Effect of heat treatment on the microstructure and micromechanical properties of the rapidly solidified Mg_61.7Zn₃₄Gd_4.3 alloy containing icosahedral phase

Abstract

In this paper, the microstructure evolution of the rapidly solidified (RS) Mg_61.7Zn₃₄Gd_4.3 (at%, atomic ratio) alloy at high temperatures was investigated. The hardness and elastic modulus of the main precipitated phases were also analyzed and compared with those of the α-Mg matrix on the basis of nanoindentation tests. The results show that the RS alloy consists of either a petal-like icosahedral quasicrystal (IQC) phase (~20 μm) and block-shaped H1 phase (~15 μm) or IQC particles with an average grain size of ~107 nm as well as a small proportion of amorphous phase, which mainly depends on the holding time at the liquid temperature and the thickness of the ribbons. The IQC phase gradually transforms at 400°C to a short-rod-shaped μ-phase (Mg_28.6Zn_63.8Gd_7.7) with a hexagonal structure. The hardness of the IQC phase is higher than that of H1 phase, and both phases exhibit a higher hardness than the α-Mg matrix and the μ-phase. The elasticity of the H1 phase is superior to that of the α-Mg matrix. The IQC phase possesses a higher elastic modulus than H1 phase. The easily formed H1 phase exhibits the poorest plastic deformation capacity among these phases but a higher elastic modulus than the α-Mg matrix.

Keywords

magnesium alloy / icosahedral phase / rapidly solidification / nanoindentation / micromechanical properties

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