Gas-solid reduction kinetic model of MgO-fluxed pellets

Qiang-jian Gao , Feng-man Shen , Xin Jiang , Guo Wei , Hai-yan Zheng

International Journal of Minerals, Metallurgy, and Materials ›› 2014, Vol. 21 ›› Issue (1) : 12 -17.

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International Journal of Minerals, Metallurgy, and Materials ›› 2014, Vol. 21 ›› Issue (1) : 12 -17. DOI: 10.1007/s12613-014-0859-z
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Gas-solid reduction kinetic model of MgO-fluxed pellets

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Abstract

The reduction process of MgO-fluxed pellets was investigated and compared with traditional acidic pellets in this paper. Based on the piston flow concept and experimental data, a kinetic model fitting for the gas-solid phase reduction of pellets in tubular reactors (blast furnace, BF) was built up, and the equations of reduction reaction rate were given for pellets. A series of reduction experiments of pellets were carried out to verify the model. As a result, the experimental data and calculated result were fitted well. Therefore, this model can well describe the gas-solid phase reduction process and calculate the reduction reaction rate of pellets. Besides, it can give a better explanation that the reduction reaction rate (reducibility) of MgO-fluxed pellets is better than that of traditional acidic pellets in BF.

Keywords

ore pellets / magnesia / reduction / kinetics / blast furnaces

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Qiang-jian Gao, Feng-man Shen, Xin Jiang, Guo Wei, Hai-yan Zheng. Gas-solid reduction kinetic model of MgO-fluxed pellets. International Journal of Minerals, Metallurgy, and Materials, 2014, 21(1): 12-17 DOI:10.1007/s12613-014-0859-z

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References

[1]

Gao QJ, Shen FM, Wei G, Jiang X, Zheng HY. Effects of MgO containing additive on low-temperature metallurgical properties of oxidized pellet. J. Iron Steel Res. Int., 2013, 20(7): 25.

[2]

Fu JY, Zhu DQ. Basic Principles, Techniques and Equipment of the Iron Ore Oxidized Pellets, 2005, Changsha, The Central South University Press, 336

[3]

Nishimura T, Higuchi K, Naito M, Kunitomo K. Evaluation of softening, shrinking and melting reduction behavior of raw materials for blast furnace. ISIJ Int., 2011, 51(8): 1316.

[4]

Iljana M, Mattila O, Alatarvas T, Kurikkala J, Paananen T, Fabritius T. Effect of circulating elements on the dynamic reduction swelling behaviour of olivine and acid iron ore pellets under simulated blast furnace shaft conditions. ISIJ Int., 2013, 53(3): 419.

[5]

Chun TJ, Zhu DQ, Pan J. Influence of sulfur content in raw materials on oxidized pellets. J. Cent. South Univ. Technol., 2011, 18(6): 1924.

[6]

Li SH, Chen TJ, Zhang YM, Zhao J. Experimental study on application of Mg -bearing additives in iron ore pellet. Sintering Pelletizing, 2011, 36(1): 33

[7]

Coetsee T, Pistorius PC, de Villiers EE. Rate-determining steps for reduction in magnetite-coal pellets. Miner. Eng., 2002, 15(11): 919.

[8]

Jiang X, Li GS, Shen FM. Study on improving the softening-melting properties of MgO-bearing iron ores. J. Northeast. Univ. Nat. Sci., 2007, 28(3): 365

[9]

Zhou GF, Yang F. Effects of adding MgO on pelletizing ability and strength of pellet. Res. Iron Steel, 2009, 37(2): 10

[10]

Shen FM, Wu GS, Jiang X, Wei G, Li XG, Shen YS. Proper MgO addition in blast furnace operation. ISIJ Int., 2006, 46(1): 65.

[11]

Shen FM, Wu GS, Jiang X. A new process of proper MgO addition in blast furnace operation. Proceedings of Commemorative International Symposium on Ironmaking Process and Environment, 2005 25

[12]

Szekely J, Evans JW, Sohn HY. Gas-Solid Reductions, 1976, New York, Academic Press, 97

[13]

Sohn HY. Rate Processes of Extractive Metallurgy, 1979, New York, Plenum Press, 115.

[14]

Gao QJ, Wei G, He YB, Shen FM. Effect of MgO on compressive strength of pellet. J. Northeast. Univ. Nat. Sci., 2013, 34(1): 103

[15]

Pal J, Ghorai S, Goswami MC, Ghosh D, Bandyopadhyay D, Ghosh S. Behavior of fluxed lime iron oxide pellets in hot metal bath during melting and refining. Int. J. Miner. Metall. Mater., 2013, 20(4): 329.

[16]

Kemppainen A, Mattila O, Heikkinen EP, Paananen T, Fabritius T. Effect of H2-H2O on the reduction of olivine pellets in CO-CO2 Gas. ISIJ Int., 2012, 52(11): 1973.

[17]

Semberg P, Andersson C, Björkman B. Interaction between iron oxides and olivine in magnetite pellets during reduction to wustite at temperatures of 1000–1300°C. ISIJ Int., 2013, 53(3): 391.

[18]

Biswas AK. Principles of Blast Furnace Ironmaking, 1981, Australia, Cootha Publishing House, 38

[19]

Shen FM, Gao QJ, Wei G, Ding ZM. Effect of MgO-bearing additive on metallurgical property of pellets. Asia Steel International Conference 2012, 2012 19

[20]

Gao QJ, Wen QL, Wei G, Jiang X, Shen FM. Study on the effect of caustic calcined magnesite to quality of green-pellets. The 4th Australia-China-Japan Symposium on Iron and Steelmaking, 2012 102

[21]

Khaki JV, Kashiwa Y, Ishii K. High temperature behaviour of selffluxed pellets during heating up reduction. Ironmaking Steelmaking, 1994, 21(1): 56

[22]

Mu L, Jiang X, Gao QJ, Wei G, Shen FM. Effect of hydrogen addition on low temperature metallurgical property of sinter. J. Iron Steel Res. Int., 2012, 19(4): 6.

[23]

Matsumura M, Hoshi M, Kawaguchi T. Improvement of sinter softening property and reducibility by controlling chemical compositions. ISIJ Int., 2005, 45(4): 594.

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