Near-net shape processing of spherical high Nb-TiAl alloy powder by gelcasting

Hui-ping Shao , Xiao-ting Liu , Ye Ji , Zhi-meng Guo

International Journal of Minerals, Metallurgy, and Materials ›› 2013, Vol. 20 ›› Issue (11) : 1076 -1080.

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International Journal of Minerals, Metallurgy, and Materials ›› 2013, Vol. 20 ›› Issue (11) : 1076 -1080. DOI: 10.1007/s12613-013-0836-y
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Near-net shape processing of spherical high Nb-TiAl alloy powder by gelcasting

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Abstract

Spherical Ti-45Al-8.5Nb-(W,B,Y) alloy powder prepared by an argon plasma process was near-net shape by gelcasting. In the non-aqueous system, methaerylate-2-hydroxy ethyl, toluene, benzoyl peroxide, and N,N-dimethylaniline were used as the monomer, solvent, initiator, and catalyst, respectively. To improve sintering and forming behaviors, many additives were included in the suspension. The concentrated suspension with a solid loading of 70vol% was prepared. The high Nb-TiAl powder was analyzed by electron microscopy and X-ray diffraction. It was found that the green bodies had a smooth surface and homogeneous microstructure, exhibiting a bending strength as high as 50 MPa. After sintering at 1480°C for 2 h in vacuum, uniform complex-shaped high Nb-TiAl parts were successfully produced.

Keywords

titanium aluminum alloys / niobium alloys / powders / gelcasting / microstructure

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Hui-ping Shao, Xiao-ting Liu, Ye Ji, Zhi-meng Guo. Near-net shape processing of spherical high Nb-TiAl alloy powder by gelcasting. International Journal of Minerals, Metallurgy, and Materials, 2013, 20(11): 1076-1080 DOI:10.1007/s12613-013-0836-y

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References

[1]

Paransky E, Gutmanas EY, Gotman I, Koczak M. Pressure-assisted reactive synthesis of titanium aluminides from dense 50Al-50Ti elemental powder blends. Metall. Mater. Trans. A, 1996, 27, 2130.

[2]

Sung SY, Kim YJ. Economic net-shape forming of TiAl alloys for automotive parts. Intermetallics, 2006, 14(10–11): 1163.

[3]

Chen G, Sun Z, Zhou X. Oxidation of intermetallic alloys in Ti-Al-Nb ternary system. Corrosion, 1992, 48(11): 939.

[4]

Wang SR, Guo PQ, Yang LY. Centrifugal precision cast TiAl turbocharger wheel using ceramic mold. J. Mater. Process. Technol., 2008, 204(1–3): 492

[5]

Zhang WJ, Chen GL, Sun ZQ. Oxidation of ternary Ti18Nb48Al and Ti10Nb45Al alloys. Scripta Metall. Mater., 1993, 28, 563.

[6]

Harding RA. Recent developments in the induction skull melting and investment casting of titanium aluminides. Kovové Mater., 2004, 42(4): 225

[7]

Lin JP, Zhao LL, Li GY, Zhang LQ, Song XP, Ye F, Chen GL. Effect of Nb on oxidation behavior of high Nb containing TiAl alloys. Intermetallics, 2011, 19(2): 131.

[8]

Bauer V, Christ HJ. Thermomechanical fatigue behaviour of a third generation γ-TiAl intermetallic alloy. Intermetallics, 2009, 17(5): 370.

[9]

Kong FT, Chen YY, Li BH. Influence of yttrium on the high temperature deformability of TiAl alloys. Mater. Sci. Eng. A., 2009, 499(1–2): 53.

[10]

Divinski SV, Hisker F, Wilger T, Friesel M, Herzig Chr. Tracer diffusion of boron in α-Ti and γ-TiAl. Intermetallics, 2008, 16, 148.

[11]

Ninomi M, Nakano S, Hasegawa T, Shibue K. Microstructure and fracture characteristics in reactive sintering TiAl intermetallic compound. J. Jpn. Inst. Light Met., 1997, 47(10): 521.

[12]

Couret A, Molénat G, Galy J, Thomas M. Microstructures and mechanical properties of TiAl alloys consolidated by spark plasma sintering. Intermetallics, 2008, 16(9): 1134.

[13]

Beschliesser M, Chatterjee A, Lorich A, Knabl W, Dehm G, Clemens H. Designed fully lamellar microstructures in a γ-TiAl based alloy: adjustment and microstructural changes upon long-term isothermal exposure at 700 and 800°C. Mater. Sci. Eng. A, 2002, 329–331, 124.

[14]

Omatete OO, Janney MA, Strehlow RA. Gelcasting: a new ceramic forming process. Am. Ceram. Soc. Bull., 1991, 70(10): 1641

[15]

Gilissen R, Erauw JP, Smolders A, Vanswijgenhoven E, Luyten J. Gelcasting, a near net shape technique. Mater. Des., 2000, 21(4): 251.

[16]

Jr WE D, Donlon WT, Allison JE. Development of TiAl-based automotive engine valves. MRS Proc., 1994, 364, 757.

[17]

Li F, Ni HJ, Wang J, Sun BD, Du ZH. Gelcasting of aqueous mesocarbon microbead suspension. Carbon, 2004, 42(14): 2989.

[18]

Yang JL, Yu JL, Huang Y. Recent developments in gelcasting of ceramics. J. Eur. Ceram. Soc., 2011, 31(14): 2569.

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