JI, Rack HJ, Marquardt B. High-strength metastable beta-titanium alloys for biomedical applications. JOM, 2004, 56(11): 49

[21]

Banerjee R, Nag S, Stechschulte J, Fraser HL. Strengthening mechanisms in Ti–Nb–Zr–Ta and Ti–Mo–Zr–Fe orthopaedic alloys. Biomaterials, 2004, 25(17): 3413

[22]

Zhou T, Aindow M, Alpay SP, Blackburn MJ, Wu MH. Pseudo-elastic deformation behavior in a Ti/Mo-based alloy. Scripta Mater., 2004, 50(3): 343

[23]

Oyama T, Watanabe C, Monzen R. Growth kinetics of ellipsoidal ω-precipitates in a Ti–20 wt%Mo alloy under compressive stress. J. Mater. Sci., 2016, 51(19): 8880

[24]

Wang CH, Yang CD, Liu M, Li X, Hu PF, Russell AM, Cao GH. Martensitic microstructures and mechanical properties of as-quenched metastable β-type Ti–Mo alloys. J. Mater. Sci., 2016, 51(14): 6886

[25]

Monzen R, Kawai R, Oyama T, Watanabe C. Tensile-stress-induced growth of ellipsoidal ω-precipitates in a Ti–20wt%Mo Alloy. J. Mater. Sci., 2016, 51(5): 2490

[26]

Zhao JC. A combinatorial approach for efficient mapping of phase diagrams and properties. J. Mater. Res., 2001, 16(6): 1565

[27]

Zhao JC, Zheng X, Cahill DG. High-throughput diffusion multiples. Mater. Today, 2005, 8(10): 28

[28]

Zhao JC, Zheng X, Cahill DG. High-throughput measurements of materials properties. JOM, 2011, 63(3): 40

[29]

Zheng X, Cahill DG, Krasnochtchekov P, Averback RS, Zhao JC. High-throughput thermal conductivity measurements of nickel solid solutions and the applicability of the Wiedemann-Franz law. Acta Mater., 2007, 55(15): 5177

[30]

Zhang XD, Liu LB, Zhao JC, Wang JL, Zheng F, Jin ZP. High-efficiency combinatorial approach as an effective tool for accelerating metallic biomaterials research and discovery. Mater. Sci. Eng. C, 2014, 39(1): 273

[31]

Wu D, Liu LB, Zhang LG, Zeng LJ, Shi X. Investigation of the influence of Cr on the microstructure and properties of Ti6Al4VxCr alloys with a combinatorial approach. J. Mater. Eng. Perform., 2017, 26(9): 4364

[32]

Wang C, Li N, Cui Y, Pérez-Prado MT. Effect of solutes on the rate sensitivity in Ti–xAl–yMo–zV and Ti–xAl–yMo–zCr β–Ti alloys. Scripta Mater., 2018, 149, 129

[33]

Williams JC, Hickman BS. Tempering behavior of orthorhombic martensite in titanium alloys. Metall. Mater. Trans. B, 1970, 1(9): 2648

[34]

Kim HY, Ikehara Y, Kim JI, Hosoda H, Miyazaki S. Martensitic transformation, shape memory effect and superelasticity of Ti–Nb binary alloys. Acta Mater., 2006, 54(9): 2419

[35]

Ho WF, Wu SC, Hsu SK, Li YC, Hsu HC. Effects of molybdenum content on the structure and mechanical properties of as-cast Ti–10Zr-based alloys for biomedical applications. Mater. Sci. Eng. C, 2012, 32(3): 517

[36]

Ho WF, Wu SC, Chang HH, Hsu HC. Structure and mechanical properties of Ti–5Cr based alloy with Mo addition. Mater. Sci. Eng. C, 2010, 30(6): 904

[37]

Du Z, Xiao S, Xu L, Tian J, Kong F, Chen Y. Effect of heat treatment on microstructure and mechanical properties of a new β high strength titanium alloy. Mater. Des., 2014, 55(55): 183

[38]

Ho WF, Ju CP, Lin JH. Structure and properties of cast binary Ti–Mo alloys. Biomaterials, 1999, 20(22): 2115

[39]

Ni Y, Khachaturyan AG. From chessboard tweed to chessboard nanowire structure during pseudospinodal decomposition. Nat. Mater., 2009, 8(5): 410

[40]

Oliveira NTC, Guastaldi AC. Electrochemical stability and corrosion resistance of Ti–Mo alloys for biomedical applications. Acta Biomater., 2009, 5(1): 399

[41]

Kar SK, Ghosh A, Fulzele N, Bhattacharjee A. Quantitative microstructural characterization of a near beta Ti alloy, Ti-5553 under different processing conditions. Mater. Charact., 2013, 81(4): 37

[42]

Wang CY, Yang LW, Cui YW, Pérez-Prado MT. High throughput analysis of solute effects on the mechanical behavior and slip activity of beta titanium alloys. Mater. Des., 2017, 137, 371

[43]

Mora L, Quesne C, Haut C, Servant C, Penelle R. Relationships among thermomechanical treatments, microstructure, and tensile properties of a near beta-titanium alloy: β-CEZ: Part I. relationships between thermomechanical treatments and microstructure. J. Mater. Res., 1996, 11(1): 89

[44]

Srinivasu G, Natraj Y, Bhattacharjee A, Nandy TK, Rao GVSN. Tensile and fracture toughness of high strength β titanium alloy, Ti–10V–2Fe–3Al, as a function of rolling and solution treatment temperatures. Mater. Des., 2013, 47, 323

[45]

Huang J, Wang Z, Xue K. Cyclic deformation response and micromechanisms of Ti alloy Ti–5Al–5V–5Mo–3Cr–0.5Fe. Mater. Sci. Eng. A, 2011, 528(29–30): 8723

[46]

Jackson M, Jones NG, Dye D, Dashwood RJ. Effect of initial microstructure on plastic flow behaviour during isothermal forging of Ti–10V–2Fe–3Al. Mater. Sci. Eng. A, 2009, 501(1–2): 248

[47]

Qin D, Lu Y, Guo D, Zheng L, Liu Q, Zhou L. Tensile deformation and fracture of Ti–5Al–5V–5Mo–3Cr–1.5Zr–0.5Fe alloy at room temperature. Mater. Sci. Eng. A, 2013, 587, 100

[48]

Ho WF, Wu SC, Hsu SK, Li YC, Hsu HC. Effects of molybdenum content on the structure and mechanical properties of as-cast Ti–10Zr-based alloys for biomedical applications. Mater. Sci. Eng. C, 2012, 32(3): 517

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