A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators (COGs)
Jian-guo Liu , Long-zhe Jin , Na Gao , Sheng-nan Ou , Shu Wang , Wei-xiang Wang
International Journal of Minerals, Metallurgy, and Materials ›› 2019, Vol. 26 ›› Issue (8) : 925 -937.
A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators (COGs)
Chemical oxygen generators (COGs) have been used worldwide in confined spaces as an emergency oxygen supply technology, mainly because they are independent and have a long shelf life. However, a number of challenges related to COGs remain unsolved, and a literature review of the current state of the technology is needed. First, the present article summarizes the basic information and applications of COGs, including their oxygen production mechanism, components, forming technology, and ignition system. Four current challenges encountered in applying COGs are discussed, along with the strategies adopted thus far to solve these problems, as found in the published literature. The literature survey reveals that, although much effort has been devoted to controlling the oxygen production rate and the heat output of COGs, the mechanism of producing toxic gases remains unclear and a reliable and safe ignition system has not been fully developed. Finally, future opportunities in the development of COGs are briefly listed.
chemical oxygen generators / oxygen supply technology / thermal decomposition / catalytic / metal fuel / combustion
| [1] |
|
| [2] |
|
| [3] |
|
| [4] |
|
| [5] |
|
| [6] |
|
| [7] |
|
| [8] |
|
| [9] |
|
| [10] |
|
| [11] |
N. Gao, J. Li, L.Z. Jin, and Z. Zhang, Oxygen Supply System of Oxygen Candle in Emergency Rescue Space, Chinese Patent, Appl. 103362544A, 2013. |
| [12] |
|
| [13] |
|
| [14] |
V.N. Harwood, Chemical oxygen generators for business and utility aircraft, SAE Trans., 1971, p. 1494. |
| [15] |
|
| [16] |
|
| [17] |
|
| [18] |
|
| [19] |
|
| [20] |
|
| [21] |
|
| [22] |
|
| [23] |
|
| [24] |
|
| [25] |
Y.J. Wang, L.E. Ma, and J.F. Ning, Chlorine suppressants and chlorine gas filtering materials for the oxygen-generating candles, Chem. Def. Ships, 2010, No. 1, p. 21. |
| [26] |
Y.C. Zhang, M.J. Brumely, J.C. Cannon, J.E. Ellison, and G.S. Kshirsagar, Filter for Chemical Oxygen Generators, U.S. Patent, Appl. 6464757, 2002. |
| [27] |
|
| [28] |
S.P. Schillaci, Chlorine Gas Filtering Material Suitable for Use in a Chemical Oxygen Generator, U.S. Patent, Appl. 4687640, 1987. |
| [29] |
|
| [30] |
|
| [31] |
|
| [32] |
|
| [33] |
|
| [34] |
|
| [35] |
|
| [36] |
|
| [37] |
|
| [38] |
|
| [39] |
|
| [40] |
|
| [41] |
|
| [42] |
|
| [43] |
A. Schwendiman, Toxicity and decomposition of sodium chlorate in soils, J. Am. Soc. Agron., 1941, p. 522. |
| [44] |
|
| [45] |
|
| [46] |
|
| [47] |
Submarine Air Regeneration and Analysis Writing Group. Submarine Air Regeneration and Analysis, 1983, Beijing, National Defence Industry Press 103. |
| [48] |
H.Y. Ding, Development of chlorate oxygen candle research to improve the air quality of submarine cabin, Chem. Def. Ships, 1991, No. 12, p. 2–3. |
| [49] |
J.G. Liu, L.Z. Jin, N. Gao, W.X. Wang, and J. Shen, Effect of forming technology on oxygen supply performance of oxygen candles in refuge spaces, [in] 3rd International Symposium on Mine Safety Science and Engineering, Québec, 2016, p. 308. |
| [50] |
Z. H. Zhang, Oxygen candle starting device of chemical oxygen self-rescuer, Saf. Coal Mines, 1995, No. 11, p. 29. |
| [51] |
|
| [52] |
R. Lester, Aircraft Passenger Oxygen, Survival and Escape Mask, U.S. Patent, Appl. 5709204, 1998. |
| [53] |
E.J. Brennan, Emergency Oxygen System for Aircraft, U.S. Patent, Appl. 4609166, 1986. |
| [54] |
R.F. Boehme and D.R. Zuck, Emergency Oxygen System for High Altitude Aircraft, U.S. Patent, Appl. 2934293, 1960. |
| [55] |
W.S. McBride, Chemical Oxygen Generator, U.S. Patent, Appl. 4278637, 1981. |
| [56] |
|
| [57] |
B.N. Arnold, Oxygen Candle Cover, UK Patent, Appl. 9703221, 1997. |
| [58] |
H.C. Gao, W.X. Ma, Y. Zhang, and F.Y. Shi, Sodium Chlorate Oxygen Candle, Chinese Patent Appl. 1035248A, 1989. |
| [59] |
|
| [60] |
|
| [61] |
|
| [62] |
X. Han, A Method of Generating Oxygen by Using Microwave Heating Oxygen Candle and the Apparatus of Microwave, Chinese Patent, Appl. CN1962415, 2007. |
| [63] |
|
| [64] |
M. Machado, D. Rodriguez, E. Shafirovich, and E. Dreizin, Selection of nanocomposite reactive materials for using in oxygen and hydrogen generators, [in] 51st AIAA Aerospace Sciences Meeting Including the New Horizons Forum and Aerospace Exposition, Grapevine, 2013, p. 822. |
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