Mechanism of Mg²⁺ dissolution from olivine and serpentine: Implication for bioleaching of high-magnesium nickel sulfide ore at elevated pH

Abstract

To inhibit the dissolution of Mg²⁺ during the bioleaching process of high-magnesium nickel sulfide ore, the effect of major bi-oleaching factors on the dissolution of Mg²⁺ from olivine and serpentine was investigated and kinetics studies were carried out. The results indicated that the dissolution rate-controlling steps are chemical reaction for olivine and internal diffusion for serpentine. The most influential factor on the dissolution of Mg²⁺ from olivine and serpentine was temperature, followed by pH and particle size. A novel method of bi-oleaching at elevated pH was used in the bioleaching of Jinchuan ore. The results showed that elevated pH could significantly reduce the dissolution of Mg²⁺ and acid consumption along with slightly influencing the leaching efficiencies of nickel and cobalt. A model was used to explain the leaching behaviors of high-magnesium nickel sulfide ore in different bioleaching systems. The model suggested that olivine will be depleted eventually, whereas serpentine will remain because of the difference in the rate-controlling steps. Bioleaching at elevated pH is a suitable method for treating high-magnesium nickel sulfide ores.

Keywords

olivine / serpentine / high-magnesium nickel sulfide ore / bioleaching / shrinking core model / elevated pH

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